Search results for "PLE"

Synthesis, structural characterization and antitumor activity of di- and tri-organotin(IV) complexes of D-galacturonic acid

2015

Speciation of dimethyltin(IV) – and trimethyltin(IV) – carbocysteinate and – glutamate systems in aqueous media

2008

The formation of complex species in the dimethyltin(IV) and trimethyltin(IV)-carboxymethyl-L-cysteinate (carbocysteinate) systems in NaClaq, at different ionic strengths, and in a multicomponent Na+, K+, Ca2+, Mg2+, Cl- and SO42- medium representative of the seawater major composition, is discussed. Experimental results give evidence for the formation of the following species (L¼carbocysteinate): [(CH3)2Sn(L)]0, [(CH3)2Sn(HL)]+, [(CH3)2Sn(OH)(L)]-, [(CH3)2Sn(OH)2(L)]2- in the DMT–CCYS system, and [(CH3)3Sn(HL)]0, [(CH3)3Sn(L)]- and [(CH3)3Sn(OH)(L)]2- in the TMT-CCYS system. The ionic strength dependence of formation constants was taken into account by an extended Debye Huckel type equation…

Developing Primary School Students’ Formal Geometric Definitions Knowledge by Connecting Origami and Technology

2019

In this paper, we present opportunities with the uses of origami and technology, in our case GeoGebra, in teaching formal geometric definitions for fifth-grade primary school students (11-12yrs). Applying origami in mathematical lessons is becoming to be recognized as a valuable tool for improving students’ mathematical knowledge. In previous studies, we developed origami and technology activities for high-school mathematics, but we wanted to explore if such approach would work in primary school as well. For this reason, we chose a flat origami model оf the crane and we used this model to introduce students to basic geometrical notions and definitions, such as points, lines, intersections o…

Effect of Germacrene-Rich Essential Oil of Parentucellia latifolia (L.) Caruel Collected in Central Sicily on the Growth of Microorganisms Inhabiting…

2022

In the present study, the chemical composition of the essential oil from aerial parts of Parentucellia latifolia (L.) Caruel collected in Central Sicily was analyzed by gas chromatography and gas chromatography–mass spectrometry. The results showed the presence of sesquiterpene hydrocarbons, with germacrene D and germacrene B accounting, respectively, for 59.2% and 24.3% of the total oil. Different colonies of bacteria and fungi frequently affect cellulosic objects such as books stored in libraries and museums. The antibacterial and antifungal activity against some microorganisms infesting historical-artistic craftsmanship was determined, demonstrating that the essential oil was particular…

{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane…

2016

The molecule of the title compound, [Rh(C42H62O3P)(C74H68O4P2]·2.7C7D8, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/ortho-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a tetrahedrally distorted square-planar coordination geometry. A tert-butyl group shows rotational disorder over two positions with refined site occupancy of 0.561 (3):0.439 (3). Two partial-occupancy toluene solvent molecules are disordered over two orientations with site occupancies of 0.5:0.3 and 0.5:0.4, respectively. Intramolecular C—H...O hydrogen bonds are observed. In the crystal, complex …

Cracking the Code : The Impact of Orthographic Transparency and Morphological-Syllabic Complexity on Reading and Developmental Dyslexia

2019

Les simplifications de l'accord du participe passé dans la CMO : un vrai tabou linguistique pour la langue Française?

2016

The aim of this article is to analyze the agreement of the past participle in Computer mediated communication, especially on Facebook. The graphic realization of the past participle agreement is considered as one of the main difficulties of the French orthography which is characterized by its extreme opacity. Breaking this rule can be compared in the French culture to a sort of a linguistic taboo. The aim of our study is to answer the question if the simplifications of the agreement of the past participle are allowed in Computer mediated communication or if they are considered as a kind of linguistic taboo. To answer this question, we have of a corpus of 200 past participle agreements downl…

Asymptotic Lipschitz regularity for tug-of-war games with varying probabilities

2018

We prove an asymptotic Lipschitz estimate for value functions of tug-of-war games with varying probabilities defined in $\Omega\subset \mathbb R^n$. The method of the proof is based on a game-theoretic idea to estimate the value of a related game defined in $\Omega\times \Omega$ via couplings.

On some partial data Calderón type problems with mixed boundary conditions

2021

In this article we consider the simultaneous recovery of bulk and boundary potentials in (degenerate) elliptic equations modelling (degenerate) conducting media with inaccessible boundaries. This connects local and nonlocal Calderón type problems. We prove two main results on these type of problems: On the one hand, we derive simultaneous bulk and boundary Runge approximation results. Building on these, we deduce uniqueness for localized bulk and boundary potentials. On the other hand, we construct a family of CGO solutions associated with the corresponding equations. These allow us to deduce uniqueness results for arbitrary bounded, not necessarily localized bulk and boundary potentials. T…

Oxidative ortho-C-N Fusion of Aniline by OsO4. Isolation, Characterization of Oxo-Amido Osmium(VI) Complexes, and their Catalytic Activities for Oxid…

2008

In an unusual reaction of osmium(VIII) oxide with p-substituted aromatic amines (X-C6H4-NH2, where X = Me, H, Cl) in heptane afforded the brown osmium(VI)-oxo complexes [OsO(L)2] (1a-c, L = N-aryl-1,2-arylenediamide) in moderate yields. The ligand L is formed in situ via oxidative ortho-C-N fusion of arylamines. The reaction occurs in an inert atmosphere, and a part of Os(VIII) is used up for the oxidation of aromatic amine. Single crystal X-ray structure of a representative complex 1a is solved. The structural analysis has authenticated the ortho-C-N fusion of ArNH2 resulting in formation of the diamide ligand, L. The complex as a whole is penta-coordinated, and the coordination sphere has…