Search results for "POINT DEFECTS"
showing 10 items of 46 documents
Pulsed X‐Ray Radiation Responses of Solarization‐Resistant Optical Fibers
2018
International audience; The transient radiation‐induced attenuation (RIA) of two different versions of pure‐silica‐core (PSC) multimode optical fibers (so‐called “solarization‐resistant” fibers) exposed to nanosecond 1 MeV X‐ray pulses are investigated. On‐line RIA spectra measurements at both room temperature (RT) and liquid nitrogen temperatures (LNT) in the range 1–3.5 eV are performed. Following the RIA kinetics, the properties of the metastable defects that are bleached just after the pulse are discussed. The spectral decomposition of the RIA is performed using known Gaussian bands associated to point defects absorbing in this spectral range. For both fiber types, the generation and th…
Coupled irradiation-temperature effects on induced point defects in germanosilicate optical fibers
2017
International audience; We investigated the combined effects of temperature and X-rays exposures on the nature of point defects generated in Ge-doped multimode optical fibers. Electron paramagnetic resonance (EPR) results on samples X-ray irradiated at 5 kGy(SiO2), employing different temperatures and dose rates, are reported and discussed. The data highlight the generation of the Ge(1), Ge(2), E0 Ge and E0 Si defects. For the Ge(1) and Ge(2), we observed a decrease in the induced defect concentrations for irradiation temperatures higher than *450 K, whereas the E0 defects feature an opposite tendency. The comparison with previous post-irradiation thermal treatments reveals peculiar effects…
X-ray irradiation effects on a multistep Ge-doped silica fiber produced using different drawing conditions
2011
International audience; We report an experimental study based on confocal microscopy luminescence (CML) and electron paramagnetic resonance (EPR) measurements to investigate the effects of the X-ray (from 50 krad to 200 Mrad) on three specific multistep Ge doped fibers obtained from the same preform by changing some of the drawing conditions (tension and speed). CML data show that, both before and after the irradiation, Germanium Lone Pair Center (GLPC) concentrations are similarly distributed along the diameters of the three fibers and they are partially reduced by irradiation. The irradiation induces also the Non Bridging Oxygen Hole Center (NBOHC) investigated by CML and other paramagnet…
Influence of Drawing Conditions on the Properties and Radiation Sensitivities of Pure-Silica-Core Optical Fibers
2012
International audience; The structure and radiation sensitivities of three different pure-silica-core fluorine-doped-cladding optical fibers, made from the same original preform, were investigated by several experimental techniques. The fibers were obtained by changing the drawing speed and tension in the typical ranges of values used for the radiation-tolerant waveguides. The Raman spectroscopy revealed no significant difference among the fibers before irradiation. At variance, the comparison between the fibers and their associated preform highlighted an increase in the amplitude of the D2 band that is related to the concentration of 3 member rings. Moreover, in the zones where the D2 incr…
Ultraviolet-visible light-induced solarisation in silica-based optical fibres for indoor solar applications
2021
Abstract The transmission performances of pure- and doped-silica (a-SiO2) optical fibres are compared during the exposure to a high-power broadband light source approximating the solar spectrum. From the Gaussian decomposition of the attenuation spectra, we found that Al- and P-doped fibres show a fast solarisation effect which leads to transmission degradation in the ultraviolet-visible range. Similarly, Ge-doped fibres undergo photoinduced colour-centre formation which, however, does not prevent visible-light propagation. One of the two tested pure-silica fibres results completely unaffected by light exposure whereas the other shows an absorption band probably due to the presence of chlor…
Luminescence features of nonbridging oxygen hole centres in silica probed by site-selective excitation with tunable laser
2008
Time-resolved photoluminescence at 1.9 eV associated with the nonbridging oxygen hole centre (NBOHC) in silica was investigated under excitation with a ns pulsed laser system, tunable in the visible range. Mapping of the excitation/emission pattern evidences the site-selective excitation of the resonant zero phonon line (ZPL) transition due to its weak coupling with the stretching mode of dangling oxygen. Decay of ZPL follows an exponential law with lifetime of 15.3 μs, which provides a precise measure of the electronic transition probability of a single NBOHC.
Photoluminescence spectral dispersion as a probe of structural inhomogeneity in silica
2011
We perform time-resolved photoluminescence measurements on point defects in amorphous silicon dioxide (silica). In particular, we report data on the decay kinetics of the emission signals of extrinsic oxygen deficient centres of the second type from singlet and directly excited triplet states, and we use them as a probe of structural inhomogeneity. Luminescence activity in sapphire (alpha-Al(2)O(3)) is studied as well and used as a model system to compare the optical properties of defects in silica with those of defects embedded in a crystalline matrix. Only for defects in silica did we observe a variation of the decay lifetimes with emission energy and a time dependence of the first moment…
Relaxation processes of point defects in vitreous silica from femtosecond to nanoseconds
2008
We studied ultrafast relaxation of localized excited states at Ge-related oxygen deficient centers in silica using femtosecond transient-absorption spectroscopy. The relaxation dynamics exhibits a biexponential decay, which we ascribe to the departure from the Frank-Condon region of the first excited singlet state in 240 fs, followed by cooling in ∼10 ps. At later times, a nonexponential relaxation spanning up to 40 ns occurs, which is fitted with an inhomogeneous distribution of nonradiative relaxation rates, following a chi-square distribution with one degree of freedom. This reveals several analogies with phenomena such as neutron reactions, quantum dot blinking, or intramolecular vibrat…
Structural modifications induced by electron irradiation in SiO2 glass: Local densification measurements
2009
We report a study on the structural modifications induced in amorphous silicon dioxide (a-SiO2) by electron irradiation in the dose range from 1.2?103 to 5?106?kGy. This study has been performed by investigating the properties of the 29Si hyperfine structure of the E '? center by electron paramagnetic resonance (EPR) spectroscopy. Our data suggest that the structural modifications induced by irradiation take place through the nucleation of confined high-defective and densified regions statistically dispersed into the whole volume of the material. In addition, we have estimated that in the high dose limit (D?105?kGy) the degree of densification associated to the local (within the defective r…
β-ray irradiation effects on silica nanoparticles
2015
By electron paramagnetic resonance (EPR) measurements, we examine the amplitude of the signal typically due to a combination of NBOHC (Non Bridging Hole Center) and POR (Peroxy Radical) defects induced by β-ray irradiation (from 1.2 to 1200 MGy) in silica nanoparticles with diameter ranging from 7 to 20 nm. Our data indicate that the signal line-shapes recorded at different doses is quite independent from the particles sizes and from the dose. Furthermore, for each considered nanoparticles size, the concentration of defects is also almost constant with respect to dose, and it does not change significantly if measured after 2 or 9 months from the irradiation. By contrast, we observed that th…