Search results for "POROSITY"

Laboratory leaching studies of oryzalin and diuron through three undisturbed vineyard soil columns

2004

Article de revue (Article scientifique dans une revue à comité de lecture); International audience; The leaching of diuron and oryzalin through undisturbed soil columns was studied in the laboratory using three vineyard soils from Vosne-Romanée (Burgundy): a rendosol, a calcosol and a vegetated calcosol. After 845 mm of simulated rainfall in 15 days, soil leachates contained higher amounts of diuron (3.2%, 11.8% and 18.8% of applied diuron, respectively) than oryzalin (0.2%, 4.9%, 3.7%, respectively). A greater proportion of soil extractable residues was obtained for diuron (42.5%, 26.8% and 32.2%, respectively) than for oryzalin (14.7%, 12% and 15.5%, respectively). The greater mobility of…

Leaching of glyphosate and AMPA under two soil management practices in Burgundy vineyards (Vosne-Romanée, 21-France)

2005

Some drinking water reservoirs under the vineyards of Burgundy are contaminated with herbicides. Thus the effectiveness of alternative soil management practices, such as grass cover, for reducing the leaching of glyphosate and its metabolite, AMPA, through soils was studied. The leaching of both molecules was studied in structured soil columns under outdoor conditions for 1 year. The soil was managed under two vineyard soil practices: a chemically treated bare calcosol, and a vegetated calcosol. After 680 mm of rainfall, the vegetated calcosol leachates contained lower amounts of glyphosate and AMPA (0.02% and 0.03%, respectively) than the bare calcosol leachates (0.06% and 0.15%, respectiv…

Recent developments in the acoustical properties of perforated and porous materials containing dead-end pores

2017

It was shown recently in Nevers, France, Sherbrooke, Canada and Salford, UK, that porous materials with semi-opened pores or materials with open pores bearing lateral cavities or resonators at the microscopic scale of the pores can result in peculiar sound absorption properties. Various examples of these materials can be found in engineering and in everyday life including bio-based materials. The cavities and resonators can be assimilated to dead-end pores, which are opened at one end and closed at the other. The dead-end pores are known to geophysicists. We studied them more recently in the field of engineering acoustics where the saturating fluid is air. The closed ends prevent the fluid …

Functionnalized Surface Acoustic Wave Sensors for the Detection of Hazardous Gases

2018

International audience; In this work, we show the capabilities of Surface Acoustic Wave (SAW) devices to probe the properties of gas sensitive materials for the manufacturing of hazardous gas sensors. The great capabilities of cobalt corroles for the trapping of carbon monoxide (CO) were exploited to produce selective sensors. These corroles were deposited on SAW delay lines surfaces and then exposed to carbon monoxide (CO) in standard conditions. Concentrations of a few hundreds of ppb were measured emphasizing the interest of such sensors for the detection of CO. Another type of sensitive layers exhibiting specific porosity adapted to the trapping of formaldehyde (CH$_2$O) were deposited …

Directed Assembly of Cellulose Nanocrystals in Their Native Solid-State Template of a Processed Fiber Cell Wall

2021

Funding Information: I.S. thanks The Academy of Finland (grant no. 300364) for funding this work. C.D. acknowledges funding from FAPESP (grant 13/07932‐6). P.A.P. thanks the Emil Aaltonen Foundation and Academy of Finland (grant no. 315768) for funding and ESRF for beamtime at beamline D2am (experiment 02‐01‐885). Rita Hatakka is acknowledged for her assistance with the GPC measurements. Work of M.L. was supported by the Jane and Aatos Erkko Foundation. The work is a part of the FinnCERES Bioeconomy ecosystem. Publisher Copyright: © 2021 The Authors. Macromolecular Rapid Communications published by Wiley-VCH GmbH Copyright: Copyright 2021 Elsevier B.V., All rights reserved. Nanoparticle ass…

Facile synthesis of sustainable activated biochars with different pore structures as efficient additive-carbon-free anodes for lithium- and sodium-io…

2022

The present work elucidates facile one-pot synthesis from biomass forestry waste (Norway spruce bark) and its chemical activation yielding high specific surface area (SBET) biochars as efficient lithium- and sodium-ion storage anodes. The chemically activated biochar using ZnCl2 (Biochar-1) produced a highly mesoporous carbon containing 96.1% mesopores in its structure as compared to only 56.1% mesoporosity from KOH-activated biochars (Biochar-2). The latter exhibited a lower degree of graphitization with disordered and defective carbon structures, while the former presented more formation of ordered graphite sheets in its structure as analyzed from Raman spectra. In addition, both biochars…

Aqueous foam as the carrier phase in the deposition of fibre networks

2015

X-ray Computed Tomography for Capillary Collapse of Loose Unsaturated Sand

2016

Abstract The collapse of unsaturated soils consists of the reduction in volume upon wetting at constant total stress. Several studies at the macro scale outline the influence of initial void ratio, confining pressure and matric suction on the onset of collapse of standard laboratory specimens. Conversely, few observations at the micro scale are available in the literature, although the influence of the particles arrangement and intergranular bonding has been formerly supposed. The collapse of fine sand derived by a pyroclastic soil of Southern Italy is investigated in this paper at the microscale using the X-ray Computed Tomography. The experimental procedure, formerly tested on similar pyr…

Potassium μ-Hydrido-Bis[Pentacarbonylchromate(0)] and Potassium μ-Hydrido-Bis[Pentacarbonyltungstate(0)]

2007

Evaluation and comparison of tailor-made stationary phases based on spherical silica-based beads for capillary electrochromatography via peptide sepa…

2004

Small cyclic peptides have been employed to elucidate the performance of novel sorbents as stationary phases in capillary electrochromatography (CEC). In this paper chain length dependencies for ordinary liquid chromatographic sorbents are reported together with findings acquired on beads specifically designed to suit CEC. The latter, tailor-made, spherical, porous silica exhibits a distinguished surface modification to meet the criteria anticipated to enhance performance profiles in CEC. With well-characterised peptides resembling the analytes, probing of the CEC system in a systematic manner (predominantly via the organic modifier content of the background electrolyte (BE)) reveals insigh…