Search results for "POSS"
showing 10 items of 345 documents
Ethylene/POSS copolymerization behavior of postmetallocene catalysts and copolymer characteristics
2017
Copolymerization of ethylene with iso-butyl substituted monoalkenyl(siloxy)- or monoalkenylsilsesquioxane (POSS) comonomers over bis(phenoxy-imine) and salen-type titanium and zirconium catalysts was studied. It was found that the polyreaction performance was significantly depended by the kind of the catalyst and by the structure and concentration of POSS in the feed. The POSS comonomer was efficiently incorporated into the polymer chain at up to 0.2 mol %. The differences in the copolymer compositions as the functions of the catalyst kind and the POSS comonomer were observed, including the varied number-average sequence length of ethylene and unsaturated end groups, as determined by 1H NMR…
Structure-properties relationships of polyhedral oligomeric silsesquioxane (POSS) filled PS nanocomposites
2012
The polyhedral oligomeric silsesquioxane (POSS) additivated polystyrene (PS) based nanocomposites were pre- pared by melt processing and the structure-properties relationships of the POSS-PS systems were compared to those of the neat PS. In order to investigate the effect of these structural parameters on the final properties of the polymer nanocompos- ites, five different kinds of POSS samples were used, in particular, POSS with different inorganic cage and with different organic pendent groups. The rheological investigation suggests clearly that the POSS acts as a plasticizer and that the processability of the PS was positively modified. The affinity between the POSS samples and the PS ma…
Multi-functional polyhedral oligomeric silsesquioxane-functionalized carbon nanotubes for photo-oxidative stable Ultra-High Molecular Weight Polyethy…
2016
Abstract Nanohybrid (phPOSS- f -CNTs) based on Carbon Nanotubes (CNTs) and Phenyl Polyhedral Olygomenric Silsesquioxane (phPOSS) have been synthesized to be used as multifunctional filler for polymer nanocomposites. The success of the functionalization procedure has been demonstrated via accurate spectroscopic, spectrometric and thermo-gravimetric analyses. The results reveal that a large portion of phPOSS is covalently linked to CNTs, while a small amount of phPOSS remains physically adsorbed due to the strong interactions coming from π electron coupling between the CNTs and phenyl rings in phPOSS. Small amounts (1 wt.%) of phPOSS- f -CNTs have been dispersed in Ultra High Molecular Weight…
Copolymers of ethylene with monoalkenyl- and monoalkenyl(siloxy)silsesquioxane (POSS) comonomers – Synthesis and characterization
2017
Abstract The hybrid ethylene/POSS copolymers were obtained using the rac -Et(Ind) 2 ZrCl 2 catalyst activated by MAO. A series of monoalkenyl- and monoalkenyl(siloxy)silsesquioxanes derivatives with different structures of reactive alkenyl substituent and types of non-reactive groups attached to the T 8 POSS cage was used as comonomers. The kind and concentration of the POSS comonomer in the reaction feed as well as extended reaction time were found to strongly influence the catalyst efficiency and incorporation of POSS units into polymer chains. The comonomer reactivity was significantly dependent on the length of the alkenyl reactive substituent in the POSS molecule and it was highest for…
On the sure criticality of tasks in activity networks with imprecise durations
2002
BB; International audience; The notion of the necessary criticality (both with respect to path and to activity) of a network with imprecisely defined (by means of intervals or fuzzy intervals) activity duration times is introduced and analyzed. It is shown, in the interval case, that both the problem of asserting whether a given path is necessarily critical and the problem of determining an arbitrary necessarily critical path (more exactly, a subnetwork covering all the necessarily critical. paths) are easy. The corresponding solution algorithms are proposed. However, the problem. of evaluating whether a given activity is necessarily critical does not seem to be such. Certain conditions are…
Evolutionary multi-objective optimization algorithms for fuzzy portfolio selection
2016
Graphical abstractDisplay Omitted HighlightsWe consider a constrained three-objective optimization portfolio selection problem.We solve the problem by means of evolutionary multi-objective optimization.New mutation, crossover and reparation operators are designed for this problem.They are tested in several algorithms for a data set from the Spanish stock market.Results for two performance metrics reveal the effectiveness of the new operators. In this paper, we consider a recently proposed model for portfolio selection, called Mean-Downside Risk-Skewness (MDRS) model. This modelling approach takes into account both the multidimensional nature of the portfolio selection problem and the requir…
A fuzzy mathematical programming approach to the assessment of efficiency with DEA models
2003
In many real applications, the data of production processes cannot be precisely measured. This is particularly worrying when assessing efficiency with frontier-type models, such as data envelopment analysis (DEA) models, since they are very sensitive to possible data errors. For this reason, the possibility of having available a methodology that allows the analyst to deal with imprecise data becomes an issue of great interest in these contexts. To that end, we develop some fuzzy versions of the classical DEA models (in particular, the BCC model) by using some ranking methods based on the comparison of α-cuts. The resulting auxiliary crisp problems can be solved by the usual DEA software. We…
The Risk, the Real, and the Impossibility of Life
2017
The discourse of the Matrix not only wakes up philosophy from the slumber they are, but reflects the rise of fears which are proper of a culture, that manipulates anxieties to fix policies otherwise would be rejected. Basically, Neo is subject to an ethical dilemma which means that we are free to make the decision to live in a fake without suffering or in “the real of the dessert” as Morpheus put it. At this extent, if technology is used to protect humankind, Matrix evinces under some circumstances, it can oppress human beings when they renounce to their “free-will”. This chapter not only explored the limitations of the society of risks within liberal thought but taking into consideration t…
How and for whom does a positive affect intervention work in fibromyalgia: An analysis of mediators and moderators.
2019
Objectives: Psychological interventions designed to enhance positive affect are promising ways to promote adaptive functioning in people with chronic pain. However, few studies have addressed the efficacy of positive affect interventions in chronic pain populations and examined which patients can benefit more from them. The aim of the present study was to identify mediators and moderators of the best possible self intervention (BPS) in fibromyalgia patients.Methods: We used data from a previous randomized controlled trial that examined changes in pain interference, depression, self‐efficacy and quality of life after the BPS intervention.Results: Mediation analyses showed that depression med…
Przyjaciele Boga (gnostycy) – współdziałającymi w trudzie nabywania cnoty. Przyczynek do aretologii Klemensa Aleksandryjskiego
2012
Acquiring virtue, understood as a well-ordered personality, is connected with a considerable toil, as follows from the writings of Clement from Alexandria. Its source is to be ascribed, first of all, to the necessity of being true to God’s commandments, but also to overcoming discouragement caused by: the long-lasting process of its acquiring, the conviction of impossibility to achieve it, undertaking yet again the ceased “moral cultivation” or other appropriate actions not infrequently given up under the influence of the opinion of the environment. Therefore, the one who acquires virtue, is supported by a gnostic, a perfect Christian, filled with concern for others, who, thanks to his acqu…