Search results for "PRECIPITATION"

Irrigation water saving strategies in Citrus orchards: Analysis of the combined effects of timing and severity of soil water deficit

2021

[EN] The knowledge of the crop response to soil water deficit is essential to predict the actual crop water requirements under limited soil water conditions. The mathematical schematization of the crop response under RDI can allow identifying the exact irrigation timing. The threshold of soil water status below which crop transpiration decreases represents a key parameter for the water stress functions. The main objective of this paper was to investigate the effects of several RDI treatments, applied during the three stages of fruit growth, on soil-plant-water relations of drip-irrigated mandarin trees. Experiments were carried out in seven irrigation treatments: a control, irrigated at 125…

Early C3A hydration in the presence of different kinds of calcium sulfate.

2009

International audience; Hydration reactions of C3A with various amounts of calcium sulfate hemihydrate, gypsum or a mixture of two, were investigated by isothermal microcalorimetry, and a monitoring of the ionic concentrations of diluted suspensions. This study shows that sulfate type used modifies the early C3A-CaSO4 hydration products and the rate of this hydration. The fast initial AFm formation observed before ettringite precipitation in the C3A-gypsum system is avoided as soon as hemihydrate is present in the suspension. This was attributed to.higher super saturation degrees and then higher nucleation frequency with regard to the ettringite obtained in the presence of hemihydrate. More…

Climate and Pedoclimate of Italy

2013

In Chap. 2 , the role played by the factors of soil formation in Italy is examined by different authors. Edoardo Costantini, Maria Fantappie´ , and Giovanni L’Abate explore the potential strong influence of climate on soil nature and distribution. In spite of being placed in the middle of the temperate zone of the boreal hemisphere, the elongated shape of the Italian peninsula, stretching along 11 parallels in the middle of the Mediterranean sea, and the presence of two morphological barriers, the Alps and the Apennines, cause great local climatic variations, to an extent that they are much more important than means. In fact, long-term mean annual air temperature for the whole country is 12…

Carbanionic Polymerization: Kinetics and Thermodynamics

1989

For a kinetic analysis, the process of anionic polymerization has to be divided into at least three main reactions common to all types of polymerization (equations 1–3). I* denotes initiator, M monomer, Pi* and Pi′ an active or inactive polymer chain of degree of polymerization i, respectively, and X a terminating agent.

Solid-state polymerization of oxetanes. II. Investigation of the growth of the polymer phase as related to the mechanism of polymerization

1973

The radiation-induced solid-state polymerization of 3,3-bischloromethyloxetane (BCMO) was investigated by direct observation of the development of the morphology of the growing polymer phase in single crystals of the monomer. Electron microscopy shows that the polymerization gives rise to amorphous polymer in the first step. The polymer forms irregular platelets which aggregate into larger units without reflecting the crystalline order of the monomer. Subsequent to polymerization, the amorphous polymer crystallizes to the β-modification of poly-BCMO. If the partially polymerized crystals are extracted by solvents of the monomer, crystallization of the polymer is enhanced, and morphological …

1980

Using a bifunctional initiator such as the tetrameric dianion of α-methylstyrene for the anionic polymerization of methyl methacrylate the rate constant is found to increase with conversion approaching that observed with a monofunctional initiator while the tacticity of the polymers obtained changes from that of an almost ideally atactic to a highly syndiotactic polymer. The results are explained by the assumption of an intramolecular association of the two terminal ion pairs yielding a new active species and gradually dissociating with increasing degree of polymerization of the chain. Using a polymeric dianion of α-methylstyrene as an initiator the association phenomenon is not observed.

Some kinetic effects in the polymerization of 1,3,5-trioxane

1960

Study of nucleation-growth processes of ettringite, alone or in a tricalcium aluminate/calcium sulfate system

2019

Ettringite Ca6Al2(SO4)3(OH)12.26H2O is one of the main hydration products of cements but despite the importance of this compound for cement chemistry, laws governing its precipitation processes have been poorly studied. This PhD thesis was entirely focused on the study of ettringite and on its nucleation-growth mechanisms.Ettringite precipitation was first studied alone from supersaturated ionic solutions. Experiments were designed in order to study separately processes of nucleation and growth. The Classical Theory of Nucleation was applied and allowed the determination of the interfacial energy of ettringite. A global description of ettringite precipitation process has been suggested. It …

Precipitation and Calcination of High-Capacity LiNiO2 Cathode Material for Lithium-Ion Batteries

2020

This article presents the electrochemical results that can be achieved for pure LiNiO2 cathode material prepared with a simple, low-cost, and efficient process. The results clarify the roles of the process parameters, precipitation temperature, and lithiation temperature in the performance of high-quality LiNiO2 cathode material. Ni(OH)2 with a spherical morphology was precipitated at different temperatures and mixed with LiOH to synthesize the LiNiO2 cathode material. The LiNiO2 calcination temperature was optimized to achieve a high initial discharge capacity of 231.7 mAh/g (0.1 C/2.6 V) with a first cycle efficiency of 91.3% and retaining a capacity of 135 mAh/g after 400 cycles. These a…

A Tropical Archipelago

2017

The tropical maritime climate of the Philippines is marked by high temperature and abundant rainfall. The chapter first examines the major characteristics of the climate, dominated by the seasonal alternation of the Amihan and Habagat monsoons, leading to sharp differences between regions for their patterns of rainy seasons. Typhoons from the western Pacific hit the islands with brutal force, even if some years are more prone than others to the onslaught of tropical storms, depending on the general atmospheric circulation and the strength—or absence—of El Nino or La Nina. Typhoons not directly hitting the Philippines can still generate high levels of rainfall and enhance flooding, due to th…