Search results for "Particle size"

Overexpression of human hepatic lipase and ApoE in transgenic rabbits attenuates response to dietary cholesterol and alters lipoprotein subclass dist…

1999

Abstract —The effect of the expression of human hepatic lipase (HL) or human apoE on plasma lipoproteins in transgenic rabbits in response to dietary cholesterol was compared with the response of nontransgenic control rabbits. Supplementation of a chow diet with 0.3% cholesterol and 3.0% soybean oil for 10 weeks resulted in markedly increased levels of plasma cholesterol and VLDL and IDL in control rabbits as expected. Expression of either HL or apoE reduced plasma cholesterol response by 75% and 60%, respectively. The HL transgenic rabbits had substantial reductions in medium and small VLDL and IDL fractions but not in larger VLDL. LDL levels were also reduced, with a shift from larger, m…

Novel porous carbon packings in reversed-phase high-performance liquid chromatography

1980

Abstract Porous carbon packings of particle size 5–20 μm were prepared by calcination of purified active carbons and cokes having narrow size ranges. Highly efficient columns packed with 10-μm particles were obtained by means of the high-viscosity slurry technique, and exhibited about 3000 theoretical plates at 100 mm length and optimal eluent flow-rate. The loading of columns, θ0.1, was determined to be 25–50 μg of solute per gram of packing. Eluotropic series of solvents were found to be similar to those on pyrocarbon-modified carbons and silicas. The log k′ values for homologous compounds increased linearly with the hydrocarbonaceous surface area at constant eluent composition. Studies w…

Tailored syntheses of nanostructured silicas: Control of particle morphology, particle size and pore size

1998

Ordered mesoporous silicas with spherical morphology and average particle size in the range between 100 nm and 2 μm were synthesised according to two novel routes. Both synthesis routes used tetraethoxysilane, water, alcohol and aqueous ammonia for producing spherical silica beads. The porosity was created by adding two different kinds of pore structure directing agents to the starting solution: one was an n-alkyltrialkoxysilane which was covalently bonded to the silica framework, the other was an n-alkylamine which acted as a nonionic template. After calcination and post treatment the resulting particles showed a specific surface area up to 1000 m2 g-1, a specific pore volume of up to 0.8 …

Testing the shape-similarity hypothesis between partide-size distribution and water retention for sicilian soils

2012

Application of the Arya and Paris (AP) model to estimate the soil water retention curve requires a detailed description of the particlesize distribution (PSD) but limited experimental PSD data are generally determined by the conventional sieve-hydrometer (SH) method. Detailed PSDs can be obtained by fitting a continuous model to SH data or performing measurements by the laser diffraction (LD) method. The AP model was applied to 40 Sicilian soils for which the PSD was measured by both the SH and LD methods. The scale factor was set equal to 1.38 (procedure AP1) or estimated by a logistical model with parameters gathered from literature (procedure AP2). For both SH and LD data, procedure AP2 …

Electron microscopy of particles collected at Praia, Cape Verde, during the Saharan Mineral Dust Experiment: particle chemistry, shape, mixing state …

2011

A large field experiment of the Saharan Mineral Dust Experiment (SAMUM) was performed in Praia, Cape Verde, in January and February 2008. The aerosol at Praia is a superposition of mineral dust, sea-salt, sulphates and soot. Particles smaller than 500 nm are mainly mineral dust, mineral dust–sulphate mixtures, sulphates and soot–sulphate mixtures. Particles larger then 2.5 μm consist of mineral dust, sea-salt and few mineral dust–sulphate mixtures. A transition range exists in between. The major internal mixtures are mineral dust–sulphate and soot–sulphate. Mineral dust–sea-salt mixtures occur occasionally, mineral dust–soot mixtures were not observed. The aspect ratio was 1.3–1.4 for dry p…

2016

Abstract. Particle concentration measurements with underwing probes on aircraft are impacted by air compression upstream of the instrument body as a function of flight velocity. In particular, for fast-flying aircraft the necessity arises to account for compression of the air sample volume. Hence, a correction procedure is needed to invert measured particle number concentrations to ambient conditions that is commonly applicable to different instruments to gain comparable results. In the compression region where the detection of particles occurs (i.e. under factual measurement conditions), pressure and temperature of the air sample are increased compared to ambient (undisturbed) conditions i…

A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: a comparison of 17 ice nucleation measurement techniques

2015

Immersion freezing is the most relevant heterogeneous ice nucleation mechanism through which ice crystals are formed in mixed-phase clouds. In recent years, an increasing number of laboratory experiments utilizing a variety of instruments have examined immersion freezing activity of atmospherically relevant ice-nucleating particles. However, an intercomparison of these laboratory results is a difficult task because investigators have used different ice nucleation (IN) measurement methods to produce these results. A remaining challenge is to explore the sensitivity and accuracy of these techniques and to understand how the IN results are potentially influenced or biased by experimental param…

Single-particle characterization of ice-nucleating particles and ice particle residuals sampled by three different techniques

2015

Abstract. In the present work, three different techniques to separate ice-nucleating particles (INPs) as well as ice particle residuals (IPRs) from non-ice-active particles are compared. The Ice Selective Inlet (ISI) and the Ice Counterflow Virtual Impactor (Ice-CVI) sample ice particles from mixed-phase clouds and allow after evaporation in the instrument for the analysis of the residuals. The Fast Ice Nucleus Chamber (FINCH) coupled with the Ice Nuclei Pumped Counterflow Virtual Impactor (IN-PCVI) provides ice-activating conditions to aerosol particles and extracts the activated particles for analysis. The instruments were run during a joint field campaign which took place in January and …

Nitric acid trihydrate nucleation and denitrification in the Arctic stratosphere

2014

Abstract. Nitric acid trihydrate (NAT) particles in the polar stratosphere have been shown to be responsible for vertical redistribution of reactive nitrogen (NOy). Recent observations by Cloud–Aerosol Lidar with Orthogonal Polarization (CALIOP) aboard the CALIPSO satellite have been explained in terms of heterogeneous nucleation of NAT on foreign nuclei, revealing this to be an important formation pathway for the NAT particles. In state of the art global- or regional-scale models, heterogeneous NAT nucleation is currently simulated in a very coarse manner using a constant, saturation-independent nucleation rate. Here we present first simulations for the Arctic winter 2009/2010 applying a n…

Particle size distributions of currently used pesticides in a rural atmosphere of France

2013

This work presents first data on the particle size distributions of current-used pesticides in the atmosphere. Ambient air samples were collected using a cascade impactor distributed into four size fractions in a rural site of Centre Region (France). Most pesticides were accumulated in the fine (0.1-1 mu m) particle size fraction such as cyprodinil, pendimethalin, fenpropidin, fenpropimorph and spiroxamine. Other pesticides such as acetochlor and metolachlor presented a bimodal distribution with maximum concentrations in the ultrafine (0.03-0.1 mu m) coarse (1-10 mu m) and in the ultrafine fine size ranges, respectively. No pesticides were detected in the size fraction >10 mu m. (C) 2013 El…