Search results for "Peat"
showing 10 items of 1026 documents
The effects of using participatory working time scheduling software on working hour characteristics and wellbeing : a quasi-experimental study of irr…
2020
Background: Studies in the health care sector indicate that good work time control is associated with better perceived wellbeing but also with non-ergonomic work schedules, such as compressed work schedules. Participatory working time scheduling is a collaborative approach to scheduling shift work. Currently, there is a lack of information on whether working hour characteristics and employees' wellbeing in irregular shift work change after implementing participatory working time scheduling. Objective: To investigate the effects of using digital participatory working time scheduling software on working hour characteristics and well-being among Finnish hospital employees. Participants and met…
Manual packing and soil reuse effects on determination of saturated hydraulic conductivity of a loam soil
2022
Abstract Performing laboratory measurement of saturated hydraulic conductivity, Ks, of sieved soil is important for many scientific purposes such as testing theories and methods to determine Ks. A given soil mass can be used only once or it can be reused after a previous use. Little is known on the dependence of the Ks measurements on both the applied packing method and the reuse of the same soil mass. This lack of knowledge makes comparisons among different investigations more or less uncertain. Four packing methods were tested on an initially dry loam soil by measuring Ks with the simplified falling head (SFH) technique. The four methods differed by the used compacting procedure (dropping…
Assessing the MALDI-TOF MS sample preparation procedure to analyze the influence of thermo-oxidative ageing and thermo-mechanical degradation on poly…
2011
[EN] Multiple processing by means of successive injection cycles was used to simulate the thermo-mechanical degradation effects on the oligomeric distribution of PLA under mechanical recycling. Likewise, an accelerated thermal ageing over PLA glass transition was performed in order to simulate its service life. MALDI-TOF MS was used for the analysis and the sample preparation procedure was assessed by means of a statistical Design of Experiments (DoE). The quality effects in use for the analysis were signal-to-noise ratio and Resolution. Different matrixes, analyte/matrix proportions and the use of NaTFA as cationization agent were considered. A deep inspection of the statistical results pr…
Modified magnetic-based solvent-assisted dispersive solid-phase extraction: application to the determination of cortisol and cortisone in human saliv…
2021
A modification of magnetic-based solvent-assisted dispersive solid-phase extraction (M-SA-DSPE) has been employed for the determination of the biomarkers cortisol and cortisone in saliva samples. M-SA-DSPE is based on the dispersion of the sorbent material by using a disperser solvent like in dispersive solid phase extraction (SA-DSPE) but a magnetic sorbent is used like in magnetic dispersive solid-phase extraction (M-DSPE). Thus, the magnetic sorbent containing the target analytes is retrieved using an external magnet like in M-DSPE. Finally, the analytes are desorbed into a small volume of organic solvent for the subsequent chromatographic analysis. To this regard, a M-SA-DSPE-based meth…
A novel peat-based biosorbent for the removal of phosphate from synthetic and real wastewater and possible utilization of spent sorbent in land appli…
2015
AbstractRemoval of potentially harmful phosphorus compounds from wastewater by adsorption onto biosorbents is a cost-effective alternative to the conventional treatment methods. Raw peat and peat modified with iron(III) hydroxy ions were used in this study to remove phosphate ions from synthetic solution and household wastewater. Interaction of iron(III) ions with carboxylic groups of peat occurred during peat modification, which was confirmed by the FTIR technique. The effect of the initial phosphate concentration, pH, contact time, temperature, and ionic strength was studied in batch experiments. It was found that the sorption capacity increased with the increasing temperature, i.e. the m…
Characterizing a hybrid zone between a cryptic species pair of freshwater snails.
2015
Characterizing hybrid zones and their dynamics is a central goal in evolutionary biology, but this is particularly challenging for morphologically cryptic species. The lack of conspicuous divergence between parental types means intermediate hybrid forms often go undetected. We aimed to detect and characterize a suspected hybrid zone between a pair of morphologically cryptic lineages of the freshwater snail, Radix. We sampled Radix from across a contact zone between two mitochondrial lineages (Radix balthica and an undescribed lineage termed 'MOTU3') and detected admixture between two nuclear genotype clusters, which were significantly but not categorically associated with the mitochondrial …
Data repeatability and acquisition techniques for Time-Domain Spectral Induced Polarization
2013
The Time Domain Induced Polarization (TDIP) technique is widely used in applied geophysics, particularly for environmental issues, for instance for delineating landfills or detecting leachate percolation. Because the reliability of IP data remains an issue at the field scale, this paper deals with the factors controlling data quality and compares different arrays and acquisition parameters for optimal collection of data in the field. The first part focuses on repeatability experiments carried out in the former Horlokke landfill (Denmark), in order to infer the degree of which a signal can be reproduced over time. Results show a good repeatability, with on average less than 10% of difference…
Identification of Three-Way DNA Junction Ligands through Screening of Chemical Libraries and Validation by Complementary in Vitro Assays
2019
International audience; The human genome is replete with repetitive DNA sequences that can fold into thermodynamically stable secondary structures such as hairpins and quadruplexes. Cellular enzymes exist to cope with these structures whose stable accumulation would result in DNA damage through interference with DNA transactions such as transcription and replication. Therefore, the chemical stabilization of secondary DNA structures offers an attractive way to foster DNA transaction-associated damages to trigger cell death in proliferating cancer cells. While much emphasis has been recently given to DNA quadruplexes, we focused here on three-way DNA junctions (TWJ) and report on a strategy t…
Simultaneous screening and quantification of aminoglycoside antibiotics in honey using mixed-mode liquid chromatography with quadrupole time-of-fligh…
2018
An analytical method based on liquid chromatography with quadrupole time-of-flight mass spectrometry has been developed for the simultaneous determination of six aminoglycoside antibiotics in honey. The sample pretreatment included extraction with aqueous trichloroacetic acid followed by solid-phase extraction on Strata-X polymeric reversed phase cartridges. Liquid chromatography separation was performed on an Obelisc R zwitterionic type mixed-mode column. An ionBooster™ heated electrospray source was used and showed enhanced ionization efficiency in comparison to a conventional electrospray source. The observed signal enhancement ranged from 3- (neomycin) to 16-fold (gentamicin C1). A data…
New perspectives on diastereoselective determination of hexabromocyclododecane traces in fish by ultra high performance liquid chromatography-high re…
2014
a b s t r a c t A new analytical method is presented for diastereoisomer-specific identification and quantitation of hexabromocyclododecanes (HBCD) in fish samples. The method is based on extraction of the target analytes from samples with a mixture of organic solvents, with further three-stage clean-up includ- ing destructive removal of matrix components with sulphuric acid and acid-impregnated silica gel, and Florisil adsorption column chromatography. Ultra high performance liquid chromatography (UPLC) cou- pled with high resolution (HR) Orbitrap mass spectrometry featuring heated electrospray ionization (HESI-II) interface operated in negative ion mode was employed for the identification…