Search results for "Penning trap"
showing 10 items of 297 documents
Photodissociation of small group-11 metal cluster ions: Fragmentation pathways and photoabsorption cross sections
2003
Noble metal cluster ions Cu(n)(+), Ag(n)(+) and Au(n)(+) (n = 3-21) have been stored in a Penning trap and photodissociated by low intensity laser pulses of 10 ns at photon energies of 3.49 eV and 4.66 eV. The fragmentation pathways, neutral monomer and dimer evaporation, have been monitored as a function of cluster size, excitation energy and element. It is found that the behavior of the branching ratio between monomer and dimer evaporation as a function of excitation energy depends on the metal under investigation. In particular, the slope of the energy dependence is positive for silver but negative for gold and copper cluster ions. Furthermore, photoabsorption cross sections are determin…
Fragmentation pattern of gold clusters collided with xenon atoms
1994
Abstract The dissociation channels of gold cluster ions Au n + (2 ≤ n ≤ 23) have been investigated via collision induced dissociation in a Penning trap. Excited odd cluster ions with n ≤ 15 decay by evaporation of dimers, all others decay by monomer evaporation. Information on the binding energies is deduced from these dissociation channels.
Photo fragmentation of metal clusters stored in a penning trap
1996
Photo fragmentation studies of stored mass selected metal cluster ions of a large size range are reported. The experimental method and the data evaluation are described in detail. Gold cluster ions were produced by laser vaporization and stored in a Penning trap. After size selection they were electronically excited by irradiation with a pulsed laser beam. Relaxation by evaporation of neutral atoms and dimers was observed as a function of photon energy. From these data upper and lower limits for dissociation energies are determined for Aun + (n=3 to 23).
Electron impact ionization/dissociation of size selected gold cluster cations
2000
Abstract Singly charged gold clusters, Au n + in the size range n =12 to 72 have been captured and stored in a Penning trap, size selected and subjected to an electron beam. This interaction leads to further ionization as well as dissociation. The resulting abundance spectra of doubly and triply charged clusters show (a) a lower size limit for the production of multiply charged clusters from an ensemble of hot precursors, which can be understood in terms of the respective decay pathways, (b) an odd/even alternation of singly and doubly charged clusters in the size range below n =30, which inverses sign with change of charge state, and (c) magic numbers, i.e. prominent signals for particular…
Au n+-induced decomposition of N2O
1994
Reactions between small gold cluster ions, Au, and N2O were studied in a Penning trap mass spectrometer. Gold clusters were produced by laser vaporization and injected into a Penning trap. After reaction times of 50–7000ms the products were detected by time-of-flight mass spectrometry. For the major reaction channel, Au + N2OAu1,2N + NO+, rates of (0.9±0.1)×10−12 cm3 s−1 and (2.4±0.4)×10−12 cm3 s−1 were determined which are about a factor 500 below the collision rate. The corresponding activation energies for N2O decomposition were estimated to lie below 0.6 eV and 0.3 eV. Additional products with small branching ratios were detected, viz. the ions Au1O+, Au1N2O+, Au2N+, Au2NO+, Au2N2O+, Au…
High-precision mass measurements for fundamental applications using highly-charged ions with SMILETRAP
2007
The Penning trap mass spectrometer SMILETRAP takes advantage of highly-charged ions for high-accuracy mass measurements. In this paper recent mass measurements on Li and Ca ions are presented and their impact on fundamental applications discussed, especially the need for accurate mass values of hydrogen-like and lithium-like ions in the evaluation of the electron g-factor measurements in highly-charged ions is emphasized. Such experiments aim to test bound state quantum electrodynamics. Here the ionic mass is a key ingredient, which can be the limiting factor for the final precision.
High-precision Penning-trap mass measurements of heavy xenon isotopes for nuclear structure studies
2009
With the double Penning-trap mass spectrometer ISOLTRAP at ISOLDE/CERN the masses of the neutron-rich isotopes $^{136\ensuremath{-}146}\mathrm{Xe}$ were measured with a relative uncertainty of the order of ${10}^{\ensuremath{-}8}$ to ${10}^{\ensuremath{-}7}$. In particular, the masses of $^{144\ensuremath{-}146}\mathrm{Xe}$ were measured for the first time. These new mass values allow one to extend calculations of the mass surface in this region. Proton-Neutron interaction strength, obtained from double differences of binding energies, relate to subtle structural effects, such as the onset of octupole correlations, the growth of collectivity, and its relation to the underlying shell model l…
Space-Charge Effects with REXTRAP
2001
The beam quality of radioactive ion beams produced by present target ion source technology is often not sufficient for direct post-acceleration. Furthermore, pulsed beams insure a more efficient use of an accelerator. In the case of REX-ISOLDE, the post accelerator at the CERN ISOLDE facility, a gas-filled Penning trap (REXTRAP) has been chosen for accumulation of the radioactive ions and conversion into cooled bunches. Radial centering of the ions is achieved by applying an rf field with a frequency equal to the cyclotron frequency of the desired ion species. The efficiency achieved in the first tests with different isotopes covering nearly the entire mass range was already >20%. Going to …
Time Characteristics of the Ion Beam Cooler-Buncher at JYFL
2001
A beam cooler for low-energy ion beams was constructed to improve the ion optical properties of radioactive ion beams produced at the IGISOL facility in Jyvaskyla. The beam cooler is a buffer gas filled RF-quadrupole. The delay properties and the possibility to accumulate a continuous IGISOL beam and release it in short bunches is discussed.
Accelerating Radioactive Ion Beams With REX-ISOLDE
2003
The post accelerator REX‐ISOLDE is installed at the ISOLDE facility at CERN, where a broad variety of radioactive ions can be addressed. Since the end of 2001 beams at the final energy of 2.2 MeV/u are available. REX‐ISOLDE uses a unique system of beam bunching and charge breeding. First a Penning trap accumulates and bunches the ions, which are delivered as a quasi‐continuous beam from the ISOLDE target‐ion‐source, and then an electron beam ion source (EBIS) charge‐breeds them to a mass‐to‐charge ratio below 4.5. This enables a very compact design for the following LINAC, consisting of a 4 rod RFQ, an IH structure and three 7‐gap‐resonators. The later ones allow a variation of the final en…