Search results for "Phonon"
showing 10 items of 466 documents
Raman scattering and infrared reflectivity in [(InP)5(In0.49Ga0.51As)8]30 superlattices
2000
6 páginas, 6 figuras, 1 tabla.
Discovery of new boron-rich chalcogenides: Orthorhombic B6X (X=S, Se)
2020
The authors thank T. Chauveau (LSPM) for help with Rietveld analysis, A. Jamali (LRCS) for assistance with SEM measurements, and Drs. Y. Tange (SPring-8) and N. Guignot (SOLEIL) for help in synchrotron experiments that were carried out during beamtimes allocated to proposals 2017A1047 & 2018A1121 at SPring-8 and proposal 20170092 at SOLEIL. Ab initio calculations have been performed using Rurik and Arkuda supercomputers. This work was financially supported by the European Union’s Horizon 2020 Research and Innovation Programme under Flintstone2020 project (grant agreement No. 689279). Z.W. thanks the National Science Foundation of China (grant No. 11604159). A.R.O. thanks the Russian Ministr…
Structural and vibrational properties of CdAl2S4 under high pressure: Experimental and theoretical approach
2014
The behavior of defect chalcopyrite CdAl2S4 at high pressures and ambient temperature has been investigated in a joint experimental and theoretical study. High-pressure X-ray diffraction and Raman scattering measurements were complemented with theoretical ab initio calculations. The equation of state and pressure dependences of the structural parameters of CdAl2S4 were determined and compared to those of other AB(2)X(4) ordered-vacancy compounds. The pressure dependence of the Raman-active mode frequencies is reported, as well as the theoretical phonon dispersion curves and phonon density of states at 1 atm. Our measurements suggest that defect chalcopyrite CdAl2S4 undergoes a phase transit…
Phonon-induced optical superlattice
2005
We demonstrate the formation of a dynamic optical superlattice through the modulation of a semiconductor microcavity by stimulated acoustic phonons. The high coherent phonon population produces a folded optical dispersion relation with well-defined energy gaps and renormalized energy levels, which are accessed using reflection and diffraction experiments.
Influence of a nano phase segregation on the thermoelectric properties of the p-type doped stannite compound Cu(2+x)Zn(1-x)GeSe4.
2012
Engineering nanostructure in bulk thermoelectric materials has recently been established as an effective approach to scatter phonons, reducing the phonon mean free path, without simultaneously decreasing the electron mean free path for an improvement of the performance of thermoelectric materials. Herein the synthesis, phase stability, and thermoelectric properties of the solid solutions Cu_(2+x)Zn_(1–x)GeSe_4 (x = 0–0.1) are reported. The substitution of Zn^(2+) with Cu^+ introduces holes as charge carriers in the system and results in an enhancement of the thermoelectric efficiency. Nano-sized impurities formed via phase segregation at higher dopant contents have been identified and are l…
Hydration entropy of BaZrO3 from first principles phonon calculations
2015
The impact of phonons on the hydration and defect thermodynamics of undoped and acceptor (Sc, In, Y and Gd) doped BaZrO3 is addressed by means of first principles supercell calculations. In contrast to previous, similar investigations, we evaluate contributions from all phonon modes, and also pressure/volume effects on the phonon properties. The calculations are performed at the GGA-level with the PBE and RPBE functionals, both of which predict for BaZrO3 a stable cubic perovskite structure. For all dopants, the vibrational formation entropy of the doubly positively charged oxygen vacancy is significantly lower than that of the protonic defect , which therefore also is the dominant contribu…
Existence of two time scales in the phase transitions of BaTiO3
1991
Abstract We report new Raman scattering measurements in the tetragonal phase of a single domain BaTiO3 crystal. Data reveal the occurence of a large quasi elastic scattering. The Raman profile is analysed in terms of coexisting soft phonon and Debye relaxation.
Microscopic calculation of the LSP detection rates for the 71Ga, 73Ge and 127I dark-matter detectors
2004
Abstract We have investigated the nuclear-structure details of the cross sections for the elastic scattering of Lightest Supersymmetric Particles (LSPs) from the promising dark-matter detectors 71 Ga, 73 Ge and 127 I. The associated LSP detection sensitivities have been obtained by a folding procedure for several recently proposed SUSY models with different scalar and axial-vector characteristics. For the nuclear problem, a realistic microscopic Hamiltonian has been used within realistic model spaces. The diagonalization of this Hamiltonian has been done by using the Microscopic Quasiparticle–Phonon Model (MQPM), suitable for description of spectroscopic properties of medium-heavy and heavy…
Proton-Hydrogen Charge Exchange and Elastic Scattering in the Faddeev Approach
2000
Results of the application of Faddeev-type integral equations to proton-hydrogen collisions are reported. The approach, realized in the impact parameter representation, incorporates the exact two-particle off-shell Coulomb T-matrices in all ‘triangle’ contributions to the effective potentials. Calculatedtotal and differential electron-transfer as well as differential elastic scattering cross sections show very good agreement with experiment, over a wide range of incident energies.
Investigation of acceptor levels and hole scattering mechanisms in p-gallium selenide by means of transport measurements under pressure
1997
The effect of pressure on acceptor levels and hole scattering mechanisms in p-GaSe is investigated through Hall effect and resistivity measurements under quasi-hydrostatic conditions up to 4 GPa. The pressure dependence of the hole concentration is interpreted through a carrier statistics equation with a single (nitrogen) or double (tin) acceptor whose ionization energies decrease under pressure due to the dielectric constant increase. The pressure effect on the hole mobility is also accounted for by considering the pressure dependencies of both the phonon frequencies and the hole-phonon coupling constants involved in the scattering rates.