Search results for "Phosphane"

showing 10 items of 79 documents

CCDC 1578509: Experimental Crystal Structure Determination

2018

Related Article: Florian Chotard, Raluca Malacea-Kabbara, Cédric Balan, Ewen Bodio, Michel Picquet, Philippe Richard, Miguel Ponce-Vargas, Paul Fleurat-Lessard, Pierre Le Gendre|2018|Organometallics|37|812|doi:10.1021/acs.organomet.7b00851

Space GroupCrystallographyCrystal Systemdichloro-((cyclohepta-35-dien-1-yl)(diphenyl)phosphane)-(ethyl benzoate)-ruthenium(ii) toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 827095: Experimental Crystal Structure Determination

2012

Related Article: P.Farras, F.Teixidor, I.Rojo, R.Kiveks, R.Sillanpaa, P.Gonzalez-Cardoso, C.Vinas|2011|J.Am.Chem.Soc.|133|16537|doi:10.1021/ja205850p

Space GroupCrystallographyCrystal Systemtetramethylammonium (33'-commo-11'-((phenyl)phosphane sulfide)-bis(3-cobalta-12-dicarba-closo-dodecaborate))Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1532063: Experimental Crystal Structure Determination

2017

Related Article: Benedict Kemper, Maximilian von Gröning, Vanessa Lewe, Daniel Spitzer, Tobias Otremba, Natascha Stergiou, Dieter Schollmeyer, Edgar Schmitt, Bart Jan Ravoo, Pol Besenius|2017|Chem.-Eur.J.|23|6048|doi:10.1002/chem.201700588

Space GroupCrystallography[3-(13-dioxo-133a477a-hexahydro-2H-47-epoxyisoindol-2-yl)prop-1-yn-1-yl]-(triphenylphosphane)-gold(i)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1978440: Experimental Crystal Structure Determination

2020

Related Article: Sarah Keller, Alessandro Prescimone, Maria-Grazia La Placa, José M. Junquera-Hernández, Henk J. Bolink, Edwin C. Constable, Michele Sessolo, Enrique Ortí, Catherine E. Housecroft|2020|RSC Advances|10|22631|doi:10.1039/D0RA03824E

Space GroupCrystallography[oxybis(21-phenylene)]-bis(diphenylphosphane)-(456-trimethyl-22'-bipyridine)-copper(i) hexafluorophosphate diethyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2193619: Experimental Crystal Structure Determination

2022

Related Article: Araceli de Aquino, Jas S. Ward, Kari Rissanen, Gabriel Aullón, João Carlos Lima, Laura Rodríguez|2022|Inorg.Chem.|61|20931|doi:10.1021/acs.inorgchem.2c03351

Space GroupCrystallography{mu-[([11'-biphenyl]-22'-diyl)bis(diphenylphosphane)]}-bis(99-dimethyl-9H-fluoren-2-yl)-di-goldCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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A Discrete P⋅⋅⋅II⋅⋅⋅P Assembly: The Large Influence of Weak Interactions on the31P NMR Spectra of Phosphane–Diiodine Complexes

2006

Thioethers, except derivatives of [7-R-7,8-C2B9H11] , are more weakly coordinating ligands than phosphanes. This difference is evidenced by the I I distances in the spokeshaped charge-transfer (CT) complexes R2S·I2 and R3P·I2 (Figure 1). The I I distance is sensitive to the strength of the interaction between the s* LUMO orbital on I2 and the HOMO orbital of the donor atom: the stronger the donor, the longer the I I distance. In these spoke CT complexes, the I I distance varies from 3.2 0.2 7 in R3P·I2 adducts [5] to 2.80 0.05 7 in R2S·I2 adducts, [6] indicating the weaker donor character of the thioether group. Whereas extended I2 arrays, spoke adducts of I2, polyiodides, and other structu…

StereochemistryInteractionsPhosphanes010402 general chemistry01 natural sciencesCatalysisAdductPolyiodidechemistry.chemical_compoundThioetherMoleculeNon-covalent interactionsCarboranesHOMO/LUMOchemistry.chemical_classificationiodine010405 organic chemistryChemistryLigandStructure elucidationGeneral MedicineGeneral ChemistryNoncovalent0104 chemical sciencesChemistryCarboraneAngewandte Chemie International Edition
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Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

1997

P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.

Structure analysisDiphospheneStereochemistryOrganic ChemistryDiphosphenesBiochemistryInorganic Chemistrychemistry.chemical_compoundchemistryFerroceneComputational chemistryMaterials ChemistryDiphosphaneReactivity (chemistry)Physical and Theoretical ChemistryJournal of Organometallic Chemistry
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CCDC 142589: Experimental Crystal Structure Determination

2001

Related Article: T.Grob, G.Seybert, W.Massa, F.Weller, R.Palaniswami, A.Greiner, K.Dehnicke|2000|Angew.Chem.,Int.Ed.|39|4373|doi:10.1002/1521-3773(20001201)39:23<4373::AID-ANIE4373>3.0.CO;2-K

bis(mu~2~-Triphenylphosphaneiminato)-tetrakis(triphenylphosphaneiminato)-diytterbiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1824417: Experimental Crystal Structure Determination

2020

Related Article: Lucia Volbach, Niklas Struch, Fabian Bohle, Filip Topić, Gregor Schnakenburg, Andreas Schneider, Kari Rissanen, Stefan Grimme, Arne Lützen|2020|Chem.-Eur.J.|26|3335|doi:10.1002/chem.201905070

catena-[(mu-[tricyclo[8.2.2.247]hexadeca-1(12)46101315-hexaene-512-diyl]bis(isocyano))-((propane-13-diyl)bis(diphenylphosphane))-palladium bis(trifluoromethanesulfonate) acetonitrile solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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ChemInform Abstract: A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading.

2010

The present new catalyst system can be used for the direct arylation of various heteroaromatic compounds at low palladium loadings.

chemistry.chemical_compoundTriphosphanechemistrychemistry.chemical_elementGeneral MedicineCombinatorial chemistryThiophene derivativesPyrrole derivativesCatalysisPalladiumChemInform
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