Search results for "Phosphate"

showing 10 items of 1874 documents

Thermokinetic Investigation of the Drying Conditions on Amorphous Calcium Phosphate

2017

The present work investigated dried calcium phosphate powders which still retain an amorphous or poorly crystalline structure under a variety of conditions. In previous studies, freeze-drying was found to be the optimum drying condition. However, several publications, as well as our previous studies, have shown that calcium phosphate amorphous, or a poorly crystalline structure, can retain their structure even if the samples are dried immediately after synthesis up to 200°C. In our study, we used the thermokinetic studies FTIR and XRD and showed that the samples are amorphous, or poorly crystalline, but were unable to answer the questions: Is there a difference between the differently dried…

0303 health sciencesChemistryMechanical EngineeringInorganic chemistry02 engineering and technologyActivation energy021001 nanoscience & nanotechnologyArrhenius plot03 medical and health sciencesMechanics of MaterialsGeneral Materials ScienceAmorphous calcium phosphate0210 nano-technologyFtir pas030304 developmental biologyKey Engineering Materials
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Hidden complexity in membrane permeabilization behavior of antimicrobial polycations.

2021

A promising alternative to classical antibiotics are antimicrobial peptides and their synthetic mimics (smAMPs) that supposedly act directly on membranes. For a more successful design of smAMPs, we need to know how the type of interaction with the membrane determines the type of membrane perturbation. How this, in turn, transfers into selectivity and microbial killing activity is largely unknown. Here, we characterize the action of two smAMPs: MM:CO (a copolymer of hydrophobic cyclooctyl subunits and charged β-monomethyl-α-aminomethyl subunits) and the highly charged poly-NM (a homopolymer of α-aminomethyl subunits). By thorough characterization of vesicle leakage experiments, we elucidate …

0303 health sciencesMembrane permeabilizationChemistryVesicleKineticsAntimicrobial peptidesStatic ElectricityGeneral Physics and Astronomy010402 general chemistryAntimicrobialFluoresceins01 natural sciencesPermeability0104 chemical sciences03 medical and health sciencesMembraneGlycerophosphatesBiophysicsPhysical and Theoretical ChemistryHydrophobic and Hydrophilic InteractionsUnilamellar Liposomes030304 developmental biologyLeakage (electronics)Antimicrobial Cationic PeptidesProtein BindingPhysical chemistry chemical physics : PCCP
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Effect of iron chelates on oil–water interface, stabilized by milk proteins: The role of phosphate groups and pH. Prediction of iron transfer from aq…

2010

International audience; Iron incorporated into food systems induces oxidation and precipitation. The consequences are reduced bioavailability and a functional modification of other food components such as proteins. The iron-chelates such as ferrous bisglycinate represent a possibility to avoid side effects, since the iron is protected. The aim of this study is to investigate the effects of iron-chelates compounds on the properties of an oil/water interface stabilized by caseinate or β-lacotoglobulin, under environmental conditions at 20 °C. Analyses were performed using dynamic drop tensiometry during 5000 s. The aqueous bulk phase is an imidazole/acetate buffer (0.1 M), containing 0.4 × 10…

030309 nutrition & dieteticsGeneral Chemical EngineeringInorganic chemistryIron fortificationSurface tension03 medical and health scienceschemistry.chemical_compound0404 agricultural biotechnologyOil-in-water emulsion[SDV.IDA]Life Sciences [q-bio]/Food engineeringChelationBeta-lactoglobulin2. Zero hunger0303 health sciencesAqueous solutionChromatographybiologyChemistryAqueous two-phase systemEmulsifying activityProteins04 agricultural and veterinary sciencesGeneral ChemistryPhosphate040401 food scienceEmulsionPhosphate groupsbiology.proteinChemical stabilityFood ScienceFood Hydrocolloids
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CCDC 1023704: Experimental Crystal Structure Determination

2014

Related Article: Anssi Peuronen, Heikki Rinta, Manu Lahtinen|2015|CrystEngComm|17|1736|doi:10.1039/C4CE01866D

11'-hexane-16-diylbis(4-diiodaniumyl-14-diazoniabicyclo[2.2.2]octane) bis(hexafluorophosphate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Studies to Elucidate the Mechanism of Cardio Protective and Hypotensive Activities of Anogeissus acuminata (Roxb. ex DC.) in Rodents

2020

Anogeissus acuminata (Roxb. ex DC.) is a folkloric medicinal plant in Asia

1Pharmaceutical Scienceacute myocardial infarction 3030204 cardiovascular system & hematologyPharmacologyCreatineAnalytical ChemistryNitric oxidelcsh:QD241-44103 medical and health scienceschemistry.chemical_compound0302 clinical medicinevasorelaxant 4lcsh:Organic chemistryIn vivoDrug DiscoveryRenin–angiotensin systemleft ventricular hypertrophy 2Physical and Theoretical ChemistryCyclic guanosine monophosphate030304 developmental biology0303 health sciencesbiologyOrganic ChemistryAngiotensin-converting enzymehypotensivechemistryChemistry (miscellaneous)biology.proteinMolecular MedicineCreatine kinasehistopathology 6cardio relaxant 5Ex vivoMolecules
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CCDC 879937: Experimental Crystal Structure Determination

2013

Related Article: A.Peuronen, A.Valkonen, M.Kortelainen, K.Rissanen, M.Lahtinen|2012|Cryst.Growth Des.|12|4157|doi:10.1021/cg300669t

1-Octyl-4-aza-1-azoniabicyclo[2.2.2]octane hexafluorophosphate diiodoSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 879938: Experimental Crystal Structure Determination

2013

Related Article: A.Peuronen, A.Valkonen, M.Kortelainen, K.Rissanen, M.Lahtinen|2012|Cryst.Growth Des.|12|4157|doi:10.1021/cg300669t

1-Octyl-4-aza-1-azoniabicyclo[2.2.2]octane hexafluorophosphate diiodoSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Structural analysis of Cu(II) ligation to the 5'-GMP nucleotide by pulse EPR spectroscopy.

2007

JBIC Journal of Biological Inorganic Chemistry, 12 (6)

10120 Department of ChemistryConformational change1303 BiochemistryAnalytical chemistryGuanosine MonophosphateLigandsBiochemistrylaw.inventionInorganic Chemistrycopper; electron-nuclear double resonance; hyperfine sublevel correlation spectroscopy; pulse electron paramagnetic resonance spectroscopy; nucleotidelaw540 ChemistryOrganometallic CompoundsDNA Z-FormElectron paramagnetic resonanceHyperfine structurehyperfine sublevel correlation spectroscopyElectron nuclear double resonanceMolecular StructurePulsed EPRChemistryLigand1604 Inorganic ChemistryElectron Spin Resonance SpectroscopyDNAnucleotideSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)CrystallographyUnpaired electronpulse electron paramagnetic resonance spectroscopyNucleic Acid Conformationelectron-nuclear double resonanceTwo-dimensional nuclear magnetic resonance spectroscopyCopperJournal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry
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Interaction of Novel Metal Complexes with DNA: Synthetic and Structural Aspects

2009

Metal ions bind to nucleic acids at various positions. This binding can be modulated by using metal complexes with appropriate ligands. Novel mono- and especially dinuclear metal complexes could be a powerful tool to detect rare, but still physiologically relevant, forms of DNA, e.g. the left-handed Z-DNA. In this review, our recent research activities in this area of bioinorganic chemistry are summarized. A special emphasis is laid on the synthetic challenges that arose upon the synthesis of the polyamine ligands. Further, some rather unusual approaches to elucidate the solution structure of copper bound to guanosine monophosphate with the help of pulsed EPR techniques like ENDOR and HYSC…

10120 Department of ChemistryMono- and dinuclear metal complexesMetal ions in aqueous solutionand dinuclear metal complexes1600 General ChemistrydnaBioinorganic chemistryZ-DNAMetalchemistry.chemical_compoundMono- and Dinuclear Metal ComplexeGuanosine monophosphate540 ChemistryQD1-999Pulsed EPRCrystal structureBioinorganic chemistryGeneral MedicineGeneral ChemistryZ-DNACombinatorial chemistrySettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Chemistrychemistryvisual_artCrystal structuresNucleic acidvisual_art.visual_art_mediumMonoSynthetic ChemistryDNAZ
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CCDC 1901898: Experimental Crystal Structure Determination

2023

Related Article: Antti J. Neuvonen, Dimitris Noutsias, Filip Topić, Kari Rissanen, Tamás Földes, Imre Pápai, Petri M. Pihko|2019|J.Org.Chem.|84|15009|doi:10.1021/acs.joc.9b01980

2-[({2-[2-({[35-bis(trifluoromethyl)phenyl]carbamoyl}amino)-4-(trifluoromethyl)phenoxy]-23-dihydro-1H-inden-1-yl}carbamothioyl)amino]-NN-dimethylcyclohexan-1-aminium diphenyl phosphate toluene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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