Search results for "Photoluminescent"

showing 5 items of 5 documents

Interplay between spin-crossover and luminescence in a multifunctional single crystal iron( ii ) complex: towards a new generation of molecular senso…

2019

Multifunctional mononuclear iron( ) complex coordinated with six phosphorescent ligands exhibiting correlated spin-crossover transition and enhanced fluorescence.

Coordination spherePhotoluminescenceMaterials scienceSpin statesMolecular SensorsPhotoluminescentSpin transition[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry01 natural sciencesSpin crossover[CHIM]Chemical SciencesIron complex010405 organic chemistrydigestive oral and skin physiologyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistry0104 chemical sciencesChemistrySynergyChemical physicsHigh spin and Low spinSpin Cross-OverLight emissionLuminescenceSingle crystal
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Efficient photoluminescent thin films consisting of anchored hybrid perovskite nanoparticles

2016

Methylammonium lead bromide nanoparticles are synthetized with a new ligand (11-aminoundecanoic acid hydrobromide) by a non-template method. Upon dispersion in toluene they show a remarkable photoluminescence quantum yield of 80%. In addition, the bifunctional ligand allows anchoring of the nanoparticles on a variety of conducting and semiconducting surfaces, showing bright photoluminescence with a quantum yield exceeding 50%. This opens a path for the simple and inexpensive preparation of multilayer light-emitting devices. NRF (Natl Research Foundation, S’pore) ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version

Materials sciencePhotoluminescencePhotoluminescent Thin FilmsPerovskite NanoparticlesInorganic chemistryNanoparticleQuantum yield02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundMaterials ChemistryThin filmBifunctionalPerovskite (structure):Materials [Engineering]LigandMetals and AlloysGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsChemical engineeringchemistryCeramics and Composites0210 nano-technologyDispersion (chemistry)Chemical Communications
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Photoluminescent hybrid nanomaterials from modified halloysite nanotubes

2018

The synthesis of photoluminescent nanomaterials based on halloysite nanotubes is described. The obtained hybrid was characterized by means of TGA, FT-IR, DLS and XPS measurements; in addition its morphology was imaged by TEM and HR-TEM. The HNT hybrid also exhibited photoluminescent properties, both in solution and in the solid state, and white-light emission (0.24, 0.36; CIE coordinates) was observed. This work could be pioneering as a new strategy for manufacturing both LEDs and fluorescent tags based on HNT nanomaterials. © 2018 The Royal Society of Chemistry.

PhotoluminescenceMaterials scienceHalloysite nanotubeSolid-statehalloysite nanotubes hybrid nanomaterials photoluminescent propertiesNanotechnology02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesHalloysitelaw.inventionNanomaterialsX-ray photoelectron spectroscopylawKaolinitePhoto-luminescent propertieMaterials ChemistryXPS measurements Nanostructured materialsYarn CIE coordinateWhite light emissionGeneral Chemistry021001 nanoscience & nanotechnologyFluorescence0104 chemical sciencesNanotubeengineering0210 nano-technologyHybrid nanomaterialLight-emitting diodeJournal of Materials Chemistry C
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Photoluminescence of Carbon Dots Embedded in a SiO2 Matrix

2016

Abstract We synthetized carbon dots by a pyrolitic method, and studied their photoluminescence in aqueous environment and upon trapping in a solid matrix. To this aim, we devised a facile procedure allowing to embed the dots in amorphous SiO2, without the need of any pre-functionalization of the nanoparticles, and capable of yielding a brightly photoluminescent monolith. Experimental data reveal a remarkable similarity between the emission properties of carbon dots in water and in SiO2, suggesting that the chromophores responsible of the photoluminescence undergo only weak interactions with the environment. Time-resolved photoluminescence data reveal that the typical photoluminescence tunab…

PhotoluminescenceMaterials sciencePhotoluminescent nanocarbonAnalytical chemistryNanoparticlechemistry.chemical_element02 engineering and technologyTrapping010402 general chemistry01 natural sciencesCarbon dots; Photoluminescent nanocarbons; Photoluminescent silica monolith; Time-resolved photoluminescence; Materials Science (all)Photoluminescence excitationMonolithgeographygeography.geographical_feature_categorybusiness.industryChromophore021001 nanoscience & nanotechnologyCarbon dot0104 chemical sciencesAmorphous solidchemistryOptoelectronicsPhotoluminescent silica monolithMaterials Science (all)0210 nano-technologybusinessCarbonTime-resolved photoluminescence
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Optimisation of photoluminescent painting treatments on different surface layers

2016

Improving drivers visibility in night time conditions is vital. Night-time visibility represents one of the most important features of road safety. Within such context, the use of photoluminescent road markings could represent an enhancement with regard to road safety. Consequently, the objective of the investigation here described was confined into the analysis of photoluminescent paints by referring to dense-graded and open-graded friction courses. Measurements, based on photometry technique, were carried out in the laboratory. Cores extracted from the surface layer of known pavements were used. Transitory effects (charge and discharge) and decay phenomena were investigated and modelled a…

dense-graded open-graded friction courses and photoluminescent pavement
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