Search results for "Plastics"
showing 10 items of 2724 documents
Synergistic effects of Janus particles and triblock terpolymers on toughness of immiscible polymer blends
2017
Abstract By influencing both the interfacial adhesion and the morphology, compatibilizers determine the mechanical properties of polymer blends. Here, we study the mechanical properties, in particular the fatigue crack propagation (FCP) of immiscible blends of poly(2,6-dimethyl-1,4-phenylene ether)/poly(styrene- co -acrylonitrile) (PPE/SAN), compatibilized with Janus nanoparticles (JPs) and linear polystyrene- block -polybutadiene- block -poly(methyl methacrylate) (SBM) triblock terpolymers. Synergistic effects of a mixture of both compatibilizers improve the FCP behavior and reveal the important role of interface stiffness and flexibility on the mechanical properties of polymer blends. The…
Darstellung einiger oligomerer Cyclo{oligo[(2-hydroxy-1,3-phenylen)methylen]}e. Spektroskopische Untersuchung ihrer Pseudorotation
1978
Es wird die Darstellung von Cyclo{tris[(2-hydroxy-5-methyl-1,3-phenylen)methylen]-(2-hydroxy-5-tert-butyl-1,3-phenylen)methylen} (4a), Cyclo{bis[(2-hydroxy-5-methyl-1,3-phenylen)methylen]-bis[(2-hydroxy-5-tert-butyl-1,3-phenylen)methylen]}(4b) und Cyclo-{pentakis[(2-hydroxy-5-methyl-1,3-phenylen)methylen]} (4c) beschrieben. Die IR-Spektren zeigen, das die phenolischen Hydroxygruppen der Vierringverbindungen 4a und 4b intramolekulare, vom Losungs(CCl4)- oder Zerteilungsmittel (KBr) weitgehend unabhangige Wasserstoffbrucken bilden, die bei der pentameren Ringverbindung 4c schwacher sind. Anhand der 1H-NMR-Spektren last sich bei diesen Verbindungen eine Pseudorotation nachweisen. Die Massenspe…
Dynamic mechanical properties of semi-interpenetrating networks based on poly(styrene-co-maleic anhydride)
1991
Semi-interpenetrating networks based on linear anionic polystyrene (PS) and poly(styrene-co-maleic anhydride) P(ScoMA) of low MA content are prepared by crosslinking the P(ScoMA) with 4,4′-diphenylmethanediamine (DPMDA). It is demonstrated by dynamic mechanical analysis and by DSC that immiscible semi-IPN's are obtained for MA contents greater 5 wt.-%. In miscible semi-IPN's the relaxation of free PS chains is observed as a second maximum in the loss tangent at higher temperatures. The position of this maximum is shifted to higher temperatures for a polystyrene of molecular weight 500000 compared to a polystyrene of molecular weight 150000. The experimental temperature shift is in good agre…
A comparative study on Kθ evaluation from [η]-M data in single and mixed solvents through various excluded volume theories
1991
Abstract By allowing for the dependence of B on molecular weight, through its relationship with A2, modified Flory-Fox-Schaefgen, Kurata-Stockmayer-Roig, Berry and Inagaki-Suzuki-Kurata equations are obtained, relating [η] to A2 and to Kθ. Through these equations, Kθ can be determined from data sets for [η]-A2. Because of the scarcity of these data sets, A2 values have been calculated from experimental data for [η] and trial Kθ values through two parameter theories, namely, through the Flory-Krigbaum-Orofino theory for Ψ. Iterative processes were followed until coincidence was obtained between trial Kθ values and those evaluated from the modified excluded volume equations. The method has be…
Synthesis of Ultra-High-Molecular-Weight Polyethylene
1984
The catalytic activity of organometallic Ti-Al complexes with donor ligands in the low-pressure polymerization of ethylene was studied. These complexes were obtained by the reaction of ethylaluminium compounds like AlEt2Cl or Al2Et3Cl3 and titanium compound of the type Ti(OR)nCl4-n (where: R = C2—C10 alkyl, C6H5, C6H4X; X — m-CH3, p-CH3, m-OCH3, p-OCH3, m-Cl, p-Cl, p-Br; n = 1—4). The optimum conditions for the synthesis of these compounds, as well as their physico-chemical properties were studied by means of EPR and polarographic methods. The effect of the type and number of OR ligands in a catalytic system on the yield of polyethylene and on its properties was examined. Ti-Al catalysts wi…
Elastic Deformation of Dispersely Failing Unidirectionally Reinforced Composites
2003
A phenomenological model is proposed for describing the elastic deformation of a unidirectionally reinforced composite capable of accumulating scattered microdamages during its loading. The composite is considered as a homogeneous transversely isotropic solid. Its damaged state at every point is characterized by a centrally symmetric scalar function on the unit sphere (the damage function), which is used to account for variations in the elastic properties of the material during its deformation. The damage itself depends on the history of some equivalent strain, for which four simplified variants are suggested. The relation between strains and stresses is defined in a differential form. Depe…
Deformation of Polypropylene Foam Neopolen® P in Compression
2004
Neopolen® P is a two-phase cellular composite foam material produced by BASF AG, Germany. In most of the practical applications, Neopolen® P works under a range of small and compressive deformations. Therefore it is necessary to determine the moduli in compression and compressive strength in the most effective way for a wide range of foam densities: 22≤ρ84≤kg/m3. Several experimental methods of different precision for deformation properties of Neopolen® P were compared. The direct measurements performed by a universal testing machine were used for the main part of the experiments. They were compared with results obtained by a more precise and time-consuming method, using an inductive exten…
On the Role of Internationalization of Firm-Level Corporate Governance – The Case of Audit Committees
2020
Motivated by agency theory and arguments from linguistic studies, we argue in this paper the internationalization of a firm’s audit committee to be associated with weaker firm-level corporate governance. Based on 2,015 publicly traded European firms from 16 countries over 2000-2018, we find the presence of foreign directors on audit committees to have a significant negative impact on financial reporting quality (FRQ). The effect is found to be weaker in countries with strong investor protection. We find linguistic differences within audit committees an important explanation for the negative influence of foreign directors on FRQ. The results are robust to alternative FRQ measures and model s…
Julio Cervera Baviera. Republicano y masón de Vicent Sampedro Ramo
2016
<p class="western" style="margin-bottom: 0in; line-height: 100%;" lang="es-ES" align="justify"><span style="font-size: small;">Doctor por la Univesitat de València (2003) en el Departament d'Història Contemporània. Profesor Ayudante Doctor en el Departament de Didàctica de les Ciències Experimentals i Socials, Facultat de Magisteri de la Universitat de València, España</span></p>
Slow Crystallization Kinetics of Poly(vinyl alcohol) in Confined Environment during Cryotropic Gelation of Aqueous Solutions
2006
The gelation kinetics of aqueous solutions of poly(vinyl alcohol) (PVA) during freezing at −13 °C has been investigated with time-resolved small angle neutron scattering. Crystallization of PVA takes place inside an unfrozen liquid microphase that forms in the matrix of ice crystals and follows a first-order kinetics during the early stages and becomes very slow in the later stages with an apparent Avrami exponent lower than 1. Crystallization of PVA at low temperatures is responsible of formation of strong physical gels upon defrosting, provided that the concentration of PVA is higher than a critical value.