Search results for "Polar"
showing 10 items of 3817 documents
Demo 98. Péndulo electrostático
2013
Objetivo: Detectar la presencia de cargas eléctricas con materiales sencillos.
Demo 21. Cuerpos cargados y el electroscopio
2013
Objetivo: Mostrar la carga de objetos por fricción, mediante el uso de un instrumento clásico como el electroscopio, en el que se pone de manifiesto la fuerza electrostática y la conservación de la carga.
Observatory science with eXTP
2019
Disponible preprint en: arXiv:1812.04023v1 [astro-ph.HE] [v1] Mon, 10 Dec 2018 19:00:52 UTC (4,376 KB)
Measurement of three-dimensional mirror parameters by polarization imaging applied to catadioptric camera calibration
2008
International audience; We present a new efficient method for calibration of cata- dioptric sensors. The method is based on an accurate measurement of the three-dimensional parameters of the mirror through polariza- tion imaging. While inserting a rotating polarizer between the cam- era and the mirror, the system is automatically calibrated without any calibration patterns. Moreover, this method permits most of the constraints related to the calibration of catadioptric systems to be relaxed. We show that, contrary to our system, the traditional meth- ods of calibration are very sensitive to misalignment of the camera axis and the symmetry axis of the mirror. From the measurement of three-di…
DC01 steel corrosion resistance in cathodic polarization
2016
Celem prowadzonych badań było okreœlenie odporności korozyjnej stali DC01 poddanej katodowej polaryzacji w zmiennych warunkach. Elektrochemiczne pomiary służące do oceny odpornoœci korozyjnej stali nienawodorowanej poddanej katodowej polaryzacji przeprowadzono metodami obejmującymi pomiar potencjału obwodu otwartego i zarejestrowania zależności i=f(E) podczas badań polaryzacyjnych w trójelektrodowym układzie pomiarowym. Do pomiarów wykorzystano układ składający się z naczynka pomiarowego, potencjostatu AMEL PSW01 System 5000 oraz komputera z oprogramowaniem „CorrWare”. Wodorowanie stali zrealizowano w wodnym roztworze 0,1 N kwasu siarkowego(VI) z dodatkiem 2 mg/dm3 tlenku arsenu(III) jako p…
Alle radici del popolarismo.Lo Cascio, Sturzo, Traina
2014
La Sicilia, considerata “l’anello più debole dello sviluppo capitalistico italiano”, fu all’avanguardia per la costruzione della cultura del popolarismo. Essa affonda le sue radici in quel movimento democratico cristiano che in Sicilia, sin dal suo esordio, si distingue per una spiccata propensione all’autonomia, sia nel campo politico-elettorale, sia in quello economico-sociale. Tale inclinazione, a detta dei democratici cristiani, avrebbe favorito il rinnovamento culturale, una maggiore libertà d’azione per la risoluzione dei problemi della società e, avrebbe consentito ai cattolici un inserimento e una presenza più incisiva nella realtà sociale e politica della nazione.
The influence of CH bond polarization on the self-association of 2-acylaminopyrimidines by NH/CH···O/N interactions: XRD, NMR, DFT, and AIM study
2013
The single crystal structures of two 2-acylaminopyrimidines, where alkyl groups in acyl moiety are iso-propyl (1) and dichloromethyl (2), were solved by X-ray diffraction method. The strength of intermolecular hydrogen bonding interactions depends on the C–H bond polarization increased by exchanging two methyl groups by chlorine atoms in the adjacent substituent. The computational methods provide an additional insight into the intermolecular interactions and are utilized in explaining the differences in the observed crystal structures. The experimental and computational data together explain the differences in the formed aggregates and revealed that these simple substitutions cause crucial …
Synthesis of conformationally restricted 1,2,3-triazole-substituted ethyl β- and γ-aminocyclopentanecarboxylate stereoisomers. Multifunctionalized al…
2010
Abstract Stereoisomers of 1,2,3-triazole-functionalized, conformationally restricted β- or γ-amino esters with a cyclopentane skeleton were efficiently synthetized from the bicyclic β-lactam 6-azabicyclo[3.2.0]hept-3-en-7-one (1) and Vince γ-lactam (15) in five or six steps involving the azide–alkyne 1,3-dipolar cycloaddition of azido-substituted amino ester stereoisomers with nonsymmetric acetylenes. The azide–alkyne click reactions were investigated under thermal and Cu(I)-catalyzed conditions. Surprisingly, the thermally induced cycloaddition furnished the corresponding 1,4-triazoles regioselectively, which also took place selectively in response to Cu(I) catalysis.
Towards highly luminescent phenylene vinylene films
1996
Abstract Fluorescence and electronic absorption spectra, fluorescence decay curves and fluorescence quantum yields of a series of oligo (p-phenylene vinylenes) are investigated in solution, nanoaggregates and vapour-deposited or cast ultrathin films. The film constituting molecules are varied in chain length and modified by electron donating and withdrawing substituents and bulky alkyl spacers. PPP-MO calculations serve to rationalize the resulting spectral changes. In dilute solutions, fluorescence yields of the short oligomers with alkyl or oxyalkyl substituents approach the region of unity. The yields decrease with chain length, reaching a long-chain limit of ΦF=0.4–0.7. Introduction of …
An analysis of the regioselectivity of 1,3-dipolar cycloaddition reactions of benzonitrile n-oxides based on global and local electrophilicity and nu…
2009
The regioselectivity of the 1,3-dipolar cycloaddition (13DC) reactions of benzonitrile N-oxides (BNOs) with electrophilic and nucleophilic alkenes has been analyzed by using global and local nucleophilicity and electrophilicity reactivity indices defined within the conceptual DFT. The BNOs react with electron-deficient and electron-rich ethylenes, but the regioselectivities of these polar reactions are different. Whereas the reactions with electron-rich ethylenes are completely regioselective, yielding 5-isoxazolines, a change in the regioselectivity is observed in the reactions with electron-deficient ethylenes, which yield a mixture of 4- and 5-isoxazolines. Analysis of the energies, geom…