Search results for "Polarizability"
showing 10 items of 240 documents
Electrons on a spherical surface: Physical properties and hollow spherical clusters
2012
We discuss the physical properties of a noninteracting electron gas constrained to a spherical surface. In particular we consider its chemical potentials, its ionization potential, and its electric static polarizability. All these properties are discussed analytically as functions of the number $N$ of electrons. The trends obtained with increasing $N$ are compared with those of the corresponding properties experimentally measured or theoretically evaluated for quasispherical hollow atomic and molecular clusters. Most of the properties investigated display similar trends, characterized by a prominence of shell effects. This leads to the definition of a scale-invariant distribution of magic n…
Field-free permanent molecular planar alignment
2009
We show the existence of a permanent molecular planar alignment in field-free conditions. We present different control strategies using shaped laser pulses to reach this state. The strategies are robust with respect to the temperature and can be implemented with the state of the art technology. They can be applied not only to linear molecules but also to symmetric or asymmetric top molecules along the most polarizable molecular axis. We propose potential applications of this planar alignment such as the increase of the adsorption on a surface.
Development of the Hamiltonian and transition moment operators of symmetric top molecules using the O(3)⊃C∞v⊃C3v group chain
2005
Abstract We present a development of the Hamiltonian, dipole moment, and polarizability operators for XY3Z molecules. These rovibrational operators are written with the aid of a tensorial formalism derived from the one already used in Dijon and adapted to the XY3Z symmetric tops in a recent paper [A. El Hilali, V. Boudon, M. Loete, J. Mol. Spectrosc. 234 (2005) 166–174]. We use the O (3) ⊃ C∞v ⊃ C3v group chain. Expressions for the matrix elements are derived for these operators.
Spectroscopy of XY5Z (C4v) Molecules: Development of the Hamiltonian and the Transition Moment Operators Using a Tensorial Formalism
2000
We present a development of the Hamiltonian, dipole moment, and polarizability operators of XY(5)Z (C(4v)) molecules using a tensorial formalism derived from the one developed previously in Dijon for XY(6) molecules. These operators are involved in the calculation of the energies and intensities of rovibrational transitions and are essential for spectrum simulations. Expressions for the matrix elements are derived for all these operators. Copyright 2000 Academic Press.
Radiative Pion Photoproduction from the Proton and π + Meson Polarizabilities
1995
We study the possibility of investigating radiative pion photoproduction from the proton at the microtron MAMI-B with the aim to obtain an experimental information about the π + meson polarizabilities. It is shown that an exposition time of about 30 days will allow to determine the π + meson polarizability with quite high accuracy.
Compton scattering off nucleons near threshold
2008
The energy dependence of the magnetic polarizability β has been evaluated by use of the delta resonance in the s- and u-channel of the Compton scattering amplitude. It was the idea to extract the influence of higher order terms (higher than ω2, ω = |k| being the photon energy) in the analysis of the polarizability. The static paramagnetic polarizability βPara(0) has been substituted by an energy dependent βδPara(k) and the result is compared with experimental data.
Polarizabilities of small annulenes from Cholesky CC2 linear response theory
2004
Using recently developed algorithms based on Cholesky decomposition of two-electron integrals to compute response properties at the correlated level, the static and dynamic (at 589 nm) polarizabilities of [4n + 2]-annulenes (n = 1, 2, 3, 4) have been calculated. The results show that the perpendicular component increases along the series linearly with the number of double bonds. The in-plane static polarizability is also increasing linearly with the area of the aromatic ring in the case of the delocalized species. However, linearity is lost for the localized conformations and for the dynamic polarizability. (C) 2004 Elsevier B.V. All rights reserved.
Screening of positrons in semiconductors and insulators
1989
Theoretical models are presented for the enhancement of the electron density at a positron in a semiconductor or insulator host. The model better suited for typical semiconductors is based on the many-body theory for the screening of a positron in electron gas. The starting point of the model for insulators is the atomic polarizability. The common parameter in both models is the high-frequency dielectric constant. Moreover, the enhancement depends on the ambient electron density in the semiconductor model and on the unit-cell volume in the insulator model. With use of the models developed, positron lifetimes in perfect semiconductor and insulator crystals have been calculated. In the calcul…
Highly transparent and birefringent chromophores for organic photorefractive materials
1999
Abstract A series of chromophores for application in organic photorefractive (PR) materials is investigated by electro-optical absorption measurements (EOAM). This experimental technique yields information on the transition dipole moment μ ag , the ground-state dipole moment μ g , and the change of the dipole moment upon optical excitation Δ μ within the intense charge transfer (CT) band of the dyes. It is shown that the results of the EOAM experiment allow us to estimate the PR figures-of-merits (FOMs) of the chromophores by either perturbational two-level equations or Kramers–Kronig transformation. In particular, chromophores based on the heterocyclic dihydropyran and dihydropyridine grou…
Theoretical investigation of electronic excitation energy transfer in bichromophoric assemblies.
2008
Electronic excitation energy transfer (EET) rates in rylene diimide dyads are calculated using second-order approximate coupled-cluster theory and time-dependent density functional theory. We investigate the dependence of the EET rates on the interchromophoric distance and the relative orientation and show that Forster theory works quantitatively only for donor-acceptor separations larger than roughly 5 nm. For smaller distances the EET rates are over- or underestimated by Forster theory depending on the respective orientation of the transition dipole moments of the chromophores. In addition to the direct transfer rates we consider bridge-mediated transfer originating from oligophenylene un…