6533b831fe1ef96bd129905e

RESEARCH PRODUCT

Field-free permanent molecular planar alignment

Stéphane GuérinDominique SugnyEdouard HertzM. Lapert

subject

PhysicsSurface (mathematics)[ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph]Field (physics)business.industryLinear molecular geometryMolecular axisLaser01 natural sciencesMolecular physicsAtomic and Molecular Physics and Optics010305 fluids & plasmaslaw.inventionPlanar[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]Polarizabilitylaw0103 physical sciencesMoleculeOptoelectronics010306 general physicsbusiness[PHYS.QPHY] Physics [physics]/Quantum Physics [quant-ph]ComputingMilieux_MISCELLANEOUS

description

We show the existence of a permanent molecular planar alignment in field-free conditions. We present different control strategies using shaped laser pulses to reach this state. The strategies are robust with respect to the temperature and can be implemented with the state of the art technology. They can be applied not only to linear molecules but also to symmetric or asymmetric top molecules along the most polarizable molecular axis. We propose potential applications of this planar alignment such as the increase of the adsorption on a surface.

https://doi.org/10.1103/physreva.80.051403