Search results for "Polyethylene"
showing 10 items of 809 documents
2014
NanosizedCeO2powders were synthesized via hydrothermal method with different types of surfactants (polyethylene glycol (PEG), cetyltrimethylammonium bromide (CTAB), and sodium dodecylbenzenesulfonate (SDBS)). X-ray diffraction, Raman spectroscopy, and transmission electron microscopy were utilized to characterize the phase structures and morphologies of the products. The sample with CTAB as surfactant (CeO2-C) has the largest specific surface area and the smallest particle size among these three samples. The humidity sensor fabricated byCeO2-C shows higher performance than those usedCeO2-P andCeO2-S. The impedance of theCeO2-C sensor decreases by about five orders of magnitude with relative…
From the solution processing of hydrophilic molecules to polymer-phthalocyanine hybrid materials for ammonia sensing in high humidity atmospheres.
2014
We have prepared different hybrid polymer-phthalocyanine materials by solution processing, starting from two sulfonated phthalocyanines, s-CoPc and CuTsPc, and polyvinylpyrrolidone (PVP), polyethylene glycol (PEG), poly(acrylic acid-co-acrylamide) (PAA-AM), poly(diallyldimethylammonium chloride) (PDDA) and polyaniline (PANI) as polymers. We also studied the response to ammonia (NH3) of resistors prepared from these sensing materials. The solvent casted films, prepared from s-CoPc and PVP, PEG and PAA-AM, were highly insulating and very sensitive to the relative humidity (RH) variation. The incorporation of s-CoPc in PDDA by means of layer-by-layer (LBL) technique allowed to stabilize the fi…
Viscoelastic material models for more accurate polyethylene wear estimation
2018
Wear debris from ultra-high-molecular-weight polyethylene components used for joint replacement prostheses can cause significant clinical complications, and it is essential to be able to predict implant wear accurately in vitro to prevent unsafe implant designs continuing to clinical trials. The established method to predict wear is simulator testing, but the significant equipment costs, experimental time and equipment availability can be prohibitive. It is possible to predict implant wear using finite element methods, though those reported in the literature simplify the material behaviour of polyethylene and typically use linear or elastoplastic material models. Such models cannot represe…
Wavelength-Selective Softening of Hydrogel Networks.
2021
Photoresponsive hydrogels hold key potential in advanced biomedical applications including tissue engineering, regenerative medicine, and drug delivery, as well as intricately engineered functions such as biosensing, soft robotics, and bioelectronics. Herein, the wavelength-dependent degradation of bio-orthogonal poly(ethylene glycol) hydrogels is reported, using three selective activation levels. Specifically, three chromophores are exploited, that is, ortho-nitrobenzene, dimethyl aminobenzene, and bimane, each absorbing light at different wavelengths. By examining their photochemical action plots, the wavelength-dependent reactivity of the photocleavable moieties is determined. The wavele…
Ruthenium-Containing Block Copolymer Assemblies: Red-Light-Responsive Metallopolymers with Tunable Nanostructures for Enhanced Cellular Uptake and An…
2015
The use of self-assembled nanostructures consisting of red-light-responsive Ru(II)-containing block copolymers (BCPs) for anticancer phototherapy is demonstrated. Three Ru-containing BCPs with different molecular weights are synthesized. Each BCP contains a hydrophilic poly(ethylene glycol) block and an Ru-containing block. In the Ru-containing block, more than half of the side chains are coordinated with [Ru(2,2':6',2''-terpyridine)(2,2'-biquinoline)](2+) , resulting in more than 40 wt% Ru complex in the BCPs. The Ru complex acts as both a red-light-cleavable moiety and a photoactivated prodrug. Depending on their molecular weights, the BCPs assemble into micelles, vesicles, and large comp…
Advancements in Sustainable PVDF Copolymer Membrane Preparation Using Rhodiasolv® PolarClean As an Alternative Eco-Friendly Solvent
2021
In this work, Rhodiasolv® PolarClean was employed as a more sustainable solvent for the preparation of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) flat sheet membranes via phase inversion technique by coupling vapour induced phase separation (VIPS) and non-solvent induced phase separation (NIPS) processes. Preliminary calculations based on Hansen solubility parameters well predicted the solubilization of the polymer in the selected solvent. The effect of exposure time on humidity and the influence of polyethylene glycol (PEG), polyvinyl pyrrolidone (PVP) and sulfonated polyether sulfone (S-PES) on membrane properties and performance, were evaluated. Three different coagulation …
Shear characterization of CaCO3-filled linear low density polyethylene
1988
Shear properties of CaCO3-filled linear low density polyethylene have been determined over a wide range of filler loading. The viscosity rises with the filler loading especially at low shear rates and a yield value appears for CaCO3-contents larger than 5%. The decrease of the die-swell ratios of the filled samples indicates a reduction of the melt elasticity.
Laboratory and in-situ tests for estimating improvements in asphalt concrete with the addition of an LDPE and EVA polymeric compound
2019
Abstract Pavement deformation is a critical issue in the design of pavement structures and the related mixture. Asphalt concretes may be very sensitive to this problem, in compliance with the viscoelastic behaviour of the adopted bitumen. To improve the material performance, many attempts have been made to introduce in the mixture other materials as “modifiers” or “additives” for increasing the permanent deformation resistance and the elastic modulus of the material. Among the different possible materials, polymers determined significant improvements in the road pavement performance. In this paper, the authors tested the adoption of a specifically engineered polymeric compound, in order to …
Liquid/Liquid Demixing in the System n-Hexane/Narrowly Distributed Linear Polyethylene
2004
Demixing conditions were measured visually for solutions of three narrowly distributed polyethylene samples (M ranging from 6.5 to 380 kg/mol) in n-hexane up to 500 K and 150 bar. This information yields the critical line for infinite molar mass; i.e., it specifies the pT area within which one is safe from phase separation irrespective of the molar mass of the polymer and of the composition of the mixture. The experimental findings are in good qualitative agreement with the predictions of the Sanchez−Lacombe theory applied without any adjustable parameters. The influences of molar masses are, however, underestimated, and the resulting critical compositions are too small. For a more quantita…
Rheological properties and morphology in LLDPE and PC based blends
1990
Abstract During an interlaboratory project on polymer blends (Technical Working Party-Polymer Blends-VAMAS), the rheological characteristics of some samples of blends of polycarbonate with linear low density polyethylene have been evaluated with the aid of a capillary rheometer. Some morphological observations on the extruded samples have also been performed through SEM and an attempt has been made to correlate the macroscopic and microscopic results.