Search results for "Porous medium"
showing 10 items of 164 documents
Computational Modeling of Protein Dynamics in Eukaryotic Cells
2012
Proteins have important functions inside the cell, traveling diffusively or being actively transported to various cellular sites where their activity is needed. Protein motion in the cellular environment is therefore an important topic to understand. However, the cell provides a very complex environment for that motion, which poses problems especially for any modeling effort designed to interpret experimentally observed features. So as to gain a realistic picture of protein dynamics inside the cell, we have recently introduced advanced numerical methods for describing that dynamics [1]. The starting point is an accurate numerical duplicate of the cell determined by LSCM, which can be used a…
Acoustical properties of air-saturated porous material with periodically distributed dead-end pores
2015
International audience; A theoretical and numerical study of the sound propagation in air-saturated porous media with straight main pores bearing lateral cavities (dead-ends) is presented. The lateral cavities are located at " nodes " periodically spaced along each main pore. The effect of periodicity in the distribution of the lateral cavities is studied, and the low frequency limit valid for the closely spaced dead-ends is considered separately. It is shown that the absorption coefficient and transmission loss are influenced by the viscous and thermal losses in the main pores as well as their perforation rate. The presence of long or short dead-ends significantly alters the acoustical pro…
Gravity-Driven Infiltration and Subsidence Phenomena in Posidonia oceanica Residues
2019
A simplified infiltration model for highly permeable porous media was introduced, assuming the matric potential gradient as negligible compared to the gravitational gradient. This model enabled us to determine the delay time, i.e., the time that the water front takes (from the beginning of rainfall) to reach the bottom of the highly permeable layer. Posidonia oceanica (Linnaeus) Delile residues were used as a porous media, in order to study the infiltration process that provides salt leaching under natural rainfall when these residues are arranged in a storage area, before reusing. By using a laboratory rainfall simulator, delay times were measured to verify the applicability of the aforeme…
Reactive thiol-ene emulsion-templated porous polymers incorporating pentafluorophenyl acrylate
2013
Abstract Highly porous polymers (polyHIPEs) incorporating activated esters have been prepared by photopolymerisation of high internal phase emulsions (HIPEs) containing pentafluorophenyl acrylate (PFPA) in the monomer phase. The resulting materials have nominal porosity of 80% and a well-defined, interconnected pore morphology with average pore diameters ranging from 30 to 50 μm. PFPA could be added at up to 50 wt% of the monomer phase without destabilising the HIPE noticeably, however analysis of the polyHIPE materials revealed that only around half of this was incorporated into the final porous materials. The pentafluorophenyl groups were shown to be reactive towards a range of amines (tr…
Selective CO 2 Sorption Using Compartmentalized Coordination Polymers with Discrete Voids**
2021
Carbon capture and storage with porous materials is one of the most promising technologies to minimize CO2 release into the atmosphere. Here, we report a family of compartmentalized coordination polymers (CCPs) capable of capturing gas molecules in a selective manner based on two novel tetrazole-based ligands. Crystal structures have been modelled theoretically under the Density Functional Theory (DFT) revealing the presence of discrete voids of 380 A3 . Single gas adsorption isotherms of N2 , CH4 and CO2 have been measured, obtaining a loading capacity of 0.6, 1.7 and 2.2 molecules/void at 10 bar and at 298 K for the best performing material. Moreover, they present excellent selectivity an…
Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks
2017
The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal-organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparency. Herein, we report the first example of a MOF with bicyclic organic dicarboxylic linkers and its use as a solid solvent.
Heads or Tails? Sandwich-Type Metallo Complexes of Hexakis(2,3-di-O-methyl)-α-cyclodextrin
2020
Native and synthetically modified cyclodextrins (CDs) are useful building blocks in the construction of large coordination complexes and porous materials with various applications. Sandwich-type co...
The importance of fracture-healing on the deformation of fluid-filled layered systems
2014
International audience; Understanding the fracturingehealingerefracturing cycle is a fundamental part of studying the deformation dynamics and the permeability evolution of rock systems. Previous studies, however, have not examined the influence of healing i.e. fracture-closure through vein formation and the mechanical properties of the " healed " fractures (veins) on the rock deformation. We present results from a two-dimensional coupled hydro-mechanical model which simulates large time and spatial scale dynamic fracturing and healing of a porous medium under the influence of gravity, tectonic stretching and elevated fluid pressures. Our results show that healing decreases the local porosi…
Flow of turbulent superfluid helium inside a porous medium
2009
The work deals with further developments of a study previously initiated, in which a macroscopic model of inhomogeneous superfluid turbulence, based on extended thermodynamics, has been formulated. The model choose as fundamental fields, beside the traditional fields, two extra variables: the averaged vortex line length per unit volume and the heat flux. Using this model the propagation of the fourth sound inside a superleak is investigated: it is shown that, if the configuration of the vortex tangle inside the superleak are not altered -on the average- by the presence of the walls, when the fourth sound is propagated, vibrations in the vortex line density are present, too.
Characterization of microscopic disorder in reconstructed porous materials and assessment of mass transport-relevant structural descriptors
2016
The targeted optimization of the functional properties of porous materials includes the understanding of their transport properties and thus requires knowledge about the relationship between material synthesis, resulting in three-dimensional material morphology, and relevant transport properties. In this Perspective, we present our views and results on the characterization of microscopic disorder in functional porous materials, which are widely used today as fixed beds in adsorption, separation, and catalysis. This allows us to identify structural parameters that impact their mass transport properties and eventually their overall performance in technological operations. We address this comp…