Search results for "Pressure"
showing 10 items of 4493 documents
Structural and Vibrational Properties of Corundum-type In2O3 Nanocrystals under Compression
2017
[EN] This work reports the structural and vibrational properties of nanocrystals of corundum-type In2O3 (rh-In2O3) at high pressures by using angle-dispersive x-ray diffraction and Raman scattering measurements up to 30 GPa. The equation of state and the pressure dependence of the Raman-active modes of the corundum phase in nanocrystals are in good agreement with previous studies on bulk material and theoretical simulations on bulk rh-In2O3. Nanocrystalline rh-In2O3 showed stability under compression at least up to 20 GPa, unlike bulk rh-In2O3 which gradually transforms to the orthorhombic Pbca (Rh2O3-III-type) structure above 12 14 GPa. The different stability range found in nanocrystallin…
Influence of Electromechanical Fields on Dielectric Properties of PLZT−x/65/35 Ceramics (x = 6 and 7)
2011
High density and transparent PLZT−x/65/35 (x = 6 and 7) ceramics with the average grain size of 5–7 μm was obtained by two−stage hot−pressing technology. The measurements of temperature/frequency dependence of the permittivities of these ceramics under uniaxial pressure (0–100 MPa) applied parallel to the ac electric field have been carried out. It was found that uniaxial pressure significantly influences dielectric properties of these ceramics. With the increase of pressure the maximum intensity in ϵ(T) curve decreases, becomes more diffuse and shifts towards higher temperature, dielectric dispersion decreases and classical ferroelectric seems to change to relaxor one. It was concluded, th…
On the influence of orientation upon the mechanical behavior of oakwood in a general state of stress
1995
Influence of orientation upon the mechanical behavior of oakwood has been studied. The approach within anisotropic medias mechanics supposes oakwood orthotropic with three orthogonal symmetry axes considered to be the privileged directions that occur during the growth of oaktree. Experimental tests consisted in compression tests under confining pressure realized on cylindric samples of oakwood chopped in 18 privileged directions. Although well known in solid mechanics, our approach is original in mechanics and rheology of wood. The obtained results disclosed an influence of the confining pressure upon the mechanical behavior of oakwood and its anisotropy including different types of anisotr…
Polyamorphic transformation induced by electron irradiation ina-SiO2glass
2009
We report a study by electron paramagnetic resonance of amorphous silicon dioxide $(a{\text{-SiO}}_{2})$ irradiated by 2.5 MeV electrons in the dose range from $1.2\ifmmode\times\else\texttimes\fi{}{10}^{3}$ to $5\ifmmode\times\else\texttimes\fi{}{10}^{6}\text{ }\text{kGy}$. By measuring the change in the splitting of the primary $^{29}\text{S}\text{i}$ hyperfine doublet of the ${E}_{\ensuremath{\gamma}}^{\ensuremath{'}}$ centers we evidenced an irradiation induced local (around the defects) densification of $a{\text{-SiO}}_{2}$. Our data show that the local degree of densification of the materials is significantly higher than that obtained by mean density measurements, suggesting that the …
High-pressure Raman scattering of the stretching mode in nitrogen along the 300-K isotherm
1996
We present Raman scattering studies of the vibrational band of nitrogen at room temperature between 1 and 31 GPa allowing a detailed line-shape analysis. For the fluid and \ensuremath{\beta} phases the vibrational linewidths compare to dephasing rates ${\mathit{T}}_{2}^{\mathrm{\ensuremath{-}}1}$ determined by experiments in the time domain. The \ensuremath{\delta}-\ensuremath{\epsilon} transition is unmistakably marked by a drop of the vibrational linewidths around 17 GPa. A further transition into the \ensuremath{\eta} phase around 20 GPa proposed from previous Raman results can be ruled out. Additionally, clear evidence is found for a dynamical freezing of the ${\mathrm{N}}_{2}$ molecule…
A novel multi-wavelength procedure for blood pressure estimation using opto-physiological sensor at peripheral arteries and capillaries
2018
© 2018 SPIE. In this study, the Carelight multi-wavelength opto-electronic patch sensor (OEPS) was adopted to assess the effectiveness of a new approach for estimating the systolic blood pressure (SBP) through the changes in the morphology of the OEPS signal. Specifically, the SBP was estimated by changing the pressure exerted on an inflatable cuff placed around the left upper arm. Pressure acquisitions were performed both with gold standard (i.e. electronic sphygmomanometer), and Carelight sensor (experimental procedure), on subjects from a multiethnic cohort (aged 28 ± 7). The OEPS sensor was applied together with a manual inflatable cuff, going slightly above the level of the SBP with in…
Determination of lifetime probabilities of carbon fibre composite plates and pressure vessels for hydrogen storage
2011
International audience; It is shown that an analogy can be made between the failure of unidirectional carbon fibre reinforced epoxy plates and filament wound carbon fibre composite pressure vessels and that their strengths and failure probabilities can be determined. Fibres in filament wound composite structures are placed on geodesic paths around the mandrel, which becomes the liner; so that when the structure is pressurised the fibres are only subjected to tensile forces, as in a unidirectional composite. Multiscale modelling reveals that composite failure is controlled by fibre breakage and that clustering of fibre breaks determines ultimate reliability of the structure. Time dependent r…
Visual indicator for the detection of end-of-life criterion for composite high pressure vessels for hydrogen storage
2012
International audience; A model to predict the accumulation of fibre breaks in advanced composites, that takes into account all physical phenomena implicated in fibre failure (i.e. the random nature, stress transfer due to breaks, fibre debonding and viscosity of the matrix) shows clearly that the failure of a unidirectional composite structure results in the formation of random fibre breaks which at higher loads coalesce into clusters of broken fibres. This stage of development is followed almost immediately by failure. This has direct application to filament wound pressure vessels of the type used to store hydrogen under high pressure. A novel, cost effective, method of revealing developi…
Hydrodynamics of a three-phase fixed-bed reactor operating in the pulsing flow regime at an elevated pressure
2002
Abstract Results are presented for a three-phase reactor operating at an elevated pressure in the pulsing flow regime. For the system air–water and pressures of 0.1– 0.9 MPa lines are determined that define the change of the hydrodynamic model from the gas continuous flow regime (GCF) to the pulsing flow regime (PF). Also, parameters are found that characterize the pulsing flow of fluids, namely the velocity of pulses travelling along the bed, the frequency of pulsations and their structure, i.e., the length of the pulses and that of the liquid-rich zone.
Electrochemical conversion of CO2 to formic acid using a Sn based electrode: A critical review on the state-of-the-art technologies and their potenti…
2021
Abstract The electrochemical conversion of carbon dioxide is considered one of the most promising strategies to convert waste-CO2 into value-added chemicals. This review focuses on the synthesis of formic acid/formate in aqueous electrolyte using Sn-based cathodes; this material is considered relatively cheap and shows promising results in terms of faradaic efficiency. In order to be suitable at an industrial scale, the process should present simultaneously high current densities, faradaic efficiencies close to 100%, high concentrations of formic acid and long-term stability. Analysing the main results reported in the literature, it was observed that to date further studies are necessary to…