Search results for "Prism"

showing 10 items of 120 documents

A trigonal prismatic anionic iron(iii) complex of a radical o-iminobenzosemiquinonate derivative: structural and spectral analyses

2017

A new iron(III) complex, [Et3NH][FeIII(L2−˙)2] (1) with a substituted o-aminophenol based ligand is reported. Complex 1 is an anionic complex with a triethylammonium cation in the lattice. It contains two O,O,N-coordinated o-iminobenzosemiquinonate(2−) radical anions with an Fe(III) centre in a high-spin configuration. The crystal structure of 1 was determined by X-ray diffraction, which revealed a trigonal prismatic coordination environment whose electronic structure was established by various physical methods including EPR, Mossbauer spectroscopy and variable-temperature (2–300 K) magnetic susceptibility measurements. Electrochemical analysis indicated primarily ligand-centred redox proce…

010405 organic chemistryChemistryLigandGeneral ChemistryCrystal structureElectronic structure010402 general chemistryTrigonal prismatic molecular geometry01 natural sciencesMagnetic susceptibilityCatalysis0104 chemical scienceslaw.inventionCrystallographylawMössbauer spectroscopyMaterials ChemistryGround stateElectron paramagnetic resonanceNew Journal of Chemistry
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Towards Quantifying Non-Photosynthetic Vegetation for Agriculture Using Spaceborne Imaging Spectroscopy

2021

Non-photosynthetic vegetation (NPV) has been identified as priority variable in the context of new spaceborne imaging spectroscopy missions. In this study we provide a first attempt to quantify NPV biomass from these unprecedented data streams to be provided by multiple recently launched or planned instruments. A hybrid workflow is proposed including Gaussian process regression (GPR) trained over radiative transfer model (RTM) simulations and applying active learning strategies. A soybean field data set including two dates with NPV measurements on yellow and senescent (brown) plant organs was used for model validation, resulting in relative errors of 13.4%. This prototype retrieval model wa…

2. Zero hunger010504 meteorology & atmospheric sciencesData stream mining0211 other engineering and technologiesEnMAPHyperspectral imagingContext (language use)PRISMA02 engineering and technologyVegetationVegetation functional trait01 natural sciencesLigninImaging spectroscopyAtmospheric radiative transfer codesWorkflowHybrid approacheCHIMEKrigingEnvironmental scienceCelluloseGaussian process regression021101 geological & geomatics engineering0105 earth and related environmental sciencesRemote sensing
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From Graz to Göttingen: Neugebauer’s Early Intellectual Journey

2016

Otto Neugebauer’s early academic career was marked by a series of transitions. His interests shifted from physics to mathematics, and finally to the history of ancient mathematics and exact sciences. Yet even from his early years in Graz, Neugebauer was strongly attracted to the mathematical culture of Gottingen. When he arrived there in 1922, he quickly established a strong personal friendship with Richard Courant, the newly appointed Director of the Mathematics Institute. Neugebauer and Courant worked together closely up until 1933, when the Nazi government decimated the Gottingen scientific community. In this essay, Neugebauer’s historical work and his vision for a new approach to the st…

Academic careerWeimar Republicmedia_common.quotation_subject010102 general mathematicsArt historyExact scienceNazismArt01 natural sciencesScholarshipFriendshipPerformance art0101 mathematicsPRISM (surveillance program)Cartographymedia_common
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Tectonic evolution of the Sicilian Thrust System (central Mediterranean)

2012

The Sicilian Thrust System (STS) is a south-verging (Africa-verging) fold-and-thrust belt including a Mesozoic-Paleogene sedimentary sequence. This thrust stack owes its origin to the deformation of pre-orogenic strata deposited in different palaeogeographic domains belonging to passive margins of the African plate. The STS was deformed during the Neogene, following the closure of the Tethys Ocean and the continental collision between the Sardo-Corso Block and the North Africa margins. The thrust pile was detached from the underlying basement during the Miocene-Pleistocene. The regional-scale structural setting recognized allows us to reconstruct the tectonic evolution of the STS as follows…

Accretionary wedgeContinental collisionSettore GEO/03 - Geologia StrutturaleextensionGeologythrustingAfrica margin depositsNeogeneTethys Oceanlanguage.human_languageaccretionary prismAfrican PlatePaleontologytectonicBasement (geology)Passive marginlanguagetectonicsSicilianSicilyGeologySeismologyAfrica margin deposit
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Pràctica 3. Relació convergència-acomodació

2018

El document forma part dels materials docents programats mitjançant l'ajut del Servei de Política Lingüística de la Universitat de València. Pràctica 3 de l'assignatura de psicofísica de la visió on l'objectiu és obtenir la gràfica de la relació convergència-acomodació trobant les amplituts relatives de convergència i acomodació per a diferents distàncies d’observació.

AcomodaciófisicalentsConvergènciaprisma
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Mapping landscape canopy nitrogen content from space using PRISMA data

2021

Abstract Satellite imaging spectroscopy for terrestrial applications is reaching maturity with recently launched and upcoming science-driven missions, e.g. PRecursore IperSpettrale della Missione Applicativa (PRISMA) and Environmental Mapping and Analysis Program (EnMAP), respectively. Moreover, the high-priority mission candidate Copernicus Hyperspectral Imaging Mission for the Environment (CHIME) is expected to globally provide routine hyperspectral observations to support new and enhanced services for, among others, sustainable agricultural and biodiversity management. Thanks to the provision of contiguous visible-to-shortwave infrared spectral data, hyperspectral missions open enhanced …

Active learningActive learning (machine learning)Computer scienceDimensionality reductionHyperspectral imagingPRISMAContext (language use)CollinearityHybrid retrievalDimensionality reductionImaging spectroscopyAtomic and Molecular Physics and OpticsComputer Science ApplicationsImaging spectroscopyCHIMEKrigingEnMAPCanopy nitrogen contentComputers in Earth SciencesEngineering (miscellaneous)Gaussian process regressionRemote sensingISPRS Journal of Photogrammetry and Remote Sensing
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Combining tDCS with prismatic adaptation for non-invasive neuromodulation of the motor cortex

2017

Abstract Background Prismatic adaptation (PA) shifts visual field laterally and induces lateralized deviations of spatial attention. Recently, it has been suggested that prismatic goggles are also able to modulate brain excitability, with cognitive after-effects documented even in tasks not necessarily spatial in nature. Objective The aim of the present study was to test whether neuromodulatory effects obtained from tDCS and prismatic goggles could interact and induce homeostatic changes in corticospinal excitability. Methods Thirty-four subjects were submitted to single-pulse transcranial magnetic stimulation (TMS) over the right primary motor cortex to measure Input-Output (IO) curve as a…

AdultCognitive Neurosciencemedicine.medical_treatmentExperimental and Cognitive PsychologyElectromyographyTranscranial Direct Current Stimulation050105 experimental psychology03 medical and health sciencesBehavioral Neuroscience0302 clinical medicineNeuromodulationHomeostatic plasticityAdaptation PsychologicalMetaplasticityNeuroplasticitytDCS TMS prismatic adaptation motor cortexmedicineHumans0501 psychology and cognitive sciencesMuscle SkeletalLensesAnalysis of VarianceNeuronal PlasticitySettore M-PSI/02 - Psicobiologia E Psicologia FisiologicaTranscranial direct-current stimulationmedicine.diagnostic_testElectromyography05 social sciencesMotor CortexEvoked Potentials MotorAdaptation PhysiologicalTranscranial magnetic stimulationmedicine.anatomical_structureVisual PerceptionPsychologyNeurosciencePsychomotor Performance030217 neurology & neurosurgeryMotor cortexNeuropsychologia
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Left insular cortex and left SFG underlie prismatic adaptation effects on time perception: Evidence from fMRI

2014

Prismatic adaptation (PA) has been shown to affect left-to-right spatial representations of temporal durations. A leftward aftereffect usually distorts time representation toward an underestimation, while rightward aftereffect usually results in an overestimation of temporal durations. Here, we used functional magnetic resonance imaging (fMRI) to study the neural mechanisms that underlie PA effects on time perception. Additionally, we investigated whether the effect of PA on time is transient or stable and, in the case of stability, which cortical areas are responsible of its maintenance. Functional brain images were acquired while participants (n = 17) performed a time reproduction task an…

AdultMaleAdolescentgenetic structuresCognitive NeurosciencePrefrontal CortexPosterior parietal cortexBrain mappingYoung AdultFigural AftereffectNeuroplasticitymedicineHumansSPACEPrismatic adaptationPrefrontal cortexFUNCTIONAL MAGNETIC RESONANCE IMAGING (FMRI)Cerebral CortexBrain MappingEvidence-Based MedicineNeuronal PlasticitySettore M-PSI/02 - Psicobiologia E Psicologia Fisiologicamedicine.diagnostic_testWorking memoryHemispatial neglectSpatial representation of timeTime perceptionAdaptation PhysiologicalMagnetic Resonance ImagingTIMENeurologySpace PerceptionFMRITime PerceptionFemaleNerve Netmedicine.symptomPsychologyFunctional magnetic resonance imagingNeuroscienceNeuroImage
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Prismatic Adaptation as a Novel Tool to Directionally Modulate Motor Cortex Excitability: Evidence From Paired-pulse TMS

2014

Abstract Background The prismatic adaptation (PA) is a visuo-motor procedure that has captured the attention of neuroscientists in the last decades, hence it seems to affect high-order cognition. However, the basic neural processes related to PA and its effects on cortical plasticity are not clear yet. Objective/hypothesis The aim of the present study is to explore whether PA induces a direct effect on the motor cortices (M1) excitability. Methods Fourteen healthy participants were submitted to paired-pulse TMS to measure short-intracortical-inhibition (SICI) and intracortical-facilitation (ICF) on both the left and the right M1, before and after PA, that could induce a leftward or rightwar…

AdultMaleBiophysicsAdaptation (eye)Affect (psychology)lcsh:RC321-571NeuroplasticitymedicineHumansPRISMSMotor cortex; Prismatic adaptation; SICI-ICF; Inter-hemispheric excitabilityPrismatic adaptationlcsh:Neurosciences. Biological psychiatry. NeuropsychiatrySettore M-PSI/02 - Psicobiologia E Psicologia FisiologicaPulse (signal processing)General NeuroscienceCognitionNeurophysiologyEvoked Potentials MotorSICI-ICFAdaptation PhysiologicalTranscranial Magnetic Stimulationmedicine.anatomical_structureEXCITABILITYFacilitationInter-hemispheric excitabilityMotor cortexSettore MED/26 - NeurologiaFemaleNeurology (clinical)PsychologyNeuroscienceMotor cortexBrain Stimulation
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Time and spatial attention: Effects of prism adaptation on temporal deficits in brain damaged patients

2011

Growing evidence indicates that the representations of space and time interact in the brain but the exact neural correlates of such interaction remain unknown. Neuroimaging and neuropsychological studies show that processing of temporal information engages a distributed network in the right hemisphere and suggest a link between deficits in spatial attention and deficits in time perception. In the present study we used the procedure of prismatic adaptation (PA) to directionally manipulate spatial attention in order to explore the effect of attentional deviation on time perception in patients with right (RBD) vs. left (LBD) brain damage. In a first experiment, two groups of RBD and LBD patien…

AdultMaleCognitive NeuroscienceRight hemisphereExperimental and Cognitive PsychologySpaceNeuropsychological TestsLeft hemisphereLateralization of brain functionPerceptual DisordersBehavioral NeuroscienceNeuroimagingHumansAttentiontimeAgedAged 80 and overNeural correlates of consciousnessNeuropsychologyCognitionMiddle AgedTime perceptionAdaptation PhysiologicalPrismBrain InjuriesSpace PerceptionTime PerceptionCerebral hemisphereFemalePsychologyNeurosciencePrism adaptationSTROKE
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