Search results for "Probe"
showing 10 items of 534 documents
Time-resolved core-level photoemission data of tungsten diselenide
2020
Pump-probe core-level photoemission spectroscopy data of tungsten diselenide (WSe2) measured using an electron momentum microscope at the FLASH Free-electron laser.
Effect of Hot Dip Galvanized Steel Surface Chemistry and Morphology on Titanium Hexafluoride Pretreatment
2017
Titanium hexafluoride pretreatments are known to improve paint adhesion and function as a barrier between the coating and the hot dip galvanized (HDG) steel surface. Interactions at the zinc/pretreatment interface are of utmost importance for the formation of pretreatment layers and the corrosion resistance of color coated hot dip galvanized steels. Removal rate of inert aluminum oxide from HDG steel samples by chemical dissolution was studied. XPS measurements showed that the surface Al2O3 layer thickness decreased rapidly already at mild alkaline cleaning, while complete removal of Al required severe etching. Low reactivity of an Al2O3-rich surface was confirmed by impaired formation of a…
Ultrafast Interface Charge Separation in Carbon Nanodot-Nanotube Hybrids
2021
Carbon dots are an emerging family of zero-dimensional nanocarbons behaving as tunable light harvesters and photoactivated charge donors. Coupling them to carbon nanotubes, which are well-known electron acceptors with excellent charge transport capabilities, is very promising for several applications. Here, we first devised a route to achieve the stable electrostatic binding of carbon dots to multi- or single-walled carbon nanotubes, as confirmed by several experimental observations. The photoluminescence of carbon dots is strongly quenched when they contact either semiconductive or conductive nanotubes, indicating a strong electronic coupling to both. Theoretical simulations predict a favo…
Detection of Southern tomato virus by molecular hybridisation
2017
Southern tomato virus (STV) is a double-stranded RNA (dsRNA) virus belonging to the genus Amalgavirus from the family Amalgamaviridae. STV has been detected in tomato plants showing symptoms of stunting, fruit discoloration and size reduction, although its role on symptom development is unclear. Also, little is known about the incidence and epidemiology of this virus and how it spreads in tomato crops. In this work, we developed a molecular hybridisation method by using a digoxigenin-labelled RNA probe based on the nucleotide sequence of the STV putative coat protein which was tested with different procedures for preparation of plant material. This technique was sensitive enough to detect S…
Oceka kačectva tekuŝih vod na osnovanii analiza kompleksa donnoj makrofauny. Primer monitoringa reki Śčinava Nemodlinska (Polʺša) v 1999-2005 godah
2008
Chasing Weak Forces: Hierarchically Assembled Helicates as a Probe for the Evaluation of the Energetics of Weak Interactions.
2017
London dispersion forces are the weakest interactions between molecules. Because of this, their influence on chemical processes is often low, but can definitely not be ignored, and even becomes important in cases of molecules with large contact surfaces. Hierarchically assembled dinuclear titanium(IV) helicates represent a rare example in which the direct observation of London dispersion forces is possible in solution even in the presence of strong cohesive solvent effects. Hereby, the dispersion forces do not unlimitedly support the formation of the dimeric complexes. Although they have some favorable enthalpic contribution to the dimerization of the monomeric complex units, large flexible…
BODIPY atropisomer interconversion, face discrimination, and superstructure appending
2016
International audience; A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two inter-convertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.
Ultrafast Coherent THz Lattice Dynamics Coupled to Spins in the van der Waals Antiferromagnet FePS3
2022
Coherent THz optical lattice and hybridized phonon–magnon modes are triggered by femtosecond laser pulses in the antiferromagnetic van der Waals semiconductor FePS3. The laser-driven lattice and spin dynamics are investigated in a bulk crystal as well as in a 380 nm-thick exfoliated flake as a function of the excitation photon energy, sample temperature and applied magnetic field. The pump-probe magneto-optical measurements reveal that the amplitude of a coherent phonon mode oscillating at 3.2 THz decreases as the sample is heated up to the Néel temperature. This signal eventually vanishes as the phase transition to the paramagnetic phase occurs, thus revealing its connection to the long-ra…
Memoria Autobiográfica y Atención. Perspectiva Cognitiva y Experimental.
2017
RESUMEN TESIS Título: Memoria Autobiográfica y Atención. Una perspectiva cognitiva y experimental. Doctoranda: Ana Isabel Agustí López Director de tesis: Juan Carlos Meléndez Moral Este trabajo plantea dos cuestiones u objetivos generales, en primer lugar se pretende comprobar si al estudiar la memoria autobiográfica (MA) existen diferencias entre jóvenes y adultos mayores no solamente en relación al tipo de memoria (episódica y semántica) sino también en relación al componente emocional asociado a los recuerdos y la distribución temporal del recuerdo (infancia/ adolescencia, bump de reminiscencia y recuerdos recientes). En segundo lugar, se pretende estudiar la atención mediante tareas de …
The Ti-influence on the tourmaline color
2008
Titanium was examined in different black tourmalines by spectrophotometric analyses in the region between 12500 and 27000 cm-1 (800-370 nm) using a microscope spectrophotometer MPV-5P, Leitz (Germany), and chemically analyzed on an electron microprobe Camebax Microbeam, Cameca (France) in WDS Mode. Fourteen tourmaline samples with their face oriented parallel to the principal axis, cut and polished down to thin sections, showed polarized spectra of two broad absorption bands at approximately 14000 cm-1 (715 nm) and 24000 cm-1 (417 nm). Precision thickness measurements were used to calculate the absorption coefficients α. For the absorption around 24000 cm-1, a linear correlation was observe…