Search results for "Processe"

showing 10 items of 3955 documents

Exceptional affinity of nanostructured organic-inorganic hybrid materials towards dioxygen: confinement effect of copper complexes

2007

We report the exceptional reactivity towards dioxygen of a nanostructured organic-inorganic hybrid material due to the confinement of copper cyclam within a silica matrix. The key step is the metalation reaction of the ligand, which can occur before or after xerogel formation through the sol-gel process. The incorporation of a Cu(II) center into the material after xerogel formation leads to a bridged Cu(I)/Cu(II) mixed-valence dinuclear species. This complex exhibits a very high affinity towards dioxygen, attributable to auto-organization of the active species in the solid. The remarkable properties of these copper complexes in the silica matrix demonstrate a high cooperative effect for O(2…

Cations DivalentMetalationInorganic chemistrychemistry.chemical_elementLigands010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundAdsorptionHeterocyclic CompoundsCyclamPolymer chemistryOrganometallic CompoundsLamellar structureReactivity (chemistry)ComputingMilieux_MISCELLANEOUSdioxygen bindingBinding Sites010405 organic chemistryLigandsol-gel processesSpectrum AnalysisOrganic ChemistryTemperatureGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistrySilicon DioxideCopperEnzymesNanostructuresPeroxides0104 chemical sciencesOxygenchemistrytetraazamacrocyclesMultiprotein Complexescopper[ CHIM.MATE ] Chemical Sciences/Material chemistryAnisotropyAdsorptionHybrid materialGelsorganic-inorganic hybrid composites
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A new Framework for the Spectral Information Decomposition of Multivariate Gaussian Processes

2021

: Different information-theoretic measures are available in the literature for the study of pairwise and higher-order interactions in multivariate dynamical systems. While these measures operate in the time domain, several physiological and non-physiological systems exhibit a rich oscillatory content that is typically analyzed in the frequency domain through spectral and cross-spectral approaches. For Gaussian systems, the relation between information and spectral measures has been established considering coupling and causality measures, but not for higher-order interactions. To fill this gap, in this work we introduce an information-theoretic framework in the frequency domain to quantify t…

CausalityTime-frequency analysisTime series analysisRedundancyGaussian processesTime measurementPhysiologyElectroencephalographySettore ING-INF/06 - Bioingegneria Elettronica E InformaticaNormal DistributionHumansSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)
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Symmetric expansion of neural stem cells from the adult olfactory bulb is driven by astrocytes via WNT7A.

2012

Adult neural stem cells (NSCs) located in the subventricular zone (SVZ) persistently produce new neurons destined to the olfactory bulb (OB). Recent research suggests that the OB is also a source of NSCs that remains largely unexplored. Using single/dual-labeling procedures, we address the existence of NSCs in the innermost layers of the OB. In vivo, these cells are more quiescent that their SVZ counterparts, but after in vitro expansion, they behave similarly. Self-renewal and proliferation assays in co-culture with niche astrocytes indicate that OB-glia restricts NSC activity whereas SVZ-glia has the opposite effect. Gene expression profiling identifies WNT7A as a key SVZ-glial factor lac…

Cellular differentiationSubventricular zoneCell Growth ProcessesBiologyMiceNeural Stem CellsIn vivomedicineAnimalsHumansreproductive and urinary physiologyWnt signaling pathwayCell DifferentiationCell BiologyAnatomyOlfactory BulbNeural stem cellnervous system diseasesOlfactory bulbCell biologyGene expression profilingWnt ProteinsWNT7Amedicine.anatomical_structurenervous systemAstrocytesMolecular Medicinebiological phenomena cell phenomena and immunityDevelopmental BiologyStem cells (Dayton, Ohio)
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Gray Matter NG2 Cells Display Multiple Ca2+-Signaling Pathways and Highly Motile Processes

2011

NG2 cells, the fourth type of glia in the mammalian CNS, receive synaptic input from neurons. The function of this innervation is unknown yet. Postsynaptic changes in intracellular Ca(2+)-concentration ([Ca(2+)](i)) might be a possible consequence. We employed transgenic mice with fluorescently labeled NG2 cells to address this issue. To identify Ca(2+)-signaling pathways we combined patch-clamp recordings, Ca(2+)-imaging, mRNA-transcript analysis and focal pressure-application of various substances to identified NG2-cells in acute hippocampal slices. We show that activation of voltage-gated Ca(2+)-channels, Ca(2+)-permeable AMPA-receptors, and group I metabotropic glutamate-receptors provo…

Central Nervous SystemAnatomy and PhysiologyVesicular glutamate transporter 1Glycobiologylcsh:MedicineHippocampal formationBiochemistryIon ChannelsTransmembrane Transport ProteinsMice0302 clinical medicinePostsynaptic potentialBiomacromolecule-Ligand Interactionslcsh:ScienceCells CulturedMembrane potential0303 health sciencesMultidisciplinarybiologyReverse Transcriptase Polymerase Chain ReactionDepolarizationNeurochemistryNeurotransmittersCell biologyElectrophysiologymedicine.anatomical_structureNeurologyNeurogliaMedicineProteoglycansNeurochemicalsGlutamateNeurogliaResearch ArticleNervous System PhysiologySignal TransductionCell PhysiologyMotilityNeuroimagingMice TransgenicNeurological System03 medical and health sciencesNeuropharmacologymedicineAnimalsHumansddc:610Biology030304 developmental biologyEndoplasmic reticulumlcsh:RProteinsGamma-Aminobutyric AcidTransmembrane ProteinsLuminescent ProteinsMicroscopy Electronnervous systemMicroscopy FluorescenceSynapsesVesicular Glutamate Transport Protein 1biology.proteinNervous System Componentslcsh:QCalciumPhysiological Processes030217 neurology & neurosurgeryNeurosciencePLoS ONE
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The effects of lasers on bond strength to ceramic materials: A systematic review and meta-analysis

2018

Lasers have recently been introduced as an alternative means of conditioning dental ceramic surfaces in order to enhance their adhesive strength to cements and other materials. The present systematic review and meta-analysis aimed to review and quantitatively analyze the available literature in order to determine which bond protocols and laser types are the most effective. A search was conducted in the Pubmed, Embase and Scopus databases for papers published up to April 2017. PRISMA guidelines for systematic review and meta-analysis were followed. Fifty-two papers were eligible for inclusion in the review. Twenty-five studies were synthesized quantitatively. Lasers were found to increase bo…

CeramicsHigh variabilitylcsh:MedicineMaterials testinglaw.inventionAdhesion strength030207 dermatology & venereal diseasesMathematical and Statistical Techniques0302 clinical medicinelawMaterials TestingCeramicComposite materiallcsh:ScienceMultidisciplinaryBond strengthResearch AssessmentSystematic reviewOptical Equipmentvisual_artMeta-analysisPhysical SciencesCementsvisual_art.visual_art_mediumEngineering and TechnologyStatistics (Mathematics)Research ArticleMaterials scienceSystematic ReviewsMaterials by StructureAmorphous SolidsMaterials ScienceEquipmentResearch and Analysis MethodsDental Materials03 medical and health sciencesBindersStatistical MethodsMaterials by AttributeSurface TreatmentsLaserslcsh:R030206 dentistryLaserManufacturing ProcessesComposite Materialslcsh:QGlassMathematicsMeta-AnalysisPLOS ONE
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Effects of femtosecond laser and other surface treatments on the bond strength of metallic and ceramic orthodontic brackets to zirconia.

2017

Femtosecond laser has been proposed as a method for conditioning zirconia surfaces to boost bond strength. However, metallic or ceramic bracket bonding to femtosecond lasertreated zirconia surfaces has not been tested. This study compared the effects of four conditioning techniques, including femtosecond laser irradiation, on shear bond strength (SBS) of metallic and ceramic brackets to zirconia.Three hundred zirconia plates were divided into five groups: 1) control (C); 2) sandblasting (APA); 3) silica coating and silane (SC); 4) femtosecond laser (FS); 5) sandblasting followed by femtosecond laser (APA+SC). A thermal imaging camera measured temperature changes in the zirconia during irrad…

CeramicsScanning electron microscopeOrthodontic Bracketslcsh:MedicineTissue AdhesionsCoating Materials030207 dermatology & venereal diseases0302 clinical medicineMedicine and Health SciencesSilaneElectron MicroscopyCubic zirconiaCeramicZirconium oxideComposite materiallcsh:ScienceMicroscopyMultidisciplinaryBond strengthBracketTemperatureOptical EquipmentMetalsvisual_artPhysical SciencesFemtosecondvisual_art.visual_art_mediumEngineering and TechnologyScanning Electron MicroscopyShear StrengthResearch ArticleMaterials scienceMaterials by StructureMaterials ScienceOral MedicineEquipmentOrthodonticsResearch and Analysis MethodsENPEP gene03 medical and health sciencesCoatingsAdhesivesShear strengthMaterials by AttributeUniversal testing machineSurface TreatmentsLaserslcsh:R030206 dentistryManufacturing ProcessesMicroscopy Electron Scanninglcsh:QZirconiumPLoS ONE
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Transcranial Magnetic Stimulation Combined With Nicotine Replacement Therapy for Smoking Cessation: A Randomized Controlled Trial.

2015

Abstract Background Further evidence suggests that repetitive Transcranial Magnetic Stimulation (rTMS) is an effective method to reduce tobacco craving among smokers. Hypothesis As relapse is common within a few days after smoking cessation, we hypothesized that combining the anti-craving effects of rTMS with Nicotine replacement therapy (NRT) to attenuate withdrawal symptoms could increase abstinence rates in smokers with severe nicotine dependence who quit smoking. Methods Thirty-seven smokers who failed to quit with the usual treatments were randomly assigned to two treatment groups to receive either active ( n  = 18) or sham ( n  = 19) 1-Hz rTMS of the right dorsolateral prefrontal cort…

CessationAdultMaleNicotinemedicine.medical_specialtymedicine.medical_treatmentmedia_common.quotation_subjectBiophysicsPrefrontal CortexCravingbehavioral disciplines and activitieslcsh:RC321-571law.inventionNicotineYoung AdultRandomized controlled triallawTobaccomental disordersmedicineHumansSingle-Blind MethodPsychiatrylcsh:Neurosciences. Biological psychiatry. Neuropsychiatrymedia_commonCravingGeneral NeuroscienceTobacco Use DisorderAbstinenceMiddle AgedNicotine replacement therapyCombined Modality TherapyTranscranial Magnetic StimulationTobacco Use Cessation DevicesTranscranial magnetic stimulationTreatment Outcomenervous systemAnesthesiaCombinationbehavior and behavior mechanismsSmoking cessationFemaleSmoking CessationNeurology (clinical)medicine.symptomTobacco Use Cessation ProductsPsychologypsychological phenomena and processesmedicine.drugBrain stimulation
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The Effect of Taper and Apical Diameter on the Cyclic Fatigue Resistance of Rotary Endodontic Files Using an Experimental Electronic Device

2021

The aim of this study was to analyze the effect of the taper and apical diameter of nickel&ndash

Characteristic strengthinorganic chemicalsCyclic stressmedicine.medical_specialtyMaterials scienceapical diameterlcsh:TechnologyDynamic resistancelcsh:Chemistry03 medical and health sciences0302 clinical medicine0502 economics and businessEndodontic filesmedicineotorhinolaryngologic diseasesGeneral Materials SciencetaperInstrumentationlcsh:QH301-705.5endodontic rotary filesWeibull distributionFluid Flow and Transfer ProcessesOrthodonticsWeibull moduluslcsh:TProcess Chemistry and Technology05 social sciencesGeneral Engineering030206 dentistryEndodonticscyclic fatiguelcsh:QC1-999Computer Science Applicationsendodonticslcsh:Biology (General)lcsh:QD1-999Nickel titaniumlcsh:TA1-2040050211 marketingrotary movementlcsh:Engineering (General). Civil engineering (General)lcsh:PhysicsApplied Sciences
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World Influence of Infectious Diseases from Wikipedia Network Analysis

2019

AbstractWe consider the network of 5 416 537 articles of English Wikipedia extracted in 2017. Using the recent reduced Google matrix (REGOMAX) method we construct the reduced network of 230 articles (nodes) of infectious diseases and 195 articles of world countries. This method generates the reduced directed network between all 425 nodes taking into account all direct and indirect links with pathways via the huge global network. PageRank and CheiRank algorithms are used to determine the most influential diseases with the top PageRank diseases being Tuberculosis, HIV/AIDS and Malaria. From the reduced Google matrix we determine the sensitivity of world countries to specific diseases integrat…

CheiRankComputer scienceHuman immunodeficiency virus (HIV)medicine.disease_cause01 natural sciences[INFO.INFO-SI]Computer Science [cs]/Social and Information Networks [cs.SI]law.invention03 medical and health sciencesPageRanklaw0103 physical sciencesGlobal networkmedicine010306 general physics030304 developmental biology0303 health sciencesInformation retrievalGoogle matrixMarkov processes[PHYS.PHYS.PHYS-SOC-PH]Physics [physics]/Physics [physics]/Physics and Society [physics.soc-ph]complex networksdata mining[SDV.BIBS]Life Sciences [q-bio]/Quantitative Methods [q-bio.QM]ranking (statistics)3. Good healthInfectious diseaseslcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:TK1-9971Network analysisWikipedia
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Coupled petrological-geodynamical modeling of a compositionally heterogeneous mantle plume

2018

Abstract Self-consistent geodynamic modeling that includes melting is challenging as the chemistry of the source rocks continuously changes as a result of melt extraction. Here, we describe a new method to study the interaction between physical and chemical processes in an uprising heterogeneous mantle plume by combining a geodynamic code with a thermodynamic modeling approach for magma generation and evolution. We pre-computed hundreds of phase diagrams, each of them for a different chemical system. After melt is extracted, the phase diagram with the closest bulk rock chemistry to the depleted source rock is updated locally. The petrological evolution of rocks is tracked via evolving chemi…

Chemical processgeographygeography.geographical_feature_category010504 meteorology & atmospheric sciences010502 geochemistry & geophysics01 natural sciencesMantle (geology)Mantle plumePlumeGeophysicsVolcanoSource rockPetrologyGeothermal gradientGeology0105 earth and related environmental sciencesEarth-Surface ProcessesPhase diagramTectonophysics
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