Search results for "Propane"

showing 10 items of 486 documents

CCDC 1049932: Experimental Crystal Structure Determination

2015

Related Article: Alina S. Dinca, Sergiu Shova, Adrian E. Ion, Catalin Maxim, Francesc Lloret, Miguel Julve, Marius Andruh|2015|Dalton Trans.|44|7148|doi:10.1039/C5DT00778J

Space GroupCrystallographyhexakis(mu2-Acetato)-hexakis(mu2-oxalato)-hexakis(mu2-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-hexa-dysprosium-hexa-zinc methanol solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1909766: Experimental Crystal Structure Determination

2019

Related Article: A. Wane, A.B. Kama, M.B. Diop, L. Diop, L. Plasseraud, H. Cattey|2019|IUCrData|4|x190500|doi:10.1107/S2414314619005005

Space GroupCrystallographypropane-13-diaminium tetrakis(oxido)-molybdenumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1966630: Experimental Crystal Structure Determination

2019

Related Article: Nikolaos Tsoureas, Akseli Mansikkamäki, Richard A. Layfield|2020|Chem.Commun.|56|944|doi:10.1039/C9CC09018E

Space GroupCrystallographytetrakis(2-methoxy-2-methylpropane)-sodium tris(2-methoxy-2-methylpropane)-tetrahydrofuran-sodium ((cyclobuta-13-diene-1234-tetrayl)tetrakis(trimethylsilane))-(3-[methyl(dimethyl)silyl]-124-tris(trimethylsilyl)cyclobut-2-en-1-yl)-tetrahydridoborato-uraniumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 170382: Experimental Crystal Structure Determination

2002

Related Article: G.Haufe, T.C.Rosen, O.G.J.Meyer, R.Frohlich, K.Rissanen|2002|J.Fluorine Chem.|114|189|doi:10.1016/S0022-1139(02)00040-4

Space GroupCrystallographytrans-2-Fluoro-2-phenylcyclopropanecarboxamideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 601429: Experimental Crystal Structure Determination

2006

Related Article: V.Mishra, F.Lloret, R.Mukherjee|2006|Inorg.Chim.Acta|359|4053|doi:10.1016/j.ica.2006.05.005

Space GroupCrystallographytrans-Diaqua-(13-bis(3-(2-pyridyl)pyrazol-1-yl)propane-NN'N''N''')-cobalt(ii) diperchlorateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

Palladium-Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One-Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene …

2013

The first utilization of acyclic cyclopropane bearing spirocyclic olefines for the generation of stereospecific complex fused ring systems with an achiral catalyst is reported.

StereochemistryOrganic Chemistrychemistry.chemical_elementGeneral ChemistryCatalysisCoupling reactionCatalysisCyclopropanePyrazolidinechemistry.chemical_compoundStereospecificitychemistryCyclopenteneBenzofuranta116PalladiumChemistry - A European Journal
researchProduct

Benzyl ions from 1,1-(2,2′-dimethoxyphenyl)-substituted 2-methylpropanes under electron ionization

2006

The electron ionization (EI)-induced fragmentations of a series of 1,1-(2,2'-dimethoxyphenyl)-substituted 2-methylpropanes (1-20) in both 70 eV and mass-analyzed ion kinetic energy (MIKE) spectra have been investigated. The EI-MS spectra of these compounds are characterized by the presence of abundant benzyl ions. These ions result from competitive hydrogen migration from the 2- and 2'-methoxy groups on the carbenium center of the diphenylmethyl cations formed by benzylic cleavage of the molecular ions. The relative abundances of the benzyl ions arising from such competitive processes are discussed and rationalized. The steric effect of the 3- or 3'-substituents is the main discriminating f…

Steric effectsSpectrometry Mass Electrospray IonizationHydrogenStereochemistrychemistry.chemical_elementKinetic energyMedicinal chemistrySpectral lineAnalytical ChemistryIonPropaneBenzyl CompoundsSpectroscopyElectron ionizationCARBON DOUBLE REARRANGEMENTMASS-SPECTRAHydrocarbons HalogenatedOrganic ChemistryCleavage (crystal)HYDROGEN-CARBONDIMETHOXY AROMATIC-COMPOUNDSSPECTROMETRYchemistryALKYLBENZENESSUBSTITUTED DIPHENYLMETHYL CATIONSHydrogenRapid Communications in Mass Spectrometry
researchProduct

Hydrogels for potential colon drug release by thiol-ene conjugate addition of a new inulin derivative.

2008

Inulin was chosen as a starting polymer for biocompatible, pH-sensitive and biodegradable hydrogels. Three INUDVSA-TT hydrogels were obtained by crosslinking inulin derivatives with trimethylolpropane tris(3-mercaptopropionate) under varying conditions. The resulting hydrogels were cell compatible, as demonstrated by MTS and trypan blue exclusion assays acting on Caco-2 cells, and were biodegraded by inulinase and esterase, thus suggesting their use as colonic drug delivery systems. 2-Methoxyestradiol, an anti-cancer drug, was soaked in INUDVSA-TT hydrogels and its in vitro release and apoptotic effect on Caco-2 cells were evaluated.

Succinic AnhydridesPolymers and PlasticsCell SurvivalColonInulinBioengineeringmacromolecular substancesDNA Fragmentationcomplex mixturesBiomaterialschemistry.chemical_compoundDrug Delivery SystemsMaterials ChemistryOrganic chemistryHumansSulfhydryl CompoundsSulfonesHYDROGELS INULIN DRUG TARGETING COLON DELIVERYTrimethylolpropaneParticle SizeEstradioltechnology industry and agricultureInulinHydrogelsCombinatorial chemistry2-MethoxyestradiolMolecular WeightCross-Linking ReagentschemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoSelf-healing hydrogelsDrug deliveryBisbenzimidazoleLiberationTrypan blueCaco-2 CellsDrug carrierBiotechnologyConjugateMacromolecular bioscience
researchProduct

Discovering Copper for Methane C–H Bond Functionalization

2015

The copper complex Tp(CF3)2,BrCu(NCMe) (1, Tp(CF3)2,Br = hydrotris((3,5-bis(trifluoromethyl)-4-bromo)-pyrazol-1-yl)borate) catalyzes the insertion of the CHCO2Et group (from ethyl diazoacetate N2CHCO2Et, EDA) into the C–H bonds of methane, in a homogeneous process that uses supercritical carbon dioxide (scCO2) as the reaction medium. Other light alkanes such as ethane, propane, and butane have been also functionalized with this copper-based catalyst, in the first example of the derivatization of the series of C1–C4 alkanes with this metal and a soluble catalyst.

Supercritical carbon dioxideTrifluoromethylchemistry.chemical_elementButaneGeneral ChemistryMedicinal chemistryCopperCatalysisMethaneCatalysischemistry.chemical_compoundchemistryEthyl diazoacetatePropaneOrganic chemistryACS Catalysis
researchProduct

Insights into the catalytic production of hydrogen from propane in the presence of oxygen: Cooperative presence of vanadium and gold catalysts

2015

7 figures.-- © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/

Vanadium and gold catalystsHydrogenGeneral Chemical EngineeringInorganic chemistryEnergy Engineering and Power Technologychemistry.chemical_elementVanadiumHydrogen catalytic productionPhotochemistryWater-gas shift reactionVanadium oxideCatalysischemistry.chemical_compoundFuel TechnologyVanadium oxidechemistryPropaneDehydrogenationGoldPropane oxidationWGSHydrogen production
researchProduct