Search results for "Propylene"

showing 10 items of 285 documents

Intraperitoneal coated polypropylene hernia meshes: the dark side of the moon.

2014

To date, the use of meshes in repairing abdominal wall defects has brought many advantages, especially in terms of recurrence prevention, but it is not exempt from complications, such as chronic pain, entero-cutaneous fistulas and intestinal obstruction. Here we report a case of intestinal obstruction in a patient with a large umbilical hernia treated laparoscopically by means of a composite polypropylene mesh, six year before.A 49-year-old man came to our care with a 3-day history of central and right lower abdominal quadrant pain and a clinical picture of intestinal obstruction. Six years before the patient underwent a laparoscopic intervention to repair his umbilical hernia, with the pos…

MaleSettore MED/18 - Chirurgia Generalehernia complications polypropylene coated hernia mesh small bowel obstruction small bowel resection umbilical herniaHumansLaparoscopyJejunal DiseasesMiddle AgedSurgical MeshPolypropylenesProsthesis DesignHernia UmbilicalHerniorrhaphyIntestinal ObstructionAnnali italiani di chirurgia
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NMDA receptor antagonist felbamate reduces behavioral deficits and blood-brain barrier permeability changes after experimental subarachnoid hemorrhag…

2007

Increased levels of glutamate and aspartate have been detected after subarachnoid hemorrhage (SAH) that correlate with neurological status. The NMDA receptor antagonist felbamate (FBM; 2-phenyl-1,3-propanediol dicarbamate) is an anti-epileptic drug that elicits neuroprotective effects in different experimental models of hypoxia-ischemia. The aim of this dose-response study was to evaluate the effect of FBM after experimental SAH in rats on (1) behavioral deficits (employing a battery of assessment tasks days 1-5 post-injury) and (2) blood-brain barrier (BBB) permeability changes (quantifying microvascular alterations according to the extravasation of protein-bound Evans Blue by a spectropho…

Malemedicine.medical_specialtyExcitotoxicityPhenylcarbamatesBehavioral deficitsmedicine.disease_causeCisterna magnaBlood–brain barrierNeuroprotectionReceptors N-Methyl-D-AspartateFelbamateRats Sprague-Dawleychemistry.chemical_compoundInternal medicinemedicineAnimalsAnimals; Blood-Brain Barrier; Rats; Subarachnoid Hemorrhage; Evans Blue; Behavioral deficits; Cognitive deficits; NMDA receptor; FelbamatePostural BalanceEvans BlueBehavior AnimalDose-Response Relationship Drugbusiness.industryCognitive deficitsMicrocirculationBody WeightGlutamate receptorSubarachnoid HemorrhageNMDA receptorFelbamateRatsEndocrinologymedicine.anatomical_structureNeuroprotective AgentsSpectrometry FluorescencechemistryBlood-Brain BarrierPropylene GlycolsAnesthesiaCerebrovascular CirculationNMDA receptorNeurology (clinical)businessmedicine.drugEvans BlueJournal of neurotrauma
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Laparoscopic Repair of Boundary Incisional Hernia in a Kidney Transplant Patient: A Safe Tacks-Fibrin Glue Combined Mesh Fixation Technique.

2018

Abstract Background Incisional hernia in renal transplant patients is a complication that negatively affects the global outcome of transplant and quality of life. The repair of this condition was classically made by open repair with mesh. Increasing evidence suggests that laparoscopic repair could be advocated as the technique of choice in these patients with optimal results. However, the fixation of mesh should be performed by a mixed combination of fibrin sealant (lateral margin of wall defect) and tacks (medial margin). The tacks fixation of the mesh along the lateral margin of the wall defect, close to the graft, is generally difficult for the small size of the remaining aponeurotic pla…

Malemedicine.medical_specialtyIncisional hernialaparoscopic hernia repairPopulationpolypropylene-polyglycolic acid (PGA composite meshFibrin Tissue AdhesiveFibrinFixation (surgical)renal transplantmedicinelower lateral abdominal herniaHumansIncisional HerniaHerniaeducationFibrin glueKidney transplantationHerniorrhaphyAgedTransplantationeducation.field_of_studybiologybusiness.industryProstheses and ImplantsSurgical Meshmedicine.diseaseKidney TransplantationSurgeryfibrin gluesurgical procedures operativeSurgical meshbiology.proteinSurgeryFemaleLaparoscopyboundary herniabusinessTransplantation proceedings
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Enhanced angiogenesis in the 3D dynamic responsive implant for inguinal hernia repair ProFlor

2021

Biologic response to hernia prostheses represents a continuous source of debate. Conventional hernia meshes, in their typical static, passive configuration have been used for decades to reinforce the herniated abdominal wall. These flat implants, mainly fixated with sutures or tacks, induce poor quality fibrotic ingrowth that shrinks the mesh. In groin hernia repair, flat meshes are applied in the delicate inguinal surrounding where uncontrolled development of a scar plate can impair movement and may incorporate the sensitive nerves crossing this area. Complications deriving from mesh fixation and nerve entrapment are frequent and unpleasant for patients. To remedy these problems, a multila…

Malemedicine.medical_specialtymedicine.medical_treatment0206 medical engineeringBiomedical EngineeringNeovascularization PhysiologicMedicine (miscellaneous)Connective tissueHernia InguinalBioengineering02 engineering and technologytissue regeneration030204 cardiovascular system & hematologyPolypropylenesProsthesis DesignProsthesis ImplantationBiomaterialsAbdominal wallarteries03 medical and health sciencesangiogenesis0302 clinical medicineregenerative scaffoldsBiopsyHumansMedicineHerniaHerniorrhaphymedicine.diagnostic_testGroinbusiness.industryGeneral MedicineveinsHernia repairmedicine.disease020601 biomedical engineeringSurgeryInguinal herniamedicine.anatomical_structureinguinal herniaFemaleImplantbusinessprostheses
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Pluronic nanoparticles as anti-oxidant carriers for polymers

2016

Abstract The immobilization of anti-oxidant stabilizers for polymers, particularly naturally occurring systems, can be considered a valuable route for preventing their migration, volatilization, thermo-degradation and decomposition at typical high processing temperatures, as well as for enhance their solubility in polymers. In this work, an innovative approach for the immobilization of naturally occurring stabilizer, through the encapsulation in copolymer nanoparticles, is proposed. Pluronic nanoparticles (PNPs), based on PEO-PPO-PEO, (PEO: poly (ethylene oxide); PPO: poly(propylene oxide)), without and with quercetin, Q, have been successfully formulated and the critical micellar condition…

Materials Chemistry2506 Metals and AlloysAnti-oxidant carrierMaterials sciencePEO-PPO-PEO nanoparticlePolymers and PlasticsNanoparticle02 engineering and technologyCondensed Matter Physic010402 general chemistry01 natural scienceschemistry.chemical_compoundDynamic light scatteringPolymer chemistryMaterials ChemistryPhoto-oxidationMechanics of MaterialPropylene oxideSolubilitychemistry.chemical_classificationPolymers and PlasticEthylene oxideAnti-oxidant carrier; PEO-PPO-PEO nanoparticles; Photo-oxidation; Condensed Matter Physics; Mechanics of Materials; Polymers and Plastics; Materials Chemistry; 2506; Metals and Alloystechnology industry and agricultureMetals and AlloysPolymerPoloxamer021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical scienceschemistryChemical engineeringMechanics of MaterialsPEO-PPO-PEO nanoparticles25060210 nano-technologyEthylene glycol
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Polymeric micelles as a new generation of anti-oxidant carriers

2017

A promising strategy to immobilize a natural stabilizer in polymeric films is presented. Par-Ticularly, nevadensin (N, a natural basil flavonoid) molecules have been encapsulated in Pluronic F-127 micelles [F127, a triblock copolymer poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide)] and the obtained nanoparticles have been introduced in poly(ethylene glycol), PEG [otherwise known as poly(ethylene oxide), PEO]. In order to verify the effectiveness of the micelles as anti-oxidant carriers, PEG-based films have been subjected to artificial weathering. The encapsulation of anti-oxidant molecules allows the enhancement of N solubility in PEG, leading to advanced materials with enh…

Materials Chemistry2506 Metals and AlloysAnti-oxidant carrierPhoto-oxidative stabilityPolymers and PlasticsGeneral Chemical EngineeringPoly(ethylene oxide)Nanoparticlemacromolecular substances02 engineering and technology01 natural sciencesMicellechemistry.chemical_compoundAnti-oxidant carriers; Photo-oxidative stability; Poly(ethylene oxide); Polymeric micelles; Chemical Engineering (all); Polymers and Plastics; Materials Chemistry; 2506; Metals and AlloysPolymeric micellePEG ratioCopolymerMaterials ChemistryChemical Engineering (all)Propylene oxidePolymers and PlasticEthylene oxidetechnology industry and agricultureMetals and AlloysPoloxamer021001 nanoscience & nanotechnology010406 physical chemistry0104 chemical scienceschemistryChemical engineeringPolymeric micelles25060210 nano-technologyAnti-oxidant carriersEthylene glycol
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Rheological, mechanical and morphological characterization of monopolymer blends made by virgin and photo-oxidized polypropylene

2021

In this work, monopolymer blends of virgin polypropylene and photo-oxidized polypropylene were prepare and characterized. The polypropylene samples were subjected to accelerated ageing to simulate the effects of outdoor exposure of polypropylene. After exposure, samples were pelletized and mixed with the same virgin polymer. The rheological, mechanical and morphological characterization was conducted on both the polymers and the blends. Both viscosity and mechanical properties decrease with increases in the content of recycled, photo-oxidized components and of the level of degradation of this component. In addition, the experimental data were compared with a model that takes into account bo…

Materials scienceAccelerated weathering Additive model Monopolymer blend Polypropylene02 engineering and technologyManagement Monitoring Policy and Law010402 general chemistry01 natural sciencesViscositychemistry.chemical_compoundRheologyGE1-350General Materials ScienceComposite materialadditive modelWaste Management and Disposalaccelerated weatheringchemistry.chemical_classificationPolypropylenemonopolymer blendPolymer021001 nanoscience & nanotechnology0104 chemical sciencesCharacterization (materials science)Environmental sciencesSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryDegradation (geology)0210 nano-technologypolypropylene
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Ionic conduction through single-pore and multipore polymer membranes in aprotic organic electrolytes

2021

Abstract We experimentally characterize the ionic conduction of single and multipore nanoporous membranes in aprotic organic electrolytes. To this end, soft-etched (SE) membranes with pore diameters in the nanometer range and track-etched (TE) membranes with pore diameters in the tens of nanometers range are investigated. In aqueous conditions, the membrane ionic conduction rates follow the same trend of the bulk solution conductivities. However, the ionic transport through the narrow SE-nanopores dramatically decreases in aprotic electrolytes due to the formation of solvated metal cations and their adsorption on the pore surface. The current-voltage recordings of single conical nanopores i…

Materials scienceAqueous solutionSynthetic membraneIonic bondingFiltration and Separation02 engineering and technologyElectrolyte010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistry0104 chemical scienceschemistry.chemical_compoundMembranechemistryChemical engineeringPropylene carbonateIonic conductivityGeneral Materials SciencePhysical and Theoretical Chemistry0210 nano-technologyAcetonitrileJournal of Membrane Science
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Copolymer−Cyclodextrin Inclusion Complexes in Water and in the Solid State. A Physico-Chemical Study

2008

The formation of inclusion complexes (ICs) composed of cyclodextrins (CDs) and poly(ethylene oxides)-poly(propylene oxides)-poly(ethylene oxides) (PEO-PPO-PEO) was studied. To this purpose, native and hydroxypropyl cyclodextrins with different cavity size were chosen. The PEO-PPO-PEO copolymers were selected to study the role of the molecular weight, keeping constant the hydrophilic/hydrophobic ratio, and the hydrophilicity. The volumetric studies at 25 degrees C allowed to determine the equilibrium constant and the volume change for the IC formation in water as well as the IC stoichiometry. Surface tension experiments evidenced that the copolymer and the CD interfacial behavior is controll…

Materials scienceChemical PhenomenaPolymersPolypropylenesPolyethylene GlycolsSurface tensionDifferential scanning calorimetryPhase (matter)Copolymer Cyclodextrin calorimetrySpectroscopy Fourier Transform InfraredMaterials ChemistryCopolymerSurface TensionOrganic chemistryPhysical and Theoretical ChemistryFourier transform infrared spectroscopyEquilibrium constantchemistry.chemical_classificationCyclodextrinsCyclodextrinChemistry Physicaltechnology industry and agricultureWaterSurfaces Coatings and FilmsChemical engineeringchemistrySolventsThermodynamicsStoichiometry
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Morphology, Rheological and Mechanical Properties of Isotropic and Anisotropic PP/rPET/GnP Nanocomposite Samples

2021

The effect of graphene nanoplatelets (GnPs) on the morphology, rheological, and mechanical properties of isotropic and anisotropic polypropylene (PP)/recycled polyethylene terephthalate (rPET)-based nanocomposite are reported. All the samples were prepared by melt mixing. PP/rPET and PP/rPET/GnP isotropic sheets were prepared by compression molding, whereas the anisotropic fibers were spun using a drawing module of a capillary viscometer. The results obtained showed that the viscosity of the blend is reduced by the presence of GnP due to the lubricating effect of the graphene platelets. However, the Cox–Merz rule is not respected. Compared to the PP/rPET blend, the GnP led to a slight incre…

Materials scienceGeneral Chemical EngineeringModulusCompression moldingmechanical propertiesArticlechemistry.chemical_compoundnanocompositesPolyethylene terephthalateGeneral Materials ScienceComposite materialQD1-999Elastic moduluspolyethylene terephthalate (PET)PolypropyleneNanocompositenanocompositepolypropylene (PP)Viscometerpolymer blendgraphene nanoplatelets (GnPs)ChemistrychemistryrheologyPolymer blendpolymer blendsNanomaterials
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