Search results for "Pyridoxal"

showing 6 items of 16 documents

CCDC 669022: Experimental Crystal Structure Determination

2009

Related Article: S.Floquet, M.C.Munoz, R.Guillot, E.Riviere, G.Blain, J.-A.Real, M.-L.Boillot|2009|Inorg.Chim.Acta|362|56|doi:10.1016/j.ica.2008.02.057

Space GroupCrystallographyCrystal System(Hydrogen pyridoxal thiosemicarbazonato-NOS)-(pyridoxal thiosemicarbazonato-NOS)-iron(iii) hydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 669023: Experimental Crystal Structure Determination

2009

Related Article: S.Floquet, M.C.Munoz, R.Guillot, E.Riviere, G.Blain, J.-A.Real, M.-L.Boillot|2009|Inorg.Chim.Acta|362|56|doi:10.1016/j.ica.2008.02.057

Space GroupCrystallographybis(Hydrogen pyridoxal thiosemicarbazonato-NOS)-iron(iii) perchlorate dihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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A simple high-performance liquid chromatography (HPLC) method for the measurement of pyridoxal-5-phosphate and 4-pyridoxic acid in human plasma.

2014

Abstract Background Low concentration of plasma pyridoxal-5-phosphate (PLP) is associated with hyperhomocysteinemia and inflammation. Most methods for the measurement of plasma PLP require large specimen volume and involve the use of toxic reagents. Methods We have developed a HPLC method for the measurement of PLP and 4-pyridoxic acid (4-PA) in plasma, which requires small specimen volume. The samples are prepared without adding any toxic reagents. Furthermore, we have examined whether intake of vitamin B 6 affects the concentration of plasma PLP and 4-PA. Results The coefficient of variation of the method was 6% and the recovery of the added vitamin in plasma was about 100%. The concentra…

VitaminVitamin bAdultMaleHyperhomocysteinemiaPyridoxal 5-PhosphatePyridoxic AcidAdolescentCoefficient of variationClinical BiochemistryBiochemistryHigh-performance liquid chromatographychemistry.chemical_compoundYoung AdultmedicineHumansHplc methodChromatography High Pressure LiquidAgedChromatographyBiochemistry (medical)General MedicineMiddle Agedmedicine.diseaseHealthy VolunteerschemistryPyridoxal PhosphateCalibrationlipids (amino acids peptides and proteins)FemaleBlood Chemical AnalysisPyridoxic AcidClinica chimica acta; international journal of clinical chemistry
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Histamine, histidine, and growth-phase mediated regulation of the histidine decarboxylase gene in lactic acid bacteria isolated from wine

2006

Fermented foods are frequently contaminated by histamine that is generated by microorganisms with histidine decarboxylase activity. The ingestion of large amounts of histamine can cause serious toxicological problems in humans. A study of the effects of histamine, histidine, and growth phase on histamine production by lactic acid bacteria isolated from wine is reported here. With northern blots and specific activity analysis, we observed that histidine induces the expression of the histidine decarboxylase gene (hdc) and that histamine causes a decrease in the expression of this gene. The expression of hdc is also mediated by the bacterial growth phase. Histidine and histamine do not affect …

WineHistidine DecarboxylaseMicrobiologyGene Expression Regulation EnzymologicMicrobiologychemistry.chemical_compoundLactobacillusGeneticsHistidinePediococcusMolecular BiologyHistamine ProductionHistidineHistamine N-methyltransferasebiologyfood and beveragesbiology.organism_classificationHistidine decarboxylaseGram-Positive CocciLactobacillusBiochemistrychemistryPyridoxal PhosphateHistidine decarboxylase activityPediococcusLeuconostocHistamineHistamineFEMS Microbiology Letters
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Evidence for essential primary amino groups in a bacterial coupling factor F1ATPase.

1980

Abstract We have found that the binding of pyridoxal-5′-phosphate to 6 primary amino groups leads to the inactivation of the enzyme. A preferential reaction of pyridoxal-5′-phosphate with the α-subunits of this enzyme can be demonstrated. The reactivity of the amino groups is influenced by various effectors. In the presence of ATP the inhibition of the ATPase activity is noncompetitive.

chemistry.chemical_classificationAdenosine TriphosphatasesPrimary (chemistry)Binding SitesChemistryStereochemistryEffectorCell MembraneBiophysicsCell BiologyBiochemistryMicrococcusCoupling (electronics)Structure-Activity RelationshipEnzymeBiochemistrySolubilityPyridoxal PhosphateAtpase activityReactivity (chemistry)Amino AcidsMolecular BiologyBiochemical and biophysical research communications
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A wide family of pyridoxal thiosemicarbazone ferric complexes: Syntheses, structures and magnetic properties

2009

Abstract This study reports the syntheses and the characterization of 12 ferric complexes of pyridoxal thiosemicarbazone. The richness of the coordination chemistry of this ligand is highlighted by the modulation of its charge from neutral H 2 L to anionic L 2− , thus leading to a wide family of ferric compounds with charge varying from +3 to −1. The structures of complexes [Fe(HL) 2 ]ClO 4  · 2H 2 O and [Fe(HL)L] · 4.5H 2 O were solved and discussed with a particular attention brought to the intermolecular interactions occurring between the complexes. The investigation of magnetic properties of these compounds revealed that two of them are in the HS state at any temperature, whereas the ot…

chemistry.chemical_classificationFerric CompoundsLigandStereochemistryIntermolecular forceCoordination complexPyridoxal thiosemicarbazoneInorganic ChemistryCrystallographychemistryMaterials ChemistrymedicineFerricPhysical and Theoretical ChemistryElectronic propertiesmedicine.drugInorganica Chimica Acta
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