Search results for "QUARTZ"

Luminescence of silicon Dioxide — silica glass, α-quartz and stishovite

2011

Abstract This paper compares the luminescence of different modifications of silicon dioxide — silica glass, α-quartz crystal and dense octahedron structured stishovite crystal. Under x-ray irradiation of pure silica glass and pure α-quartz crystal, only the luminescence of self-trapped exciton (STE) is detected, excitable only in the range of intrinsic absorption. No STE luminescence was detected in stishovite since, even though its luminescence is excitable below the optical gap, it could not be ascribed to a self-trapped exciton. Under ArF laser excitation of pure α-quartz crystal, luminescence of a self-trapped exciton was detected under two-photon excitation. In silica glass and stishov…

Toxicity of gold-nanoparticles: Synergistic effects of shape and surface functionalization on micromotility of epithelial cells

2010

Nanoparticle exposure is monitored by a combination of two label-free and non-invasive biosensor devices which detect cellular shape and viscoelasticity (quartz crystal microbalance), cell motility and the dynamics of epithelial cell-cell contacts (electric cell-substrate impedance sensing). With these tools we have studied the impact of nanoparticle shape on cellular physiology. Gold (Au) nanoparticles coated with CTAB were synthesized and studied in two distinct shapes: Spheres with a diameter of (43 ± 4) nm and rods with a size of (38 ± 7) nm × (17 ± 3) nm. Dose-response experiments were accompanied by conventional cytotoxicity tests as well as fluorescence and dark-field microscopy to v…

Thickness-dependent properties of ultrathin bismuth and antimony chalcogenide films formed by physical vapor deposition and their application in ther…

2021

This work was supported by the European Regional Development Fund (ERDF) project No 1.1.1.1/16/A/257. J. A. acknowledges the ERDF project No. 1.1.1.2/1/16/037. Institute of Solid State Physics, University of Latvia, Latvia as the Center of Excellence has received funding from the European Union's Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017 TeamingPhase2 under grant agreement No. 739508, project CAMART2 . The raw/processed data required to reproduce these findings cannot be shared at this time as the data also form a part of an ongoing study.

Enzymatic Synthesis and Surface Deposition of Tin Dioxide using Silicatein-α

2011

Nanostructured tin dioxide was synthesized by making use of the catalytic activity of silicatein-α. TEM, HRTEM, and XRD revealed the formation of cassiterite SnO2. Surface bound silicatein retains its biocatalytic activity. This was demonstrated by immobilizing silicatein on glass surfaces using a histidine-tag chelating anchor. The subsequent deposition of SnO2 on glass was monitored by quartz crystal microbalance (QCM) measurements and scanning electron microscopy (SEM). This new aspect of silicatein activity toward the formation of metal oxides other than SiO2, TiO2, and BaTiO3 opens up new vistas in composite material synthesis.

Deposition Kinetics and Compositional Control of Vacuum-Processed CH3NH3PbI3 Perovskite

2020

Halide perovskites have generated considerable research interest due to their excellent optoelectronic properties in the past decade. To ensure the formation of high-quality semiconductors, the deposition process for the perovskite film is a critical issue. Vacuum-based processing is considered to be a promising method, allowing, in principle, for uniform deposition on a large area. One of the benefits of vacuum processing is the control over the film composition through the use of quartz crystal microbalances (QCMs) that monitor the rates of the components in situ. In metal halide perovskites, however, one frequently employed component or precursor, CH3NH3I, exhibits nonstandard sublimatio…

TSL and fractional glow study of Ge-doped α-quartz

2013

Crystalline α-quartz doped with 0.1wt% and 0.9wt% germanium was studied using TSL and FGT equipment. Sample was chosen because previously it is known that Ge in quartz is efficient trap for electrons, therefore it could be used for detection of hypothetic self-trapped hole in α-quartz. However previous investigations of ODMR and TSL shows that in α-quartz the hole is still mobile and trapping occurs only on defect states. The activation energies for both TSL peaks are found by fractional glow and Hoogenstraaten method. The TSL distribution changes depending on Ge concentration and also on irradiation type. The TSL peaks below 70K in quartz doped with Ge could belong to hole trapped on Ge.

Biochemical Applications of Solid Supported Membranes on Gold Surfaces: Quartz Crystal Microbalance and Impedance Analysis

2004

?Short Distance?-Variabilit�t der Na-Gehalte niedrigmetamorpher mit Albit ber�hrungsparagenetisch koexistierender Hellglimmer

1973

White micas coexisting with albite, quartz, chlorite, and clinozoisite in low-grade schists of the Beaume Valley (Massif Central, France) have been analyzed by standard microprobe techniques. As the micas of an albite-rich thin section show significantly higher Na-contents than those of an albite-poor one of the same rock sample, the application of the muscovite-albite-geothermometer results in inconsistent temperature values. Thus the analyses may indicate that the distribution of sodium between coexisting white micas and albite not only depends on temperature and pressure but also on the chemical potentials of the alkalies in the metamorphic fluid phase.

Cell motility probed by noise analysis of thickness shear mode resonators.

2006

The quartz crystal microbalance (QCM) technique is an emerging bioanalytical tool to study the behavior of animal cells in vitro. Due to the high interfacial sensitivity of thickness shear mode (TSM) resonators it is possible to monitor the formation and breakage of cell-matrix interactions and changes in viscoelasticity of the cell bodies, as well as minute cell volume alterations by the time course of their resonance frequency even with millisecond time resolution. We found that mammalian MDCK-II cells grown on TSM resonators impose characteristic fluctuations on the resonance frequency, which are a quantitative indicator for dynamic activities of the cells on the surface and report on th…

Mineral and trace element composition of the Lokpanta oil shales in the Lower Benue Trough, Nigeria

2011

Abstract The concentrations of minerals and trace elements in the Lokpanta oil shale from the Lower Benue Trough, Nigeria have been determined by X-ray diffraction (XRD) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), respectively. X-ray diffraction data were evaluated using the SIROQUANT™ interactive data processing system based on Rietveld interpretation methods. A new method of trace element determination in oil shale, involving LA-ICP-MS analysis of glass beads prepared by fusing oil shale ash on an iridium strip heater was used, and the accuracy of the method was assessed by including a standard shale reference material (SGR-1b) in the analysis program. The…