Search results for "QUARTZ"

Partially Reversible Adsorption of Annexin A1 on POPC/POPS Bilayers Investigated by QCM Measurements, SFM, and DMC Simulations

2005

The kinetics of annexin A1 binding to solid-supported lipid bilayers consisting of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC)/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphoserine (POPS; 4:1) has been investigated as a function of the calcium ion concentration in the bulk phase. Quartz crystal microbalance measurements in conjunction with scanning force microscopy, fluorescence microscopy, and computer simulations indicate that at a given Ca2+ concentration annexin A1 adsorbs irreversibly on membrane domains enriched in POPS. By contrast, annexin A1 adsorbs reversibly on the POPC-enriched phase, which is composed of single POPS molecules embedded within a POPC matrix. The overall are…

Crystal-Plastic Deformation, Recovery and Recrystallisation of Quartz

2009

As stated in the introduction, this chapter is included because of the special importance of quartz to estimate metamorphic conditions during and after mylonitisation. The theory behind crystal-plastic deformation is treated elsewhere (e.g. Passchier & Trouw 2005). The main optical expression of crystal-plastic deformation is smooth, non-patchy undulose extinction. Elongated grains with such undulose extinction, sometimes accompanied by deformation lamellae, are indicative for low-temperature deformation. At slightly higher temperatures recovery produces subgrains and recrystallisation tends to substitute the old deformed grains by small new ones. Three types of recrystallisation can be dis…

Medium-Grade Mylonites

2009

The temperature range for the formation of this group of mylonites is approximately 500 to 650 °C. In medium-grade mylonites quartz is usually fully recrystallised, mainly by subgrain rotation, and has grown to a polygonal crystalloblastic fabric of strain free grains with an average grain size exceeding about 50 micrometers.

Protomylonite, Mylonite and Ultramylonite

2009

The objective of this chapter is to show how variation of strain intensity can be judged in thin section. Usually this kind of variation can best be observed in low-grade mylonites where the percentage of porphyroclasts decreases progressively with strain intensity. However, the percentage of matrix is highly dependent on mineralogical composition (e.g. quartz and biotite tend to convert to matrix readily). Compositional banding in gneiss can therefore result in mylonitic banding of apparent strain variation, which in fact only reflects variation in composition of the parent rock. Several examples of ultramylonite are derived from quartzitic rocks that tend to form few or no porphyroclasts …

Low-Grade Mylonites

2009

The temperature range for these mylonites is thought to be roughly between 250 and 500 °C. There is a gradual transition between cataclasites and low-grade mylonites. Whereas many feldspar porphyroclasts in low-grade mylonites still show fracturing by cataclasis, the quartz is usually deformed by crystal-plastic processes as shown by its change in shape and by undulose extinction. At increasing temperature bulging recrystallisation starts to manifest itself along the lobate contacts and eventually recrystallisation by subgrain rotation takes over (Chapter 10).

Reactivity of the Superheavy Element 115, Mc, and Its Lighter Homologue, Bi, with Respect to Gold and Hydroxylated Quartz Surfaces from Periodic Rela…

2021

Adsorption energies (Eads) of the superheavy element (SHE) Mc, its lighter homologue (Bi), as well as of another superheavy element Nh and some lighter homologues of SHEs on gold and hydroxylated quartz surfaces are predicted via periodic relativistic density functional theory calculations. The aim of this study is to support "one-atom-at-a-time" gas-phase chromatography experiments that are examining the reactivity and volatility of Mc. The obtained Eads values of the Bi and Mc atoms on the Au(111) surface are >200 kJ/mol. On the hydroxylated quartz surface, Mc should adsorb with a minimal energy of 58 kJ/mol. On both types of surfaces, Eads(Mc) should be ∼100 kJ/mol smaller than Eads(Bi) …

Palaeomagnetic results from the late Precambrian Chela Group of southwest Angola (Dataset)

1992

Experimental and theoretical studies on electropolymerization of polar amino acids on platinum electrode

2017

International audience; The anodic oxidation of polar amino acids (L-serine, L-threonine, L-asparagine, and L-glutamine) in aqueous electrolyte on smooth platinum electrode was carried out by cyclic voltammetry coupled to electrochemical quartz crystal microbalance (EQCM). pH (zwitterion, acidic and alkaline) effects on their electrochemical behavior were examined. The maximum current values are measured for zwitterion species. In addition, the current increases with increasing of concentration and scan rate, and decreases with increasing pH. The resulting passivation was studied by spectroscopic analysis such as attenuated total reflection FT infrared spectroscopy (ATR-FTIR), X-ray photoel…

High sensing potentialities of tetra-tert-butyl-metallophthalocyaninesbased acoustic microsensors for xylenes measurement in air at room temperature

2022

International audience; Xylenes, classified as Volatil Organic Compounds, is a very harmful pollutant for human health that can be absorbed into the body via all exposures routes: inhalation, ingestion, or dermal. As defined by the US Environmental Protection Agency, the occupational exposure limi-tes are set to 100 ppm while the guidelines in non-occupational context are fixed to 50 ppm. For the concentration measurements in the at-mosphere, authorities commonly used sampling methods with post-exposure chemical titration or chromatography. A strong interest remains on the development of low cost, low power consumption and easy implemented microsensors able to deliver real-time indicative m…

Elastic Geobarometry for Anisotropic Inclusions in Anisotropic Host Minerals: Quartz-in-Zircon

2021

Current models for elastic geobarometry have been developed with the assumption that the host and/or inclusion minerals are elastically isotropic. This assumption has limited applications of elastic thermobarometry to mineral inclusions contained in cubic quasi-isotropic host minerals (e.g., garnet). Here, we report a new elastic model that takes into account the anisotropic elastic properties and relative crystallographic orientation (RCO) of a host-inclusion system where both minerals are noncubic. This anisotropic elastic model can be used for host-inclusion elastic thermobarometric calculations provided that the RCO and elastic properties of both the host and inclusion are known. We the…