Search results for "QUARTZ"
showing 10 items of 239 documents
Vapor-phase introduction of alkyltin compounds in atomic absorption spectrophotometry
1990
Abstract Different systems for the introduction of alkyltin compounds in atomic absorption spectrophotometry using the vapor-phase introduction approach have been compared. Samples and standards were introduced in both quartz cell and flame atomizer using a vertical and a horizontal reactor. The better sensitivity was obtained with the quartz cell and the horizontal reactor.
Sixfold coordinated phosphorus by oxygen in AlPO4 quartz homeotype under high pressure.
2007
International audience; AlPO4 belongs to the berlinite quartz homeotype family, which has been the subject of intense high pressure research triggered by the supposed existence of reversible pressure induced amorphization. New x-ray diffraction experiments, complemented with ab initio calculations, demonstrate the existence of two high pressure crystalline polymorphs and show that AlPO4 share the same two stage densification mechanism as silica. In first place a compact hexagonal sublattice of oxygen atoms is formed. In a second step the cations redistribute in the interstices giving rise to a monoclinic distorted CaCl2 phase. The most outstanding feature of the new phase is that phosphorou…
X-ray diffraction microstructure analysis of mullite, quartz and corundum in porcelain insulators
2005
Abstract The X-ray diffraction microstructure analysis has been performed on commercial samples of the silica and alumina porcelain insulators obtained at 1300 °C, with the same time of firing. The study was carried out on mullite, corundum and quartz by applying several integral breadth methods (i.e. the Williamson–Hall analysis, the Langford method and the Halder–Wagner approximation) and the Fourier analysis (Warren–Averbach method). The apparent crystallite sizes determined for the mullite are direction-dependent (anisotropic) and within each group of samples, on average, the greatest values are obtained along the direction [0 0 1]. With regard to the microstructure of the corundum and …
Versuche zur Lichtbeugung an Ultraschall in Quarz
1967
Diffraction of a continuous laser beam (He-Ne) by standing ultrasonic waves of 260 Mcs/s in quartz has been investigated. Besides the principal maximum at exact Bragg-incidence, the variation of intensity of first order diffraction pattern with tilt angle shows up to 15 secondary maxima. The effective depth of sound field and the maximum variation of refractive index were determined by comparison with the theory ofBhatia andNoble.
Effective hydrostatic limits of pressure media for high‐pressure crystallographic studies
2007
The behavior of a number of commonly used pressure media, including nitrogen, argon, 2-propanol, a 4:1 methanol–ethanol mixture, glycerol and various grades of silicone oil, has been examined by measuring the X-ray diffraction maxima from quartz single crystals loaded in a diamond-anvil cell with each of these pressure media in turn. In all cases, the onset of non-hydrostatic stresses within the medium is detectable as the broadening of the rocking curves of X-ray diffraction peaks from the single crystals. The onset of broadening of the rocking curves of quartz is detected at ∼9.8 GPa in a 4:1 mixture of methanol and ethanol and at ∼4.2 GPa in 2-propanol, essentially at the same pressures …
The formation of peak rings in large impact craters.
2016
The Chicxulub impact crater, known for its link to the demise of the dinosaurs, also provides an opportunity to study rocks from a large impact structure. Large impact craters have “peak rings” that define a complex crater morphology. Morgan et al. looked at rocks from a drilling expedition through the peak rings of the Chicxulub impact crater (see the Perspective by Barton). The drill cores have features consistent with a model that postulates that a single over-heightened central peak collapsed into the multiple-peak-ring structure. The validity of this model has implications for far-ranging subjects, from how giant impacts alter the climate on Earth to the morphology of crater-dominated …
Textures and c-axis orientations of deformed quartz crystals from porphyric dikes of the Alpine »Root Zone« (Western Alps)
1986
Deformation textures and c-axis preferred orientations of quartz phenocrysts from porphyric dikes of the Alpine »Root Zone« have been formed under conditions of greenschist to low amphibolite facies. It is shown that the deformation textures as shear planes and kink bands, boudins, grain boundary sutures, subgrains, coarse and fine recrystallized grains, deformation lamellae and fractures are developed in a chronological sequence during first increasing and later decreasing temperatures. The c-axis orientations are chiefly influenced by kinking during the early stage of metamorphism and later by recrystallization but not by the initial orientations of the c-axes. The shape of crossed-girdle…
Microstructural analysis of shearband boudin - preliminary results
2011
The internal structure of a shearband boudin resulting from an original igneous, hydrothermal or metamorphic segregation tabular rigid body is a subject of scientific interest. It allows understanding the deformation mechanisms acting on homogeneous quartz aggregate activated during simple shear progressive deformation. This communication is focused on the characterization of two main structural aspects: (i) the existence of different internal domains in shearband boudins; (ii) the development of internal structures related with its genesis and evolution, namely, secondary shear planes c’ type-I and c’ type-II, parameter B-t (mass accumulation sector on blunt tip of shearband boudin) and S-…
Carbonyl compounds of Rh, Ir, and Mt: electronic structure, bonding and volatility
2020
With the aim to render assistance to future experiments on the production and investigation of chemical properties of carbonyl compounds of element 109, Mt, calculations of the molecular properties of M(CO)4 and MH(CO)4, where M = Rh, Ir, and Mt, and of the products of their decomposition, M(CO)3 and MH(CO)3, were performed using relativistic Density Functional Theory and Coupled-Cluster methods implemented in the ADF, ReSpect and DIRAC software suites. According to the results, MH(CO)4 should be formed at experimental conditions from the M atom with a mixture of CO and He gases. The calculated first M–CO bond dissociation energies (FBDE) of Mt(CO)4 and MtH(CO)4 turned out to be significant…
Sedimentary features reveal transport paths for Holocene sediments on the Kristianstad coastal plain, SE Sweden.
2017
AbstractWe have investigated coastal and aeolian deposits on the Kristianstad plain in southernmost Sweden by a combination of methods that has yielded data on sedimentary features such as grain-size variations, shape and character of quartz grain surfaces (determined in light microscope and scanning electron microscope), and mineralogical composition. Such sedimentary techniques have been not applied to coastal deposits in this part of the Baltic Sea region before. The littoral, foredune and parabolic dune sands are sedimentologically similar, only a slight grain-size transformation by aeolian processes in the foredune was observed. Sand in straight-crested dunes, on the other hand, origin…