Search results for "Quadrupole ion trap"
showing 6 items of 26 documents
A highly selective laser ion source for bunched, low emittance beam release
2004
A novel type of resonance ionization laser ion source (RILIS) is under development, which combines the advantages of laser ionization with those of a source-implemented ion trap. This laser ion source trap (LIST) system, based on a gas-filled linear radio-frequency quadrupole ion trap, decouples the evaporation and ionization process by introduction of a primary surface ion repeller. Apart from significantly enhancing the selectivity in radioactive ion beam production, optimum control on the temporal pulse structure and the emittance of the generated laser ion bunch is obtained. A variety of operational modes from quasi-dc to microseconds-bunched ion beams with variable repetition rate can …
Isotope separation by nonlinear resonances in a Paul trap
1996
Deviations from the ideal quadrupole potential in a Paul ion trap create nonlinear resonances at certain operating points inside the stability diagram, where in the absence of potential pertubations storing times are very long. In the presence of those pertubations, however, the ions are lost from the trap. Since these resonances are mass dependent and the mass resolution is of the order of 100 it can be used to separate isotopes of a given element by choosing suitable trap operating conditions. Experiments on a natural mixture of Eu+ ions of mass 151 and 153 show that in a simple way, by proper choice of the operating point, the ions can be completely separated and laser-induced optical sp…
Nonlinear collective oscillations of an ion cloud in a Paul trap
1997
In an experiment using a Paul trap, we create a ${\mathrm{H}}_{2}^{+}$ ion cloud by electron ionization of the background gas at ${10}^{\ensuremath{-}9}$-mbar residual pressure. Exciting the ions parametrically at twice the frequency of the secular motion of ions in the $r$ or $z$ direction, we observe a narrow resonance at some distance from the motional resonance center if the amplitude of the exciting field exceeds a threshold value. The threshold value decreases with increasing ion number. Since the narrow resonance does not shift with ion number, we interpret it as a collective resonance of the center of mass of the ion cloud. The resonance shape exhibits the typical form of a driven a…
Ultrahigh-Throughput Proteomics Using Fast RPLC Separations with ESI-MS/MS
2005
We describe approaches for proteomics analysis using electrospray ionization-tandem mass spectrometry coupled with fast reversed-phase liquid chromatography (RPLC) separations. The RPLC separations used 50-microm-i.d. fused-silica capillaries packed with submicrometer-sized C18-bonded porous silica particles and achieved peak capacities of 130-420 for analytes from proteome tryptic digests. When these separations were combined with linear ion trap tandem mass spectrometry measurements, approximately 1000 proteins could be identified in 50 min from approximately 4000 identified tryptic peptides; approximately 550 proteins in 20 min from approximately 1800 peptides; and approximately 250 prot…
Comparison of four mass analyzers for determining carbosulfan and its metabolites in citrus by liquid chromatography/mass spectrometry
2006
Four liquid chromatography/mass spectrometry (LC/MS) systems, equipped with single quadrupole, triple quadrupole (QqQ), quadrupole ion trap (QIT) and quadrupole time-of-flight (QqTOF) mass analyzers, were evaluated for the analysis of carbosulfan and its main transformation products. The comparison of quantitative aspects (sensitivity, precision and accuracy) was emphasized. Results showed that the triple quadrupole instrument reaches at least 20-fold higher sensitivity (LOD from 0.04 to 0.4 microg kg(-1)) compared to the single quadrupole (4-70 microg kg(-1)), the QIT (4-25 microg kg(-1)) and the QqTOF (4-23 microg kg(-1)) instruments. Recoveries were over 70% for all the analytes, except …
Anisotropy-Induced Effects in the Dynamics of an Ion Confined in a Two-Dimensional Paul Trap
2006
We investigate the role of anisotropy in the dynamics of a single trapped ion interacting with two orthogonal laser beams, considering how it modifies a scheme for the generation of Schrödinger cat states and the so called parity effect in two-dimensional isotropic Paul traps. We find that anisotropy gives rise to a richer class for the generated states and to a larger number of observables sensitive to the parity of the number of excitation of the vibrational motion of the ion.