Search results for "RADIOCHEMISTRY"
showing 10 items of 273 documents
Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule
2004
The speciation of Mn, Fe, As and Zn in a fast-growing (0.02mm/yr), shallow-marine ferromanganese nodule has been examined by micro X-ray fluorescence, micro X-ray diffraction, and micro X-ray absorption spectroscopy. This nodule exhibits alternating Fe-rich and Mn-rich layers reflecting redox variations in water chemistry. Fe occurs as two-line ferrihydrite. The As is strictly associated with Fe and is mostly pentavalent, with an environment similar to that of As sorbed on or coprecipitated with synthetic ferrihydrite. The Mn is in the form of turbostratic birnessite with ~;10 percent trivalent manganese in the layers and probably ~;8 percent corner-sharing metal octahedra in the interlayer…
Magnetic field effects on tritium release from neutron-irradiated beryllium pebbles
2007
The effects of temperature, magnetic field (MF), and ionizing radiation on the release of tritium from the Be pebbles irradiated in the BERYLLIUM experiment in 1994 in Petten, The Netherlands (irradiation neutron fluence 1.24×10 25 m -2 , irradiation temperature 780 K, and 3 H content 7 appm) were investigated in this study. Simultaneous action of these factors corresponds to the real operating conditions of the blanket of a fusion reactor. The total amount of tritium in a separate pebble, the chemical forms of localized tritium (T 0 , T 2 , and T + ), and the tritium distribution in the pebble volume were determined by a lyomethod (dissolution). Thermoannealing experiments were performed a…
Tritium release behavior of beryllium pebbles after neutron irradiation between 523 and 823K
2013
Abstract Post-irradiation tritium release from the Pebble Bed Assembly (PBA) neutron-irradiated beryllium (Be) pebbles (∅ ≈ 1 mm; the total tritium inventory 2–4 GBq/g) was investigated on annealing in He + 0.1% H 2 . Temperature ramps of 2.3 K/min followed by annealing for 1 h at 1310–1320 K resulted in complete detritiation of the PBA Be pebbles. The tritium burst release occurred after a time lag of 1–6.5 h during constant temperature anneals at 1089–1180 K, with the release time measured after reaching the annealing temperature. Tritium burst release was also observed to occur during cool down. Anneals at 1089 K for 8 h and at 1045 K for 23 h caused detritiation of the PBA Be pebbles by…
Yields of neutron-rich rubidium and cesium isotopes from fast-neutron induced fission of 238U, obtained by studying their release from a thick ISOL t…
2006
Abstract In the framework of the EURISOL project, the production of neutron-rich isotopes of rubidium and cesium has been studied. The intensities of mass-separated beams of rubidium and cesium isotopes generated from a thick 238 UC x target connected to a surface ionizer have been measured. The release properties of 140 Cs and 91 Rb have been investigated. The obtained results allowed us to determine the relative fission yields of rubidium and cesium isotopes with high accuracy.
Selective laser ionization of radioactive Ni-isotopes
1997
Abstract A chemically selective laser ion source based on resonance ionization of atoms in a hot cavity has been applied in the study of Ni-isotopes at the CERN-ISOLDE on-line isotope separator. Laser ionization enhanced the yields of long-lived Ni-isotopes almost four orders of magnitude when compared to the yields obtained with the surface ionization mode of the source. As a result, high yields of long-lived Ni-isotopes were obtained. Separation efficiencies of 0.3 and 0.8% were obtained for Ni produced in uranium-carbide, produced from uranium-di-pthalocyanine, and Ta-foil targets, respectively. Ni was found to be released very slowly from the present target and ion source combination.
A new 400 ms isomer in125Ce→125La
1998
By using the IGISOL technique, adapted for the study of products of heavy ion induced fusion-evaporation reactions, it has been possible to identify a new isomer in the mass chainA=125.
The development and status of the IGISOL technique
1997
Abstract The development of the IGISOL technique since its earliest beginnings at the University of Jyvaskyla in the early '80s is reviewed. The processes involved in ion survival in the ion guide are discussed. The design and performance of ion guides for different types of reactions is summarised. The mass-separated beam quality for different skimmer systems is compared.
The role of radiolysis products in in situ luminescence of Li2O
1998
Abstract A new phenomenon of an “excess luminescence” (EL) in Li 2 O observed at 4.5–2.5 eV under light ion (H + , He + ) irradiation during the rise of temperature (>573 K ) was studied. The essence of the EL is in the rapid pulse increase of the luminescence intensity. It is proposed that this phenomenon is based on the thermo-dissociation of colloidal Li into Li lattice ions, F + and F 0 centers, and oxygen vacancies. Formed oxygen vacancies capture electrons during the irradiation and form excited F-centers, whose relaxation gives the EL. This phenomenon was reproduced using X-ray irradiation and a sample containing colloidal Li introduced by irradiation with electron accelerator to an …
Tritium localisation and release from the ceramic pebbles of breeder
2004
Magnetic field (MF) effects on the radiolysis and tritium release from Li4SiO4 (FZK) and Li2TiO3 (CEA) ceramic pebbles were investigated. The tritium chemical forms in Li4SiO4 were estimated by means of lyomethods. In the case of the neutron fluence Fn 6 10 18 nm � 2 , the tritium is mostly in the T þ form, but in the case of Fn � 10 25 nm � 2 , the T þ form accounts for 86–95% of the tritium. A high subsurface concentration of tritium is characteristic of a separate pebble and correlates with the distribution of radiation-induced defects. The MF increases the radiolysis of Li4SiO4 by 20–25%. Irradiation with electrons to 1000 MGy at 1200 K increases the grain size by 5–10%, decreasing the …
First radioactive ions charge bred in REXEBIS at the REX-ISOLDE accelerator
2003
REXEBIS is the charge breeder of the REX-ISOLDE post accelerator. The radioactive 1$^{+}$ ions produced at ISOLDE are accumulated, phase-space cooled and bunched in the REXTRAP, and thereafter injected into the EBIS with an energy up to 60 keV. The REXEBIS produced the first charge bred ions in August 2001 and has been running nearly non-stop during September to December 2001. It has delivered stable $^{39}$K$^{10+}$ and $^{23}$Na$^{6+}$ beams generated in the ion source in front of REXTRAP with a Na$^{7+}$ current exceeding 70 pA (6x10$^{7}$ p/s). Stable $^{27}$Al$^{7+}$ and $^{23}$Na$^{6+}$ from ISOLDE and also the first radioactive $^{26}$Na$^{7+}$ and $^{24}$Na$^{7+}$ beams (just 5x10$^…