Search results for "RAMAN"
showing 10 items of 1328 documents
Identification of the contaminants present on the surface of lactose for pharmaceutical use and analysis of the impact of their presence on the inter…
2018
The discovery of the problem will go through training techniques at the nanoscale characterization and chemical analysis, the discovery of the industrial problem in society Armor Proteins, the validation of a pharmaceutical lactose. With the aim to increase our knowledge on powders for food or pharmaceutical use, we propose to study the effect of manufacturing processes, shaping, granulation on the reactivity of powders. The first part is devoted to the effect of purity on interactions-Lactose Lactose and Lactose-API measured / quantified by near-field techniques (AFM, SMM, MSAFM) under ambient atmosphere and under stressful conditions storage. Deriving a second portion of the preceding par…
Inhomogeneous speed effects on H-2 vibrational line profiles in ternary mixtures
2000
International audience; A study of speed inhomogeneous broadening of the hydrogen vibrational line profiles in the collisional regime for ternary mixtures is reported. The Q(1) line of H-2 in H-2-Ar-N-2, H-2-He-Ar, and H-2-He-N-2 mixtures is investigated by high resolution stimulated Raman spectroscopy for various concentrations and temperatures. A model, successfully used for binary mixtures, is extended to ternary mixtures. An excellent agreement is obtained between theory and experiment for H-2-Ar-N-2, by using the collisional parameters previously obtained from binary mixtures study. For H-2-He-Ar and H-2-He-N-2, H-2-He collisions play a "hardening" effect in the H-2 soft speed memory m…
Speed-dependent line profile: A test of a unified model from the Doppler to the collisional regime for molecule-molecule collisions
2000
International audience; A speed-dependent line profile combining soft and hard fully correlated Dicke-narrowing collisions was recently successfully tested on Ar-broadened H-2 spectra in a wide density and temperature range. A further test for mixtures of H-2 in nitrogen molecules (instead of Ar atoms) is presented. This test is also based on high resolution Raman investigation of the isotropic Q(1) line of H-2 from low to high density at various temperatures. The same consistency of the speed-dependent line profile as for H-2-Ar is obtained for H-2-N-2 through a remarkable agreement with all the data by using a unique set of four parameters (the collisional width and shift, the kinetic fre…
Suppression of plasma contribution in femtosecond degenerate four-wave mixing (fs-DFWM) at high intensity
2007
Femtosecond degenerate four-wave mixing (fs-DFWM) experiments in CO2 exhibit a strong background due to plasma produced at high intensity (≥20 TW/cm2), when significant molecular alignment is likely to arise. This perturbing phenomenon renders the measurements of alignment very difficult. It is shown that the plasma contribution can be avoided by employing perpendicular polarizations for the two pump pulses. The effect is explained on the basis of the different diffraction angles between signals produced by molecular alignment and plasma. Copyright © 2007 John Wiley & Sons, Ltd.
Real time measurement of long parabolic optical similaritons
2008
International audience; Long optical similaritons using a Raman fibre amplifier are generated. These pulses, with a highly parabolic profile, are monitored in real time on a high speed oscilloscope. Tunability of both the temporal and spectral widths of the pulses is then investigated.
New concepts based on nonlinear polarization effects and Raman amplification in optical fibers
2009
We report a theoretical analysis and experimental demonstration of a polarization attraction process at telecommunication wavelengths in isotropic optical fibers. The combined effects of polarization attraction and Raman amplification are also presented.
Influence of third-order dispersion on the propagation of incoherent light in optical fibers
2010
International audience; We study the influence of third-order dispersion effects on the propagation of an incoherent nonlinear wave in an optical fiber system. The wave spectrum is shown to exhibit a highly asymmetric deformation characterized by a lateral spectral shoulder and the subsequent formation of an unexpected constant spectral pedestal. A kinetic approach to the problem reveals the existence of an invariant that explains in detail the essential properties of such asymmetric spectral evolution of the wave.
Collisional effects on spectral line shape from the Doppler to the collisional regime: A rigorous test of a unified model
2000
International audience; The paper presents high resolution Raman investigations of the Q(1) line of H-2 in Ar mixture from low density (Doppler regime) to high density (collisional regime) analyzed with a unique line shape profile. Measurements are performed by stimulated Raman gain spectroscopy between 300 and 1000 K in a wide density range (from 0.2 to 11 amagat). All the observed spectral features are accurately described by a unified model recently proposed by two of the authors. This model accounts for a velocity-memory process, not restricted to the usual hard and soft limits. It also includes correlation between velocity- and phase-changing collisions. An exhaustive analysis of vario…
New developments in the study of optical parabolic pulses in normally dispersive fibers
2011
International audience; We report two recent studies dealing with the evolution of parabolic pulses in normally dispersive fibers. On the one hand, the nonlinear reshaping from a Gaussian intensity profile towards the asymptotic parabolic shape is experimentally investigated in a Raman amplifier. On the other hand, the significant impact of the fourth order dispersion on a passive propagation is theoretically discussed: we numerically demonstrate flat-top, coherent supercontinuum generation in an all-normal dispersion-flattened photonic crystal fiber. This shape is associated to a strong reshaping of the temporal profile what becomes triangular.
Supercontinuum generation by cascaded intermodal Raman and FWM processes in step-index few-mode fibers
2018
International audience; This work shows that step-index few-mode fibers can be combined with a simple microchip picosecond laser to give a multi-octave spanning supercontinuum output by cascaded Raman scattering and intermodal FWM.