Search results for "RAMAN"
showing 10 items of 1328 documents
Observation of Modulational Instability induced by a dynamical Bragg grating in an optical fiber
2001
We present a detailed experimental study on Bragg Modulational Instability in a highly birefringent fiber. The originality of our scheme is that the index modulation is obtained through cross phase modulation with a beating wave.
Structural and vibrational study of Bi2Se3under high pressure
2011
The structural and vibrational properties of bismuth selenide (Bi${}_{2}$Se${}_{3}$) have been studied by means of x-ray diffraction and Raman scattering measurements up to 20 and 30 GPa, respectively. The measurements have been complemented with ab initio total-energy and lattice dynamics calculations. Our experimental results evidence a phase transition from the low-pressure rhombohedral ($R$-3$m$) phase (\ensuremath{\alpha}-Bi${}_{2}$Se${}_{3}$) with sixfold coordination for Bi to a monoclinic $C$2/$m$ structure (\ensuremath{\beta}-Bi${}_{2}$Se${}_{3}$) with sevenfold coordination for Bi above 10 GPa. The equation of state and the pressure dependence of the lattice parameters and volume …
Orbital dimerization in NaTiSi2O6: An orbital analogue of the spin-Peierls phase transition
2004
We measure the Raman scattering spectra of NaTiSi2O6, analyze the vibrational properties, and study the origin of the phase transition in this compound. In this quasi-one-dimensional S = 1/2 system we observe anomalous high-temperature phonon broadenings, and large changes of the phonon energies and line-widths across the phase transition temperature of 210 K. These results, combined with theoretical considerations, indicate that the phonon anomalies originate from an orbital order-disorder type of phase transition. We find that the high temperature dynamical Jahn-Teller phase of NaTiSi2O6 exhibits a spontaneous breaking of translational symmetry into a dimerized, Jahn-Teller distorted, orb…
Vibrational properties of delafossiteCuGaO2at ambient and high pressures
2005
In this paper we investigate the vibrational properties of $\mathrm{Cu}\mathrm{Ga}{\mathrm{O}}_{2}$ delafossite by means of Raman experiments and ab initio calculations. Both investigations have been performed at ambient pressure and also at high pressure. The two Raman-active modes have frequencies ${w}_{{E}_{g}}=368\ifmmode\pm\else\textpm\fi{}1\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}$ and ${w}_{{A}_{1g}}=729\ifmmode\pm\else\textpm\fi{}1\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}$, and pressure coefficients $2.78\ifmmode\pm\else\textpm\fi{}0.03\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}∕\mathrm{GPa}$ $({E}_{g})$ and $4.64\ifmmode\pm\else\text…
Ab initiostudy of compressedAr(H2)2: Structural stability and anomalous melting
2010
We study the structural stability and dynamical properties of $\text{Ar}{({\text{H}}_{2})}_{2}$ under pressure using first-principles and ab initio molecular-dynamics techniques. At low temperatures, $\text{Ar}{({\text{H}}_{2})}_{2}$ is found to stabilize in the cubic C15 Laves structure $({\text{MgCu}}_{2})$ and not in the hexagonal C14 Laves structure $({\text{MgZn}}_{2})$ as it has been assumed previously. Based on enthalpy energy and phonon calculations, we propose a temperature-induced ${\text{MgCu}}_{2}\ensuremath{\rightarrow}{\text{MgZn}}_{2}$ phase transition that may rationalize the existing discrepancies between the sets of Raman and infrared vibron measurements. Our AIMD simulati…
Resonant hyper-Raman scattering in semiconductors
1998
A theoretical model for resonant hyper-Raman scattering by LO phonons is developed, taking into account excitonic effects. The model is valid for energies below and above an allowed absorption edge. The matrix elements corresponding to the exciton-photon and exciton-phonon interactions are derived analytically, and their contributions to the total scattering efficiency are analyzed. The two main electron-phonon interaction mechanisms present in polar semiconductors, deformation potential, and Fr\"ohlich interaction, are considered. It is shown that the one-phonon resonance hyper-Raman scattering mediated by the deformation potential interaction is dipole forbidden, whereas it is allowed whe…
Role of excitons in double Raman resonances in GaAs quantum wells
1996
Raman scattering by longitudinal-optical phonons has been measured in GaAs-AlAs multiple quantum wells at high magnetic fields. Doubly resonant scattering processes are observed at photon energies corresponding to magneto-excitons with different principal quantum numbers for the incoming and outgoing channels. The existence of these initially forbidden scattering processes, their resonance energies, and their relative intensities are correctly reproduced by our theoretical description. The model takes into account the excitonic nature of the intermediate states, as well as scattering processes involving a nonzero in-plane phonon wave vector, which is required to allow inter-Landau level sca…
Comparison between observation and simulation of sodium LGS return flux with a 20W CW laser on Tenerife
2016
We report on the comparison between observations and simulations of a completed 12-month field observation campaign at Observatorio del Teide, Tenerife, using ESO's transportable 20 watt CW Wendelstein laser guide star system. This mission has provided sodium photon return flux measurements of unprecedented detail regarding variation of laser power, polarization and sodium D2b repumping. The Raman fiber laser and projector technology are very similar to that employed in the 4LGSF/AOF laser facility, recently installed and commissioned at the VLT in Paranal. The simulations are based on the open source LGSBloch density matrix simulation package and we find good overall agreement with experim…
Suppression of the frequency drifts in polarization modulational instability spectra by means of a photon reservoir
2012
By appropriately combining the effects of second- and fourth-order dispersion, and by carefully choosing the pump power, we create a photon reservoir which suppresses the drifts of sidebands in the spectra of polarization modulational instability
ARCADE: Description of the project and setup of the Lidar/AMT system
2015
The ARCADE (Atmospheric Research for Climate and Astroparticle DEtection) project is a 3 years project funded by MIUR, that aims to study the aerosol attenuation of UV light in atmosphere using multiple instruments and techniques, as those commonly used in the cosmic rays community: elastic Lidar, Raman Lidar, side-scattering measurements using a distant laser source. All measurements will be acquired on the same air mass at the same time, in a semi-desertic site near Lamar, Colorado (U.S.). For each instrument, multiple analysis techniques will be tested: the target is a better comprehension of the systematics and limits of applicability of each method. The system is composed by a Lidar (e…