Search results for "RAY"

showing 10 items of 8009 documents

Recognition of N-Alkyl- and N-Aryl-Acetamides by N-Alkyl Ammonium Resorcinarene Chlorides

2014

N-alkyl ammonium resorcinarene chlorides are stabilized by an intricate array of intra- and intermolecular hydrogen bonds that leads to cavitand-like structures. Depending on the upper-rim substituents, self-inclusion was observed in solution and in the solid state. The self-inclusion can be disrupted at higher temperatures, whereas in the presence of small guests the self-included dimers spontaneously reorganize to 1:1 host-guest complexes. These host compounds show an interesting ability to bind a series of N-alkyl acetamide guests through intermolecular hydrogen bonds involving the carbonyl oxygen (C=O) atoms and the amide (NH) groups of the guests, the chloride anions (Cl(-)) and ammoni…

chemistry.chemical_classificationHydrogen bondStereochemistryArylOrganic ChemistryIntermolecular forceGeneral Chemistrymacromolecular substancesResorcinareneMedicinal chemistryCatalysischemistry.chemical_compoundchemistryAmideAmmoniumresorcinarenes; NMR titration; amides; host-guest complexes; X-ray crystallographyta116AlkylAcetamide
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Polymorphism and solvates of flecainide base

2013

Flecainide base is pharmaceutically active substance used for production of flecainide acetate which is known in market as Tambacor, Almarytm, Apocard, Ecrinal or Flecaine. It is determined that flecainide base forms four polymorphic forms abbreviated as Ib, IIb, IIIb and IVb. Flecainide base form Ib is thermodynamically stable form at laboratory temperature while form IIIb is stable at higher temperatures. Flecainide form Ib absorbs water in its structure between layers and forms non-stoichiometric hydrate. Flecainide base binds with organic solvents and form monosolvates. Flecainide base form Ib crystallizes in orthorhombic crystals with lattice parameters a = 27.88 Å, b = 13.78 Å, c = 9.…

Voltage-Gated Sodium Channel BlockersFlecainideChemistryWaterPharmaceutical ScienceGeneral MedicineFlecainide Acetatelaw.inventionCrystallographyX-Ray DiffractionPolymorphism (materials science)lawX-ray crystallographymedicineThermodynamicsMoleculeOrthorhombic crystal systemCrystallizationCrystallizationHydrateAnti-Arrhythmia AgentsFlecainidemedicine.drugPharmaceutical Development and Technology
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Study of scintillation light collection, production and propagation in a 4 tonne dual-phase LArTPC

2020

The $3 \times 1 \times 1$ m$^3$ demonstrator is a dual phase liquid argon time projection chamber that has recorded cosmic rays events in 2017 at CERN. The light signal in these detectors is crucial to provide precise timing capabilities. The performances of the photon detection system, composed of five PMTs, are discussed. The collected scintillation and electroluminescence light created by passing particles has been studied in various detector conditions. In particular, the scintillation light production and propagation processes have been analyzed and compared to simulations, improving the understanding of some liquid argon properties.

photon: propagationPhotomultiplierCERN LabPhysics - Instrumentation and DetectorsPhysics::Instrumentation and DetectorstutkimuslaitteetPerformance of High Energy Physics DetectorPhase (waves)FOS: Physical sciencesCosmic rayNoble liquid detectors (scintillation ionization double-phase)Scintillator01 natural sciences7. Clean energyHigh Energy Physics - ExperimentHigh Energy Physics - Experiment (hep-ex)Optics0103 physical sciences[PHYS.HEXP]Physics [physics]/High Energy Physics - Experiment [hep-ex][PHYS.PHYS.PHYS-INS-DET]Physics [physics]/Physics [physics]/Instrumentation and Detectors [physics.ins-det]Detectors and Experimental Techniques010306 general physicsInstrumentationphysics.ins-detMathematical Physicsscintillation counterPhysicsScintillationTime projection chamberphotomultiplier010308 nuclear & particles physicsbusiness.industryhep-exDetectorScintillators scintillation and light emission processes (solid gas and liquid scintillators)Instrumentation and Detectors (physics.ins-det)time projection chamber: liquid argonNoble liquid detectors (scintillation ionization double-phase); Performance of High Energy Physics Detectors; Photon detectors for UV visible and IR photons (vacuum) (photomulti-pliers HPDs others); Scintillators scintillation and light emission processes (solid gas and liquidscintillators)Photon detectors for UV visible and IR photons (vacuum) (photomultipliers HPDs others)FIS/01 - FISICA SPERIMENTALEilmaisimetScintillation counterbusinesskosminen säteilyperformanceParticle Physics - Experiment
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Microcalorimeter/EBIT measurements of X-ray spectra of highly charged ions

2001

Spectra of highly charged Ar, Kr, Xe and Fe ions, produced in an Electron Beam Ion Trap (EBIT), have been recorded in a broad X-ray energy band (0.2 keV to 10 keV) with a microcalorimeter detector. The first analysis of the Kr spectra has been completed and most of the spectral lines have been identified as transitions of B- to Al-like Kr. Line intensity ratios of Fe XVII have been measured and compared with theoretical models.

PhysicsAtomic and Molecular Physics and OpticPhysics::Instrumentation and DetectorsDetectorTheoretical modelsCondensed Matter PhysicsAtomic and Molecular Physics and OpticsSpectral lineIonSettore FIS/05 - Astronomia E AstrofisicaMathematical PhysicAtomic physicsElectronic band structureX ray spectraMathematical PhysicsLine (formation)Electron beam ion trap
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Analysis of thiabendazole and procymidone in fruits and vegetables by capillary electrophoresis–electrospray mass spectrometry

2002

Abstract A capillary electrophoresis–mass spectrometry method for determining procymidone and thiabendazole in apples, grapes, oranges, pears, strawberries and tomatoes is described. Separation is achieved using a buffer of formic acid–ammonium formate at pH 3.5 with 2% of methanol. Fungicide residues present in the sample are preconcentrated by both solid-phase extraction and injection of large sample volumes into the capillary by a stacking technique, to obtain lower detection limits. Ionization is performed at atmospheric pressure in an electrospray type source and detection is carried out using positive ionization and selected ion monitoring modes. The quantitation limits are 0.005 and …

Detection limitSpectrometry Mass Electrospray IonizationElectrosprayChromatographyOrganic ChemistryPesticide ResiduesElectrophoresis CapillaryGeneral MedicineMass spectrometrySensitivity and SpecificityBiochemistryFungicides IndustrialAnalytical ChemistryBridged Bicyclo Compoundschemistry.chemical_compoundCapillary electrophoresischemistryFruitThiabendazoleVegetablesSample preparationSelected ion monitoringSolid phase extractionProcymidoneJournal of Chromatography A
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Soret Effect In Forced Rayleigh-scattering

1987

In forced Rayleigh scattering of mixtures or suspensions the temperature gratings generate, by the Soret effect, concentration gratings that may be very important since they produce both a phase and an amplitude grating superimposed on the principal one. The experimental evidence of their influence was given by Thyagarajan and Lallemand using a mixture of carbondisulfide and ethanol. In this paper we study the temporal behaviour of the concentration grating versus the sample properties and its effect on the detected diffracted beam. Explicit expressions are given for the output intensity taking into account both the generated amplitude and phase gratings.

DiffractionMaterials sciencePhysics and Astronomy (miscellaneous)business.industryscatteringGeneral EngineeringPhase (waves)Physics::OpticsGeneral Physics and AstronomySoret effectGratingThermophoresisIntensity (physics)symbols.namesakeOpticsAmplitudesymbolsPhysics::Atomic PhysicsRayleigh scatteringAtomic physicsbusinessBeam (structure)
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Giant hepatic hydatid cyst as a cause of small bowel obstruction.

2006

Today, giant hydatid cysts are fairly rare even in endemic areas. We describe a case of an extremely large hydatid cyst of the liver that was causing massive compression of the neighboring organs, giving rise to a subocclusive syndrome of the intestine. After considering the various approaches available for the treatment of this disease, it was decided that radical surgery was still the best therapeutic choice, especially when extremely large cysts are involved. In particular, in clinical situations where it is difficult to perform radical surgical procedures, less aggressive surgery followed by drug treatment should be the treatment of choice.

Malemedicine.medical_specialtyEchinococcosis Hepaticalanine aminotransferase aspartate aminotransferase contrast mediumoral contraceptive agentHelminthiasisAntiprotozoal AgentsHydatid cystHepatic ComplicationAlbendazoleAggressive surgeryDrug treatmentparasitic diseasesIntestine SmallmedicineHumansRadical surgeryAgedbusiness.industryGeneral Medicinemedicine.diseaseEchinococcosisSurgeryBowel obstructionSettore MED/18 - Chirurgia GeneraleDrug Therapy CombinationbusinessTomography X-Ray ComputedIntestinal Obstruction
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Ecotoxicity assessment of natural attenuation effects at a historical dumping site in the western Baltic Sea.

2005

During the late 1950s and early 1960s of the past century, industrial waste material highly enriched in various contaminants (heavy metals, PAHs) was dumped in the inner Mecklenburg Bay, western Baltic Sea. Large-scale shifts in the spatial distribution of heavy metals in surface sediments were mapped by geochemical monitoring in the mid-1980s and 12 years later in 1997. A further study in 2001 was designed to investigate the small-scale spatial distribution of contaminants inside, on top of, and around the historical dumping ground and to examine possible effects to benthic organisms (Arctica islandica, microbiological toxicity tests). The site is located within an area characterized by a …

Geologic SedimentsChromatography GaseducationAquatic ScienceOceanographycomplex mixturesIndustrial wasteDeposition (geology)Metals HeavyToxicity TestsAnimalsPolycyclic Aromatic HydrocarbonsWater pollutionArctica islandicaDiatomsbiologyBacteriaSpectrophotometry AtomicEnvironmental engineeringSedimentSpectrometry X-Ray EmissionSedimentationbiology.organism_classificationPollutionBivalviaBenthic zoneEnvironmental chemistryEnvironmental scienceEnvironmental PollutantsNorth SeaBayEnvironmental MonitoringMarine pollution bulletin
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Towards modelling the central engine of short GRBs

2011

Numerical relativity simulations of non-vacuum spacetimes have reached a status where a complete description of the inspiral, merger and post-merger stages of the late evolution of close binary neutron systems is possible. Determining the properties of the black-hole-torus system produced in such an event is a key aspect to understand the central engine of short-hard gamma-ray bursts (sGRBs). Of the many properties characterizing the torus, the total rest-mass is the most important one, since it is the torus' binding energy which can be tapped to extract the large amount of energy necessary to power the sGRB emission. In addition, the rest-mass density and angular momentum distribution in t…

PhysicsHistoryAngular momentumAstrophysics::High Energy Astrophysical PhenomenaX-ray binaryAstronomyTorusAstrophysicsComputer Science ApplicationsEducationBlack holeStarsNeutron starNumerical relativityTheory of relativitymagnetohydrodynamics binary neutron stars gravitational waves
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Retroaortic left renal vein joining the left common iliac vein

2000

Retroaortic left renal vein joining the left common iliac vein is a rare congenital anomaly in the development of the inferior vena cava. To our knowledge, only one case has been reported in the literature; however, its imaging features have never been described. A 27-year-old male presented with a 1-year history of recurrent right flank pain, dysuria, hematuria, and fever (39 degrees C). Computed tomography and MR venography showed a retroaortic left renal vein joining the left common iliac vein. We present the CT and MR venography findings and discuss their feasibility in showing this congenital anomaly.

AdultMalemedicine.medical_specialtyVena Cava InferiorIliac Veinurologic and male genital diseasesInferior vena cavaRenal VeinsMagnetic resonance angiographyImaging Three-DimensionalmedicineLeft common iliac veinHumansDysuriaRadiology Nuclear Medicine and imagingNeuroradiologyKidneymedicine.diagnostic_testbusiness.industryLeft renal veinInterventional radiologyGeneral MedicineAnatomymedicine.anatomical_structuremedicine.veincardiovascular systemRadiologymedicine.symptomTomography X-Ray ComputedbusinessMagnetic Resonance AngiographyEuropean Radiology
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