Search results for "REDUCTION"

Effect of Er3+-doping on 65GeS2-25Ga2S3-10CsCl glass probed by annihilating positrons

2019

Abstract Effect of Er3+-doping resulting in pronounced mid-IR fluorescence functionality was examined first in chalcohalide 65GeS2-25Ga2S3-10CsCl glass using positron annihilation lifetime (PAL) spectroscopy. The detected PAL spectra were reconstructed from unconstrained x2-term analysis employing two-state simple trapping model for one kind of positron trapping free-volume defects, the parameterization being performed at the example of 65GeS2-25Ga2S3-10CsCl glass doped with 0.6 at. % of Er3+. The observed decrease in positron trapping rate was proved to be primary void-evolution process in this Er-activated glass, like in many other chalcogenide glasses affected by rare earth doping. The n…

Poverty Reduction: The Paradox of the Endogenous Poverty Line

2007

When evaluating poverty, the relative poverty line may be considered as a percentage of the median income or it may be a percentage of the average income. It is proved that, with a poverty line relative to the median income, reducing poverty may become less costly in proportion to the total income as poverty increases (measured by the Sen, the Sen-Shorrocks-Thon or the Foster-Greer-Thorbecke poverty indexes) by passing from a Lorenz concentration curve to another curve associated with more poverty. This is obviously a paradox, although a largely overlooked one. However, it is shown that the paradox vanishes if the poverty line is relative to the average income. The demonstration is both exp…

Numerical and Experimental Study of a Novel Concept for Hydraulically Controlled Negative Loads

2016

This paper presents a numerical and experimental investigation of a novel concept that eliminates oscillations in hydraulic systems containing a counterbalance valve in series with a pressure compensated flow supply. The concept utilizes a secondary circuit where a low-pass filtered value of the load pressure is generated and fed back to the compensator of the flow supply valve. The novel concept has been implemented on a single boom actuated by a cylinder. A nonlinear model of the system has been developed and an experimental verification shows good correspondence between the model and the real system. The model is used for a parameter study on the novel concept. From the study it is found…

Smart prototype selection for machine learning based on ignorance zones analysis

2018

The size of databases has been considerably growing over recent decades and Machine Learning algorithms are not ready to process such large volume of information. Being one of the most useful algorithms in Data Mining the Nearest neighbor classifier suffers from high storage requirements and slow response when working with large data sets. Prototype Selection methods help to alleviate this problem by choosing a subset of data with a smaller size. In this thesis, the overview of existing instance selection methods is provided together with the introduction of a new approach. The majority of current methods select a subset experimentally by checking whether certain point affects classificatio…

Intrusion detection applications using knowledge discovery and data mining

2014

1,2,4-OSSADIAZOLI: UTILI SCAFFOLD NEL DESIGN DI NUOVI FARMACI

2021

The emissions reduction potential of substituting short-haul flights with non-high-speed rail (NHSR) : The case of Finland

2021

Replacing short-haul flights with high-speed rail (HSR) has been widely discussed as one solution to mitigate the climate change impacts of aviation. However, although HSR can provide travel times similar to those provided by short-haul flights, and at lower emission levels, it also requires considerable investments in time and infrastructure to build. Instead, this study considers the feasibility of replacing short-haul flights with existing non-high-speed rail (NHSR). Our study is based in Finland, a country that has an extensive route network of short-haul flights but does not possess any HSR. We compared all 16 city pairs for which short-haul flights are offered with existing NHSR based…

Proton reduction by phosphinidene-capped triiron clusters

2021

Bis(phosphinidene)-capped triiron carbonyl clusters, including electron rich derivatives formed by substitution with chelating diphosphines, have been prepared and examined as proton reduction catalysts. Treatment of the known cluster [Fe3(CO)9(µ3-PPh)2] (1) with various diphosphines in refluxing THF (for 5, refluxing toluene) afforded the new clusters [Fe3(CO)7(µ3-PPh)2(κ2-dppb)] (2), [Fe3(CO)7(µ3-PPh)2(κ2-dppv)] (3), [Fe3(CO)7(µ3-PPh)2(κ2-dppe)] (4) and [Fe3(CO)7(µ3-PPh)2(µ-κ2-dppf)] (5) in moderate yields, together with small amounts of the corresponding [Fe3(CO)8(µ3-PPh)2(κ1-Ph2PxPPh2)] cluster (x = -C4H6-, -C2H2-, -C2H4-, -C3H6-, -C5H4FeC5H4-). The molecular structures of complexes 3 a…

The SO2F2 quasi-spherical top: Correspondence between tensorial and Watson's formalisms

2006

Abstract The SO2F2 quasi-spherical top molecule with C2v symmetry is considered as a distorted spherical top deriving from the SO 4 2 − tetrahedral ion. We present here a detailed correspondence between the tensorial formalism using the Td⊃C2v reorientation and the usual Hamiltonian of Watson. We have also performed ab initio calculations in order to determine the centrifugal distorsion constants in the vibrational ground state.

Reduction and solipsism : Husserl's method of reduction and solipsism critique presented against it

2017

Työssäni tutkin Hursserlin reduktion metodia, joka on hänen kehittämänsä suuntauksen, transsendentaalisen fenomenologian, tutkimusmenetelmä. Vastaan kysymykseen, viekö reduktion metodi välttämättä solipsismiin vai ei. Lähtökohtanani on reduktion metodia vastaan esitetty ulkoinen ja sisäinen solipsismi-kritiikki. Vastaan erityisesti Hubert L. Dreyfusin esittämään ulkoiseen kritiikkiin, jonka mukaan Husserlin transsendentaalis-fenomenologinen tutkimus ajautuu välttämättä tilanteeseen, jossa ei voida esittää objektiivisia väittämiä. Analysoin myös Husserl-tutkimuksen keskusteluissa esiintyvää sisäistä kritiikkiä, jonka mukaan reduktion metodi on ongelmallinen tutkittaessa yhteisöllisyyttä ja k…