Search results for "REINFORCED"
showing 10 items of 236 documents
Reactivity of the carbon-carbon double bond towards nucleophilic additions. A dft analysis
2004
Abstract The global and local electrophilicity indexes have been used to characterize the reactivity pattern of the CC double bond towards nucleophilic addition reactions. A wide family of molecules including ketones, esters, anhydrides, nitriles and nitrocompounds containing appropriate substitution on the CC double bond have been classified within an unique scale of reactivity. The predictive capability of the theoretical model is tested against a series of benzylidenemalononitriles and substituted α-nitrostilbenes.
The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction
2020
We demonstrate here the suitability of CsPbBr3nanoparticles as photosensitizers for a demanding photoredox catalytic homo- and cross-coupling of alkyl bromides at room temperature by merely using visible light and an electron donor, thanks to the cooperative action between the nanoparticle surface and organic capping. Fil: Rosa-Pardo, Ignacio. Instituto de Ciencia Molecular; España. Universidad de Valencia; España Fil: Casadevall, Carla. Barcelona Institute Of Science And Technology. Institut Català D'investigació Química.; España Fil: Schmidt, Luciana Carina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigac…
Steel Fibres: Effective Way to Prevent Failure of the Concrete Bonded with FRP Sheets
2016
Although the efficiency of steel fibres for improving mechanical properties (cracking resistance and failure toughness) of the concrete has been broadly discussed in the literature, the number of studies dedicated to the fibre effect on structural behaviour of the externally bonded elements is limited. This experimental study investigates the influence of steel fibres on the failure character of concrete elements strengthened with external carbon fibre reinforced polymer sheets. The elements were subjected to different loading conditions. The test data of four ties and eight beams are presented. Different materials were used for the internal bar reinforcement: in addition to the conventiona…
Cupole in cemento armato in Sicilia occidentale nella prima metà del Novecento
2014
The paper intends to examine through three case studies the change introduced by the technology of reinforced concrete in the construction of domes. After a brief description of the geometric and architectural characteristics of reinforced concrete domes, the study focuses on three interventions, for which a considerable archival documentation was collected. Chronologically the first intervention is related to the construction of the dome of the mother-church of Bisacquino (1923-25), built on the basis of the architectural project and under the direction of the engineer Pietro Scibilia. The second concerns the reconstruction of the dome of Sant’Ignazio martire all'Olivella church in Palermo…
Assessment and strengthening of reinforced concrete bridges with half-joint deterioration
2022
Existing Niagara-type concrete cantilever bridges, which in Italy are called Gerber bridges, suffer from degradation due to reinforcement corrosion and a consequent reduced load-bearing capacity. The assessment of these structures is therefore an important part of the procedures for analyzing the state of existing bridges and any interventions required for their retrofitting. In particular, safety against failure of the half-joint must be evaluated with respect to the behavior of the entire bridge and its state of conservation, determining what the conditions are that lead to failure, in terms of loads, state of stress, and possibly cracking state. This evaluation has to be carried out cons…
Review of photoelastic image analysis applied to structural birefringent materials: glass and polymers
2015
Photoelasticity is particularly suitable for the analysis of the stress state in structural materials that are transparent and birefringent. Some techniques of digital photoelasticity (phase shifting and RGB) are applied to the analysis of stress field in two classes of structural materials. The first one consists of tempered glasses, such as those used in the automotive and architectural fields. The second one consists of thermoset polymers, typically used as matrices in fiber reinforced plastic structural composites. The birefringence of such resins is, in particular, exploited to investigate the development of swelling stresses and changes in fracture toughness as induced by water uptake…
Calcestruzzi rinforzati con fibre di PET. Sperimentazioni sull'impiego delle fibre di PET provenienti dalla raccolta differenziata nella produzione d…
2013
La sperimentazione esposta tratta dell’impiego di fibre di PET, ricavate dal semplice taglio di contenitori per bevande, nel rinforzo di calcestruzzi destinati anche a impieghi strutturali. Indaga la durabilità delle fibre in ambiente fortemente basico e le caratteristiche meccaniche di calcestruzzi rinforzati con differenti dosaggi di fibre. Le osservazioni al microscopio elettronico a scansione (SEM) di fibre di PET immerse per 13 giorni a 65°C in acqua distillata e in due soluzioni fortemente basiche mostrano la buona durabilità delle fibre in soluzione 0,103 M di NaOH, che simula la basicità della soluzione acquosa che permea la matrice cementizia. L’influenza delle fibre e del loro dos…
Some recent results on the compressive and flexural behaviour of composite members
2005
Experiemntal results from compression and flexural tests on steel tubulare columns having circular or rectangular transverse cross-section and infilled with plain or fiber reinforced concrete (FRC) are analysez. for composite members differenti lengths and different dimensions of transverse cross-section were considered in order to assess the influence on behavior in flexure and in compression.The fiber investigated with different percentage were syntetic, carbon and deformed steel fibers. The constituent materials were characterised through compressive and split tests on conconcrete cylinders. Load.shortning and load-delection curves were determined including the sotnening response. Simpli…
A new general fragmentation reaction in mass spectrometry: The hydrogen-carbon, carbon-carbon double rearrangement of 2 heteroalkyl substituted diphe…
1995
Diphenylmethyl cations formed by benzylic cleavage of the molecular ions of ortho heteroalkyl substituted 1,1-diphenylalkanes undergo the double rearrangement process (H to C followed by C to C) previously reported for ortho-methoxy derivatives. Hence the formation of substituted benzyl (or tropylium) ions allowing this double rearrangement process constitutes an interesting type of fragmentation reaction characteristic for 1,1-diphenylalkanes bearing ortho substituents (OMe, OEt, OiPr, SMe, NHMe, NMe2) which are able to transfer a hydride to the charged benzyl carbon of diphenylmethyl cations formed by benzylic cleavage of the molecular ion.
EFFECTIVENESS OF BASALT FIBRE-REINFORCED CEMENTITIOUS SYSTEMS IN CONFINING MASONRY MEMBERS: AN EXPERIMENTAL INVESTIGATION
2020
The use of composites based on fibre-reinforced polymers (FRPs) to strengthen masonry columns has become a common practice in the last decades. FRPs, however, exhibit some shortcomings when applied to masonry substrates, due to the organic nature of their matrix. For this reason, increasing attention is paid today to composites based on fibre-reinforced cementitious matrices (FRCMs), in which the polymeric matrix is replaced with an inorganic matrix (such as cementitious mortars). Cementitious matrices guarantee higher breathability and compatibility with the substrate, less sensitivity to debonding at the interfaces, and higher resistance to fire and high temperatures. Moreover, due to the…