Search results for "RESIDUES"

Pesticide monitoring in the basin of Llobregat River (Catalonia, Spain) and comparison with historical data.

2014

Through an extensive sampling in the Llobregat River basin, the presence of 50 currently used pesticides in water, sediment, and biota was assessed. Pesticides were detected primarily in water (up to 56% of the analytes), whereas their presence in sediments was more intermittent, and in biota was scarce. Those at high concentrations in water were the benzimidazoles (carbendazim in 22% of the samples up to 697ngL-1), the organophosphorus (malathion in 54% of the samples up to 320ngL-1), and the ureas (diuron in 54% of the samples up to 159ngL-1). However, this pattern differed in sediments and biota, which were contaminated primarily with organophosphorus (higher Kow) (chlorpyrifos 93% of se…

Screening of currently used pesticides in water, sediments and biota of the Guadalquivir River Basin (Spain)

2013

The occurrence of 50 currently used pesticides and their transformation products in surface and waste waters, sediment and fish in the Guadalquivir River Basin was determined in 2010 and 2011. After selective sample extraction, pesticides were identified and quantified by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS). The contamination profile in water and sediments is marked by the presence of organophosphorus and triazines. Transformation products were even at higher concentrations than parent pesticides. A wider range of pesticides was present in water than in sediments but none of them were detected in fish. The mean concentrations ranged from 0.2 to 13.0 ng/L in …

Application of Toxkit microbiotests for toxicity assessment in soil and compost

2004

The potential of Toxkit microbiotests to detect and analyze pollution in agricultural soil and the quality of compost was studied. The toxicity tests used included seed germination biotests using cress salad (Lepidum sativum L.), tomato (Lycopersicum esculentum L.), and cucumber (Cucumis sativus L.), and the Toxkit microbiotests included those with microalgae (Selenastrum capricornutum), protozoa (Tetrahymena thermophila), crustaceans (Daphnia magna, Thamnocephalus platyurus, and Heterocypris incongruens), and rotifers (Brachionus calyciflorus). Experiments on compost were undertaken in a modified solid-state fermentation system (SSF) and under field conditions (in a windrow). To promote th…

Measured and Modeled Residue Dynamics of Famoxadone and Oxathiapiprolin in Tomato Fields

2018

A reliable analytical method for the simultaneous determination of famoxadone and oxathiapiprolin dissipation kinetics as well as the metabolites of oxathiapiprolin (IN-E8S72 and IN-WR791) in tomato and soil was developed. We studied the dissipation of famoxadone and oxathiapiprolin in tomatoes grown using different kinetic curves in the area of Beijing in 2015 and 2016. Our results show that the most suitable model for two fungicides in 2015 and 2016 was first-order kinetic and second-order kinetic with the half-lives of 3.4 to 5.2 and 2.4 to 3.0 days, respectively. In addition, we applied the dynamic plant uptake model dynamiCROP and combined it with results from the field experiments to …

Monoclonal antibody-based immunoassays for cyprodinil residue analysis in QuEChERS-based fruit extracts

2015

Cyprodinil is among the most common agrochemical residues found in highly perishable fruits, such as strawberries. In the present study, high-affinity monoclonal antibodies to this anilinopyrimidine fungicide were raised for the first time with the aim to produce valuable immunochemical analytical assays. Cyprodinil bioconjugates and the generated novel monoclonal antibodies were employed for sensitive competitive immunoassay development in two different formats. The limits of detection of the optimized assays were 20 and 30 ng L-1 for the indirect and direct assay, respectively. Influence over assay parameters of different physicochemical factors was studied. Strawberry samples were extrac…

Determination of pesticide residues in fruit and vegetables.

1996

A review concerning the determination of pesticide residues in fruit and vegetables is presented. The basic principles and recent developments in the extraction and quantitation of pesticides are discussed. Consideration is given to solid phase and supercritical extraction techniques, automation and robotic systems, and immunoassay procedures.

REUTILIZACIÓN DE RESIDUOS DE PODA DE VID Y DE POSIDONIA OCEANICA EN LAS OBRAS DE BIOINGENIERÍA DEL PAISAJE

La popolazione mondiale è in continua espansione e la crescita demografica ed economica inducono allo sfruttamento progressivo dell’ambiente ed al depauperamento delle risorse naturali (acqua ed energia in particolare), con conseguenti impatti potenzialmente importanti sul cambiamento globale. Si rende, pertanto, necessaria ed urgente una più efficiente gestione delle risorse basata sulla rielaborazione di obiettivi sostenibili di politiche e strategie ambientali e sulla riduzione del consumo delle risorse, promuovendo la transizione da un modello di economia lineare ad uno circolare, costituito da un ciclo continuo di sviluppo positivo che preserva e migliora il capitale naturale, ottimizz…

Accumulation of Tetradifon in an Algae ( Nannochloris oculata ) and the Cladoceran, Daphnia magna

1996

Dissipation and distribution of atrazine, simazine, chlorpyrifos, and tetradifon residues in citrus orchard soil.

1997

An environmental fate study was conducted in a citrus orchard plot in Valencia (Spain) in the fall of 1993. Dissipation and distribution of atrazine, simazine, chlorpyrifos and tetradifon residues following their controlled addition for agricultural purposes in a mediterranean red soil (Luvic Calcisol, Rhodoxeralf) were evaluated. During a two-month period, the amounts of applied pesticides in different soil layers (0-0.05, 0.05-0.22, 0.22-0.42, and 0.42-0.52 m) were monitored. In addition, information on soils, weather and agricultural practice were collected. Degradation half-lives were calculated, assuming zero-order kinetics: 11 days for atrazine, 12 days for simazine, 10 days for chlor…

Analysis of insecticides in honey by liquid chromatography–ion trap-mass spectrometry: Comparison of different extraction procedures

2010

The feasibility of different extraction procedures was tested and compared for the determination of 12 organophosphorus and carbamates insecticides in honey samples. In this sense, once the samples were pre-treated - essentially dissolved in hot water by stirring - and before they could be analyzed by liquid chromatography-ion trap-second stage mass spectrometry (LC-MS(2)), four different approaches were studied for the extraction step: QuEChERS, solid-phase extraction (SPE), pressurized liquid extraction (PLE) and solid-phase microextraction (SPME). The main aim of this work was to maximise the sensitivity of pesticides and to minimise the presence of interfering compounds in the extract. …