Search results for "RET"

2021

Intracratonic basins tend to subside much longer than the timescale predicted by thermal relaxation of the lithosphere. Many hypotheses have been suggested to explain their longevity, yet few have been tested using quantitative thermo-mechanical numerical models, which capture the dynamic of the lithosphere. Lithospheric-scale geodynamic modelling preserving the tectono-stratigraphic architecture of these basins is challenging because they display only few kilometres of subsidence over 1000 of km during time periods exceeding 250 Myr. Here we present simulations that are designed to examine the relative role of thermal anomaly, tectonics and heterogeneity of the lithosphere on the dynamics …

Incised valleys and tidal seaways: the example of the Miocene Uzès-Castillon basin, SE France.

2012

Abstract The sedimentology and stratigraphy of the Miocene deposits of the Uzès-Castillon basin are revisited. This basin, located in SE France at the junction between the perialpine foreland basin and the W Mediterranean margin, sits in a syncline that formed during the latest Cretaceous Pyrenean tectonic phase. It records the succession of shallow-water mixed siliciclastic to dominantly bioclastic carbonates that alternate with shelf marls. The clastic carbonates were accumulated as a stack of subtidal dunes and bars that were formed by tidal currents channelized in a seaway following the syncline axis. The marls indicate deposition in more protected and locally deeper waters, as interflu…

High-resolution spectroscopy and analysis of the nu3/2nu4 dyad of CF4

2011

International audience; CF4 is a strong greenhouse gas of both anthropogenic and natural origin [D.R. Worton et al., Environ. Sci. Technol. 41, 2184 (2007)]. However, high-resolution infrared spectroscopy of this molecule has received only a limited interest up to now. Until very recently, the public databases only contained cross-sections for this species, but no detailed line list. We reinvestigate here the strongly absorbing ν3 region around 7.8 μm. New Fourier transform infrared (FTIR) spectra up to a maximal resolution of 0.0025 cm−1 have been recorded: (i) room-temperature spectra in a static cell and (ii) a supersonic expansion jet spectrum at a 23 K estimated temperature. Following …

Global modeling of the lower three polyads of PH_{3} Preliminary results

2009

International audience; In order to model the high-resolution infrared spectrum of the phosphine molecule in the 3 mu m region, a global approach involving the lower three polyads of the molecule (Dyad, Pentad and Octad) as been applied using an effective hamiltonian in the form of irreducible tensors. This model allowed to describe all the 15 vibrational states involved and to consider explicitly all relevant ro-vibrational interactions that cannot be accounted for by conventional perturbation approaches. 2245 levels (up to J=14) observed through transitions arising from 34 cold and hot bands including all available existing data as well as new experimental data have been fitted simultaneo…

Comparison of SMOS and SMAP soil moisture retrieval approaches using tower-based radiometer data over a vineyard field

2014

International audience; The objective of this study was to compare several approaches to soil moisture (SM) retrieval using l-band microwave radiometry. The comparison was based on a brightness temperature (TB) data set acquired since 2010 by the L-band radiometer ELBARA-II over a vineyard field at the Valencia Anchor Station (VAS) site. ELBARA-II, provided by the European Space Agency (ESA) within the scientific program of the SMOS (Soil Moisture and Ocean Salinity) mission, measures multiangular TB data at horizontal and vertical polarization for a range of incidence angles (30°–60°). Based on a three year data set (2010–2012), several SM retrieval approaches developed for spaceborne miss…

The 2009 Edition of the GEISA Spectroscopic Database

2011

The updated 2009 edition of the spectroscopic database GEISA (Gestion et Etude des Informations Spectroscopiques Atmosphériques; Management and Study of Atmospheric Spectroscopic Information) is described in this paper. GEISA is a computer-accessible system comprising three independent sub-databases devoted, respectively, to: line parameters, infrared and ultraviolet/visible absorption cross-sections, microphysical and optical properties of atmospheric aerosols. In this edition, 50 molecules are involved in the line parameters sub-database, including 111 isotopologues, for a total of 3,807,997 entries, in the spectral range from 10-6 to 35,877.031cm-1.The successful performances of the new …

Numerical evidence for thermohaline circulation reversals during the Maastrichtian

2005

[1] The sensitivity of the Maastrichtian thermohaline circulation to the opening/closing of marine communications between the Arctic and North Pacific oceans is investigated through a set of numerical experiments using the model CLIMBER-2 (Earth Model of Intermediate Complexity). We show here that the opening or closing of an Arctic-Pacific marine gateway induces transitions between different equilibrium states of the thermohaline circulation. Sensitivity tests of the inferred modes of thermohaline circulation to atmospheric CO2 level changes have also been explored. An abrupt switch in deep convection from high northern to high southern latitudes, a change consistent with isotopic evidence…

Fluid storage and migration properties of sheared Neptunian dykes

2019

Abstract Neptunian dykes are widely reported along the Tethyan carbonate platforms and are commonly considered as subsurface baffles or barriers to fluid flow. However, the fluid storage and migration properties of sheared Neptunian dykes are poorly known. For this reason, we investigate the inner structure and fluid flow properties of two Neptunian dykes, which can be characterized by different architectures if involved or not in brittle shearing processes. The dykes strike ca. WNW-ESE and crosscutting the tight Jurassic limestones exposed at Maranfusa Mt., NW Sicily, Italy. The unsheared and sheared Neptunian dykes are almost sub-vertical and at high-angle with respect to the horizontal p…

The giant inoceramid Platyceramus platinus as a high-resolution paleoclimate archive for the Late Cretaceous of the Western Interior Seaway

2018

Abstract Platyceramus platinus was a giant inoceramid bivalve that inhabited the outer shelf environments of the Western Interior Seaway (WIS) in North America. With axial heights typically exceeding 1 m, the shells of this species potentially serve as a unique high-resolution geochemical proxy archive for Late Cretaceous paleoclimate. Here we present the first sclerochronological investigation of P. platinus shells to evaluate the usefulness of this species as an archive of short-term (e.g., seasonal to inter-annual) paleoenvironmental variability. We analyzed the growth patterns, the stable oxygen (δ18O) and carbon (δ13C) isotope values of well-preserved P. platinus shell fragments from t…

Reactive oxygen species formed in aqueous mixtures of secondary organic aerosols and mineral dust influencing cloud chemistry and public health in th…

2017

Mineral dust and secondary organic aerosols (SOA) account for a major fraction of atmospheric particulate matter, affecting climate, air quality and public health. How mineral dust interacts with SOA to influence cloud chemistry and public health, however, is not well understood. Here, we investigated the formation of reactive oxygen species (ROS), which are key species of atmospheric and physiological chemistry, in aqueous mixtures of SOA and mineral dust by applying electron paramagnetic resonance (EPR) spectrometry in combination with a spin-trapping technique, liquid chromatography-tandem mass spectrometry (LC-MS/MS), and a kinetic model. We found that substantial amounts of ROS includi…