Search results for "ROTATIONAL"

showing 10 items of 381 documents

High-Resolution Jet-Cooled Spectroscopy of SF6: The ν2+ ν6Combination Band of32SF6and the ν3Band of the Rare Isotopomers

1998

The Fourier transform infrared spectrum of SF6 was recorded in a supersonic expansion jet of an SF6/argon mixture. The SF6:Ar seeding ratio was 2:3. The instrumental bandwidth was 0.005 cm-1. A globar source and an MCT detector were used. A rotational temperature of approximately 30 K was achieved. The nu2 + nu6 combination band of 32SF6 was analyzed using a modified version of the spherical top data system (STDS) programs developed in Dijon. A very good fit was obtained for this band with an rms of 0.0036 cm-1. The effective Hamiltonian was developed up to fourth order for the nu2 + nu6 part, to second order for the nu2 and ground state parts, and to first order for the nu6 part. Five hund…

PhysicsArgonInfraredbusiness.industrychemistry.chemical_elementRotational temperatureAtomic and Molecular Physics and OpticsIsotopomerssymbols.namesakeFourier transformOpticschemistryGlobarsymbolsPhysical and Theoretical ChemistryAtomic physicsSpectroscopybusinessGround stateSpectroscopyJournal of Molecular Spectroscopy
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On the maximum efficiency of the propeller mass-ejection mechanism

2007

Aims. We derive simple estimates of the maximum efficiency with which matter can be ejected by the propeller mechanism in disk-fed, rotating magnetic neutron stars. Some binary evolution scenarios envisage that this mechanism is responsible for expelling to infinity the mass inflowing at a low rate from the companion star, therefore limiting the total amount of mass that can be accreted by the neutron star. Methods. We demonstrate that, for typical neutron star parameters, a maximum of ��_{pro} < 5.7 (P_{-3})^{1/3} times more matter than accreted can be expelled through the propeller mechanism at the expenses of the neutron star rotational energy (P_{-3} is the NS spin period in unit of …

PhysicsAstrophysics::High Energy Astrophysical PhenomenaAstrophysics (astro-ph)PropellerFOS: Physical sciencesOrder (ring theory)Astronomy and AstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsAstrophysicsStar (graph theory)AstrophysicsMagnetic fieldRotational energyNeutron starSpace and Planetary ScienceAstrophysics::Solar and Stellar AstrophysicsAstrophysics::Earth and Planetary AstrophysicsLow MassAstrophysics::Galaxy AstrophysicsSpin-½
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Numerical Simulations of the Thermal Instability Collapse in Radiation Pressure Dominated Disks

2005

We show that accretion disks, both in the subcritical and supercritical accretion rate regime, may exhibit significant amplitude luminosity oscillations. The luminosity time behavior has been obtained by performing a set of time‐dependent 2D SPH simulations of accretion disks with different values of α and accretion rate. An explanation of this luminosity behavior is proposed in terms of limit‐cycle instability: the disk oscillates between a radiation pressure dominated configuration (with a high luminosity value) and a gas pressure dominated one (with a low luminosity value). The origin of this instability is the difference between the heat produced by viscosity and the energy emitted as r…

PhysicsAstrophysics::High Energy Astrophysical PhenomenaQuasarAstrophysics::Cosmology and Extragalactic AstrophysicsAstrophysicsRadiationInstabilityLuminosityViscosityAmplitudeRadiation pressureMagnetorotational instabilityAstrophysics::Solar and Stellar AstrophysicsAstrophysics::Earth and Planetary AstrophysicsAstrophysics::Galaxy Astrophysics
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Development of the Dipole Moment and Polarizability Operators of Octahedral Molecules

1999

We present a development of the dipole moment and polarizability operators of octahedral molecules, using a tensorial formalism analogous to the one developed for tetrahedral molecules. These operators are involved in the calculation of the intensities of rovibrational transitions as well as in the calculation of the Stark effect. Expressions for the matrix elements are derived. Two simplified models for the study of the Stark effect in such molecules are also proposed and discussed. Copyright 1999 Academic Press.

PhysicsBond dipole momentTransition dipole momentTetrahedral molecular geometryRotational–vibrational spectroscopyMolecular physicsAtomic and Molecular Physics and Opticssymbols.namesakeDipoleStark effectPolarizabilityQuantum mechanicsPhysics::Atomic and Molecular ClusterssymbolsMoleculePhysics::Atomic PhysicsPhysics::Chemical PhysicsPhysical and Theoretical ChemistrySpectroscopyJournal of Molecular Spectroscopy
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Topological charge selection rule for phase singularities

2009

We present a study of the dynamics and decay pattern of phase singularities due to the action of a system with a discrete rotational symmetry of finite order. A topological charge conservation rule is identified. The role played by the underlying symmetry is emphasized. An effective model describing the short range dynamics of the vortex clusters has been designed. A method to engineer any desired configuration of clusters of phase singularities is proposed. Its flexibility to create and control clusters of vortices is discussed.

PhysicsCharge conservationSingularity theoryRotational symmetryFOS: Physical sciencesFísicaPattern Formation and Solitons (nlin.PS)ÒpticaNonlinear Sciences - Pattern Formation and SolitonsAtomic and Molecular Physics and OpticsAction (physics)Symmetry (physics)VortexClassical mechanicsGravitational singularityTopological quantum numberPhysical Review A
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Spectroscopy of XY2Z2 (C2v) Molecules: A Tensorial Formalism Adapted to the O(3)⊃Td⊃C2v Chain. Application to the Ground State of SO2F2

2002

Abstract A tensorial formalism adapted to the case of quasi-spherical XY 2 Z 2 asymmetric tops such as SO 2 F 2 has been developed as an extension of the usual one for the tetrahedral molecules. We use the O (3)⊃ T d ⊃ C 2 v group chain. All the coupling coefficients and formulas for the computation of matrix elements are given for this chain. Such relations are then deduced in the C 2 v group itself. We also present a development of the Hamiltonian, dipole moment, and polarizability operators for the molecules under consideration using this formalism. These operators are involved in the calculation of the energies and intensities of rovibrational transitions and are essential for spectrum …

PhysicsComputationTetrahedral molecular geometryRotational–vibrational spectroscopyAtomic and Molecular Physics and OpticsDipolesymbols.namesakePolarizabilityQuantum mechanicssymbolsPhysical and Theoretical ChemistryGround stateSpectroscopyHamiltonian (quantum mechanics)SpectroscopyJournal of Molecular Spectroscopy
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Ellipsoidal deformation of vertical quantum dots

1999

Addition energy spectra at 0 T of circular and ellipsoidally deformed few-electron vertical quantum dots are measured and compared to results of model calculations within spin-density functional theory. Because of the rotational symmetry of the lateral harmonic confining potential, circular dots show a pronounced shell structure. With the lifting of the single- particle level degeneracies, even a small deformation is found to radically alter the shell structure leading to significant modifications in the addition energy spectra. Breaking the circular symmetry with deformation also induces changes in the total spin. This "piezo-magnetic" behavior of quantum dots is discussed, and the additio…

PhysicsCondensed Matter - Mesoscale and Nanoscale PhysicsCondensed matter physicsQuantum dotMesoscale and Nanoscale Physics (cond-mat.mes-hall)Rotational symmetryFOS: Physical sciencesCircular symmetryDeformation (meteorology)AnisotropyGround stateSpin-½Magnetic field
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Dynamics of heavy fermions: Drude response in and

2006

While the effective mass of heavy fermions governs their thermodynamics, the optical properties are dominated by the characteristic relaxation rate which is expected to scale inversely with the effective mass. At the relaxation rate clear features, the so-called Drude response occur in the real and imaginary parts of the complex conductivity. Conventional optical spectroscopy can only indirectly probe the Drude response; thus we use novel broadband microwave spectroscopy to directly measure the frequency-dependent conductivity of UPd2Al3 and UNi2Al3 in the relevant frequency range and unambiguously observe the full low-energy electrodynamics of the heavy fermions including the Drude respons…

PhysicsCondensed matter physicsFermionConductivityCondensed Matter PhysicsDrude modelElectronic Optical and Magnetic Materialssymbols.namesakeEffective mass (solid-state physics)Relaxation ratesymbolsDrude particleRotational spectroscopyElectrical and Electronic EngineeringSpectroscopyPhysica B: Condensed Matter
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Low-energy spectrum and finite temperature properties of quantum rings

2002

Recently it was demonstrated that the rotational and vibrational spectra of quantum rings containing few electrons can be described quantitatively by an effective spin-Hamiltonian combined with rigid center-of-mass rotation and internal vibrations of localized electrons. We use this model Hamiltonian to study the quantum rings at finite temperatures and in presence of a nonzero magnetic field. Total spin, angular momentum and pair correlation show similar phase diagram which can be understood with help of the rotational spectrum of the ring.

PhysicsCondensed matter physicsRotational transitionCondensed Matter PhysicsQuantum numberSpin quantum numberMolecular physicsElectronic Optical and Magnetic MaterialsAzimuthal quantum numbersymbols.namesakePauli exclusion principleTotal angular momentum quantum numberPrincipal quantum numberAngular momentum couplingsymbolsThe European Physical Journal B
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Dynamics of the rotational degrees of freedom in a supercooled liquid of diatomic molecules

1997

Using molecular dynamics computer simulations, we investigate the dynamics of the rotational degrees of freedom in a supercooled system composed of rigid, diatomic molecules. The interaction between the molecules is given by the sum of interaction-site potentials of the Lennard-Jones type. In agreement with mode-coupling theory (MCT), we find that the relaxation times of the orientational time correlation functions C_1^(s), C_2^(s) and C_1 show at low temperatures a power-law with the same critical temperature T_c, and which is also identical to the critical temperature for the translational degrees of freedom. In contrast to MCT we find, however, that for these correlators the time-tempera…

PhysicsCondensed matter physicsStatistical Mechanics (cond-mat.stat-mech)Degrees of freedom (physics and chemistry)ThermodynamicsRotational diffusionFOS: Physical sciencesType (model theory)Diatomic moleculeFick's laws of diffusionPower lawRelaxation (physics)Critical exponentCondensed Matter - Statistical Mechanics
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