Search results for "ROTATIONAL"
showing 10 items of 381 documents
Applied study on the rotational molding and processing technology of rotational molds
2021
Computer-aided manufacturing involves a set of computerized activities related to the preparation, launch and follow-up of manufacturing. Computer-aided manufacturing is a tool that allows the use of 3D models based on computer-aided design. This paper addresses the process of rotational formation, with an effective focus on the technology of processing a rotational mold using CAM simulation as a research method. In this sense, the right choice of CNC and cutting tools is essential. The use of numerically controlled machine tools and high-performance cutting tools reduces the number of operations. The manufacturing route realized is specific to the parts machining on numerical control machi…
On the history of torsional stress concentrations in shafts: From electrical analogies to numerical methods
2014
This article proposes a retrospective on experimental and numerical methods developed throughout the past century to solve the torsion problem in shafts, with particular emphasis on the determination of shear stress concentration factors in discontinuities of typical use in shaft design. This article, in particular, presents the theory and related solutions distinguishing between two classes of geometries: shafts with constant cross section and axisymmetric shafts with variable diameter. Emphasis is given to approaches based on physical analog methods and, in particular, those based on electrical analogies proposed since about 1925. Experimental methods based on structural physical models …
Long-term FRII jet evolution: Clues from three-dimensional simulations
2018
We present a long-term numerical three-dimensional simulation of a relativistic outflow designed to be compared with previous results from axisymmetric, two-dimensional simulations, with existing analytical models and state-of-art observations. We follow the jet evolution from 1~kpc to 200~kpc, using a relativistic gas equation of state and a galactic profile for the ambient medium. We also show results from smaller scale simulations aimed to test convergence and different three-dimensional effects. We conclude that jet propagation can be faster than expected from axisymmetric simulations, covering tens of kiloparsecs in a few million years, until the dentist drill effect produced by the gr…
Soil quality indicators as affected by a long term barley-maize and maize cropping systems
2011
Most soil studies aim a better characterization of the system through indicators. In the present study nematofauna and soil structure were chosen as indicators to be assess soil health as related to agricultural practices. The field research was carried out on the two fodder cropping systems continuous maize (CM, Zea mays L.) and a 3-year rotation of silage-maize – silage-barley (Hordeum vulgare L.) with Italian ryegrass (R3) and grain-maize maintained in these conditions for 18 years. Each crop system was submitted to two management options: 1) the high input level (H), done as a conventional tillage, 2) the low input level (L), where the tillage was replaced by harrowing and the…
Accurate spectroscopic constants of nitrogen determined from stimulated Raman spectra of the fundamental and first hot bands
1990
Nitrogen spectra of the Q-branch of the fundamental and the first hot bands were recorde with a high-resolution stimulated Raman spectrometer at atmospheric pressure and ca. 1300 K. The absolute frequencies of the Raman lines were measured with high accuracy, leading to a refinement of spectroscopic constants. A temperature estimation was also performed from the Raman intensities.
High-resolution spectroscopy of the ν3 band of WF6 and ReF6 in a supersonic jet
2002
We have recorded the Fourier-transform infrared (FTIR) spectrum of the ν3 fundamental band of WF6 in a continuous supersonic jet expansion with an instrumental bandwidth of 0.0024 cm−1 (FWHM, full width at half maximum, unapodized), using a Bomem DA.002 spectrometer. Some parts of this band have also been recorded with 0.0007 cm−1 bandwidth using a diode laser spectrometer combined with a pulsed slit jet expansion. A multiple-pass arrangement has been used for the slit jet to observe low-intensity lines. In each case, we have used a WF6:He mixture with a seeding ratio 1:3 leading to a rotational temperature of ca. 50 K. This work extends the previous investigation of Takami and Kuze [J. Che…
Infrared Difference Spectroscopy of Proteins: From Bands to Bonds
2020
Infrared difference spectroscopy probes vibrational changes of proteins upon their perturbation. Compared with other spectroscopic methods, it stands out by its sensitivity to the protonation state, H-bonding, and the conformation of different groups in proteins, including the peptide backbone, amino acid side chains, internal water molecules, or cofactors. In particular, the detection of protonation and H-bonding changes in a time-resolved manner, not easily obtained by other techniques, is one of the most successful applications of IR difference spectroscopy. The present review deals with the use of perturbations designed to specifically change the protein between two (or more) functional…
"Expanded" local mode approach and isotopic effect in polyatomic molecules
2014
In this thesis, on the base of the "expanded", local mode approach and general isotopic substitution theory we obtain sets of simple analytical relations between spectroscopic parameters (harmonic frequencies, anharmonic coefficients, ro-vibrational parameters, different kinds of Fermi and Coriolis-type interaction parameters) of the CH2D2, CH3D and CHD3 molecules. All of them are expressed as simple functions of spectroscopic parameters of the mother CH4 molecule. Test calculations with the isotopic relations show that even without including prior informations about the isotopic species, numerical results of calculations are in a good agreement both with experimental data and results of ab…
Dual Substituent Parameter Modeling of Theoretical, NMR and IR Spectral Data of 5-Substituted Indole-2,3-diones
2002
Correlations of AM1 and PM3 theoretical data, 13C-NMR substituent chemical shifts (13C-SCS) and IR carbonyl group wave numbers [ν(C3â•ÂO)] were studied using dual substituent parameter (DSP) models for 5-substituted indole-2,3-diones. For the C7 atom a reverse substituent effect attributed to extended À-polarization was observed. On the other hand, the DSP approaches for the C3 atom showed normal substituent effects with some contribution of reverse effect supported strongly by 13C-SCS correlations. In the ν(C3â•ÂO) and p(C3â•ÂO) DSP correlations the field effect contribution predominates over the resonance effect, which justifies the using of earlier suggested vibrational cou…
Resolving the forbidden band of SF6
2013
Sulfur hexafluoride is an important molecule for modeling thermophysical and polarizability properties. It is also a potent greenhouse gas of anthropogenic origin, whose concentration in the atmosphere, although very low is increasing rapidly; its global warming power is mostly conferred by its strong infrared absorption in the ν3 S-F stretching region near 948 cm(-1). This heavy species, however, features many hot bands at room temperature (at which only 31% of the molecules lie in the ground vibrational state), especially those originating from the lowest, v6 = 1 vibrational state. Unfortunately, the ν6 band itself (near 347 cm(-1)), in the first approximation, is both infrared- and Raman…