Search results for "Raphe"

Recent applications of carbonaceous nanosorbents for the analysis of mycotoxins in food by liquid chromatography: a short review

2019

Carbonaceous nanomaterials (multi-walled carbon nanotubes (MWCNTs), graphene, and graphene oxide (GO)) have attracted attention over the last decade as adsorbents suitable for the analysis of organic and inorganic pollutants. In the present paper we review methods of mycotoxin analysis that involve sample extraction with carbonaceous nanosorbents, reported from 2011 onwards. Recent studies have highlighted the advantages of magnetically modified MWCNTs and GO in mycotoxin analysis, which may enable sample isolation through magnetic separation, reduce the interaction of nanoparticles, and enhance the recovery of analytes. The papers covered in this review point to promising applications of …

Reduced graphene oxide decorated with metals nanoparticles electrode as electrochemical sensor for dopamine

2019

Dopamine (DA) is one of the most important neurotransmitters that influences the processes that involve memory, sleep, mood, learning among others [1]. In fact, in the last years, dopamine concentration in human body fluids has been related to some neurodegenerative diseases, such as Parkinson and Alzheimer's diseases [2]. The possibility to have a bio-marker for these disease is of extreme importance because, disease related with dementia, are diagnosed when they are already developed and their management become almost impossible. The possibility to continuously monitor DA level in fluids, such as blood and urine, could accelerate the early diagnosis of these diseases. The principal analyt…

Time-Resolved Coherent Anti-Stokes Raman Scattering of Graphene: Dephasing Dynamics of Optical Phonon.

2017

We report dynamics of the G-mode in graphene probed with time-resolved coherent anti-Stokes Raman scattering measurements. By applying BOXCARS excitation geometry with three different excitation wavelengths, various nonlinear processes can be selectively detected due to energy and momentum conservation and temporal sequence of the pulses. The Raman signal due to resonant coherent excitation of the G-mode shows exponential decay with lifetime of ∼325 ± 50 fs. This decay time is shorter than expected based on the line width of the G-mode in the Raman spectrum. We propose that the unexpectedly short dephasing time is a result of dynamic variation of nonadiabatic coupling of the photoexcited el…

Adiabatic versus Non-Adiabatic Electron Transfer at 2D Electrode Materials

2021

<div><div><div><p>Outer-sphere electron transfer (OS-ET) is a cornerstone elementary electrochemical reaction, yet microscopic understanding is largely based on idealized theories, developed in isolation from experiments that themselves are often close to the kinetic (diffusion) limit. Focusing on graphene as-grown on a copper substrate as a model 2D material/metal-supported electrode system, this study resolves the key electronic interactions in OS-ET, and identifies the role of graphene in modulating the electronic properties of the electrode/electrolyte interface. An integrated experimental-theoretical approach combining co-located multi-microscopy, centered on sc…

Sensors for the monitoring of analytes in the sweat

In the last decade, can be found an exceptional growth in research activity relating to the development of wearable devices, capable of continuously monitoring the health conditions of the wearer by analyzing body fluids such as blood, urine, saliva, tears and sweat. Among the body fluids available, sweat is a biofluid of particular interest, as it allows a non-invasive, continuous and comfortable collection. Human sweat contains useful information on the health of an individual and therefore is an excellent biofluid for the detection of specific analytes. The most abundant ions in the sweat are Na+ and Cl- (10 - 100 mM), and their monitoring is useful in patients with cystic fibrosis. Othe…

Cannabinoid type-1 receptor signaling in central serotonergic neurons regulates anxiety-like behavior and sociability.

2015

The endocannabinoid (eCB) system possesses neuromodulatory functions by influencing the release of various neurotransmitters, including γ-aminobutyric acid (GABA) and glutamate. A functional interaction between eCBs and the serotonergic system has already been suggested. Previously, we showed that cannabinoid type-1 (CB1) receptor mRNA and protein are localized in serotonergic neurons of the raphe nuclei, implying that the eCB system can modulate serotonergic functions. In order to substantiate the physiological role of the CB1 receptor in serotonergic neurons of the raphe nuclei, we generated serotonergic 5-hydroxytryptamine (5-HT) neuron-specific CB 1 receptor-deficient mice, using the Cr…

Radiofrequency performances of different Graphene Field Effect Transistors geometries

2016

In this work, we investigated on microwave parameters geometry dependence in Graphene Field Effect Transistors (GFETs). A DC and RF characterization of the fabricated GFETs has been performed. The parametric analysis was carried out on 24 GFET families fabricated on the same chip and differing only for the channel length (Δ) and the gate length (Lg). In order to obtain a statistical average, each family included ten devices with the same geometry.Our study demonstrates that the output resistance and the cut-off frequency depend on both Δ and Lg. As expected, Rout increases with the graphene channel surface thus confirming the good quality of the fabrication procedures. An optimum region whi…

Le Dictionnaire de l’Académie française source des dictionnaires bilingues franco-italiens (1694-1870)

2016

L'articolo si propone di sondare l'influenza del Dictionnaire de l'Académie française sulla lessicografia bilingue franco-italiana in un arco cronologico compreso tra il 1694 e il 1870. In particolare, si passano in rassegna le prefazioni dei principali dizionari bilingui pubblicati nel periodo considerato, al fine di valutare se il Dictionnaire de l'Académie venga citato tra le fonti e qual uso il lessicografo intenda farne. The article aims to explore the influence of the Dictionnaire de l'Académie française on French-Italian bilingual lexicography in a chronological arc between 1694 and 1870. In particular, the prefaces of the main bilingual dictionaries published in the period considere…

Quantifying the Covalent Functionalization of Black Phosphorus

2020

Abstract A straightforward quantification method to consistently determine the overall functionalization degree of covalently modified two‐dimensional (2D) black phosphorus (BP) by Raman spectroscopy has been carried out. Indeed, the successful reductive methylation of the BP lattice using sodium intercalation compounds and exhibiting different functionalization degrees has been demonstrated by 31P‐magic angle spinning (MAS) NMR spectroscopy. Furthermore, the correlation of 31P‐MAS NMR spectroscopy and statistical Raman spectroscopy (SRS) revealed the first method to determine the functionalization degree of BP solely by evaluating the intensities of distinct peaks in the Raman spectra of t…

Estimation des performances, test et contrôle des systèmes cyber-physiques employant des réseaux de communication non idéaux

2020

Wireless technology is a key enabler of the promises of Industry 4.0 (Smart Manufacturing). As such, wireless technology will be adopted as a principal mode of communication within the factory beginning with the factory enterprise and eventually being adopted for use within the factory workcell. Factory workcell communication has particular requirements on latency, reliability, scale, and security that must first be met by the wireless communication technology used. Wireless is considered a non-ideal form of communication in that when compared to its wired counterparts, it is considered less reliable (lossy) and less secure. These possible impairments lead to delay and loss of data in indus…