Search results for "Ray"

showing 10 items of 8009 documents

Pd2Au36(SR)(24) cluster: structure studies

2015

The location of the Pd atoms in Pd2Au36(SC2H4Ph)(24), is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

spectroscopyAtomsElectronic-propertiesnanoclustersMass-spectrometrychemistry.chemical_elementNanotechnologyCrystal structureSpectral lineÀtomsCondensed Matter::Materials ScienceX-ray photoelectron spectroscopyOptical-propertiesCondensed Matter::SuperconductivityRay-absorption spectroscopyCluster (physics):Física::Electromagnetisme [Àrees temàtiques de la UPC]General Materials ScienceGold nanoclustersta116Theoretical-analysista114Extended X-ray absorption fine structureDopingProtected au-25 nanoclustersEspectroscòpia de raigs XCrystallographyLigand-exchangechemistryCrystal-structureddc:540X-ray spectroscopyNanoparticles:Física::Física molecular [Àrees temàtiques de la UPC]Absorption (chemistry)Palladium
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Two new organic-selenate salts: syntheses and crystal structures of bis(di-iso-propylammonium) selenate and di-n-butylammonium hydrogenoselenate

2017

Abstract Two new dialkyammonium selenate salts [i-Pr2NH2]2[SeO4] (1) and [n-Bu2NH2][HSeO4] (2) have been isolated and characterized by single-crystal X-ray diffraction. Salt 1 crystallizes in the monoclinic system, space group P21/n with a=8.7190(5), b=8.8500(4), c=22.5953(9) Å, β=94.6290(17)°, V=1737.84(14) Å3 and Z=4. Salt 2 crystallizes in the monoclinic system space group P21/n with a=10.9328(9), b=8.1700(6), c=13.8095(11) Å, β=97.130(3)°, V=1223.94(17) Å3 and Z=4. In both salts, dialkylammonium cations and selenate anions are connected through NH···O and OH···O hydrogen bonds. In the crystal structure, 1 and 2 are organized in layer-like arrangements. Structural characterizations were …

spectroscopyGeneral ChemistryCrystal structure[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesSelenatedialkylammonium cation[ CHIM ] Chemical Scienceshydrogen bonding networkNMR0104 chemical sciencesCrystallographychemistry.chemical_compoundchemistryX-ray crystallographyorganic-selenate salt[CHIM]Chemical SciencesComputingMilieux_MISCELLANEOUSX-ray crystallography
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Characterization of a CZT focal plane small prototype for hard X-ray telescope

2005

The promise of good energy and spatial resolution coupled with high efficiency and room temperature operation has fuelled a large international effort to develop cadmium zinc telluride (CZT) for hard X-ray applications. We are involved on the development of a hard X-ray telescope based on multilayer optics and focal plane detector operative in the 10-80 keV energy range. This telescope requires a high efficiency focal plane providing both fine spatial resolution and spectroscopy with a compact and robust design. This paper reports preliminary results on the characterization both in spectroscopic and spatial response of two small pixellated CZT detectors (10times10times1 mm3 and 10times10tim…

spectroscopyNuclear and High Energy PhysicsPhysics::Instrumentation and DetectorsX-ray telescopeParticle detectorlaw.inventionTelescopechemistry.chemical_compoundOpticslawElectronicsElectrical and Electronic EngineeringImage resolutionPhysicsPixelbusiness.industryAstrophysics::Instrumentation and Methods for AstrophysicsCadmium zinc tellurideCZTCardinal pointNuclear Energy and Engineeringchemistrypixel detectorfocal planehard X-rayOptoelectronicsbusinessIEEE Transactions on Nuclear Science
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Spectroscopic characterization of alkaline earth uranyl carbonates

2005

A series of alkaline uranyl carbonates, M[UO{sub 2}(CO{sub 3}){sub 3}].nH{sub 2}O (M=Mg{sub 2}, Ca{sub 2}, Sr{sub 2}, Ba{sub 2}, Na{sub 2}Ca, and CaMg) was synthesized and characterized by inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectrometry (AAS) after nitric acid digestion, X-ray powder diffraction (XRD), and thermal analysis (TGA/DTA). The molecular structure of these compounds was characterized by extended X-ray absorption fine-structure (EXAFS) spectroscopy and X-ray photoelectron spectroscopy (XPS). Crystalline Ba{sub 2}[UO{sub 2}(CO{sub 3}){sub 3}].6H{sub 2}O was obtained for the first time. The EXAFS analysis showed that this compound consists of …

spectroscopysynthesisAbsorption spectroscopyTRLFSAnalytical chemistryElectron spectroscopyUranyl carbonateuraniumInorganic Chemistrycarbonatechemistry.chemical_compoundXPSMaterials ChemistrystructurePhysical and Theoretical ChemistrySpectroscopyX-ray spectroscopyExtended X-ray absorption fine structureChemistryCondensed Matter PhysicsUranylalkaline earthElectronic Optical and Magnetic MaterialsEXAFSX-ray crystallographyCeramics and CompositesJournal of Solid State Chemistry
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Spray nozzle characterization using high speed imaging techniques

2013

International audience; Spray characteristics play an important role in the application accuracy and efficiency of plant protection products. In this study, the spray angles, liquid sheet lengths and spray shapes of five hydraulic spray nozzles (Albuz ATR orange, Albuz ATR red, TeeJet XR 110 01, TeeJet XR 110 04 and TeeJet AI 110 04) were measured using a developed high speed imaging system. Results were compared with the results of existing measuring techniques using a flow rate test bench, a horizontal patternator and a Phase Doppler Particle Analyzer (PDPA) laser.

spray angle[SDV] Life Sciences [q-bio][SDE] Environmental Sciencesspray shape[SDV]Life Sciences [q-bio][SDE]Environmental Sciences[SDV.BV]Life Sciences [q-bio]/Vegetal Biology[SDV.BV] Life Sciences [q-bio]/Vegetal Biologyspray characterizationhigh speed imaging
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The effects of antimicrobial sprays and mouthrinses on supragingival plaque regrowth: a comparative study.

2006

BACKGROUND: Due to the side effects of chlorhexidine digluconate (CHX) mouthrinsing, a spray has been proposed as an alternative method of CHX delivery to the oral cavity. The aim of this study was to investigate the plaque inhibitory effects of CHX, cetylpyridinium chloride (CPC), and triclosan (TRN) delivered by sprays and mouthrinses. METHODS: The study was an observer-masked, randomized cross-over design balanced for carryover effects, involving 15 healthy volunteers in a 4-day plaque regrowth model. Products being tested (0.2% CHX, 0.12% CHX, 0.05% CPC, and 0.03% TRN) were used both as sprays and mouthrinses. A saline solution served as a negative control. On day 1, subjects received p…

spray/therapeutic useAdultMalemedicine.medical_treatmentDental PlaqueMouthwashesDentistryCetylpyridiniumCetylpyridiniumSodium ChlorideCetylpyridinium chlorideDental plaqueOral hygienetriclosan/therapeutic use.chemistry.chemical_compoundSettore MED/28 - Malattie OdontostomatologichemedicineHumansSingle-Blind MethodColoring AgentsSalinedental plaque/prevention and controlAerosolsObserver VariationCross-Over Studiesmouthrinse/therapeutic usebusiness.industryChlorhexidineChlorhexidineDental ProphylaxisReproducibility of Resultsmedicine.diseaseOral HygieneCrossover studyTriclosanTriclosanchlorhexidine/ therapeutic usechemistryCetylpyridinium chloride/therapeutic useAnti-Infective Agents LocalPeriodonticsFemalebusinessmedicine.drugJournal of periodontology
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Analysis of Exosomal Cargo Provides Accurate Clinical, Histologic and Mutational Information in Non-Small Cell Lung Cancer

2022

Simple Summary Non-small cell lung cancer (NSCLC) is the second most commonly diagnosed cancer and the leading cause of cancer-related death worldwide. Clinical decision-making depends on the histological classification; however, tissue biopsy is frequently not technically feasible due to tumor location or limited tissue samples. Therefore, we propose to find clinical, molecular and histological biomarkers using a minimally invasive approach based on the analysis of the cargo of the blood extracellular vesicles. Exosomes are membranous vesicles present in several biological fluids, which carry biological information to distant tissues, regulating several tumor processes. This study aims to …

squamous cell carcinomaCancer ResearchtumorspheresMICRORNASBIOMARKERSCANCER/TESTIS ANTIGENexosomesNSCLCnon-small cell lung cancer; liquid biopsy; exosomes; extracellular vesicles; cell cultures; adenocarcinoma; squamous cell carcinoma; biomarker; tumorspheresMECHANISMSRNASMICROARRAYIMMUNOTHERAPYCàncernon-small cell lung cancerScience & Technologyadenocarcinomaliquid biopsycell culturesSTATISTICSOncologyPulmonsbiomarkerextracellular vesiclesLife Sciences & Biomedicine
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Coronal properties of active G-type stars in different evolutionary phases

2005

We report on the analysis of XMM-Newton observations of three G-type stars in very different evolutionary phases: the "weak-line" T Tauri star HD 283572, the Zero Age Main Sequence star EK Dra and the Hertzsprung-gap giant star 31 Corn. The X-ray luminosities of the three stars are all in the range 10(30) - 10(31) erg/s. We compare the Emission Measure Distributions of these bright sources, derived from high-resolution X-ray spectra, as well as the pattern of elemental abundances vs. First Ionization Potential (FIP). The results of our analysis suggest that the coronae of these stars are very similar in terms of dominant coronal magnetic structures, in spite of differences in their evolutio…

stars : activitystars : individual : EK DraSettore FIS/05 - Astronomia E AstrofisicaX-rays : starstars : individual : HD 283572stars: individual: 31 Comstars; techniques : spectroscopic; stars : activity; stars : coronae; stars: individual: 31 Com; stars : individual : EK Dra; stars : individual : HD 283572 [X-rays]stars : coronaetechniques : spectroscopic
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The XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST)

2007

(abridged:) The XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST) surveys the most populated ~5 square degrees of the Taurus star formation region, using the XMM-Newton X-ray observatory to study the thermal structure, variability, and long-term evolution of hot plasma, to investigate the magnetic dynamo, and to search for new potential members of the association. Many targets are also studied in the optical, and high-resolution X-ray grating spectroscopy has been obtained for selected bright sources. The X-ray spectra have been coherently analyzed with two different thermal models (2-component thermal model, and a continuous emission measure distribution model). We present ov…

stars : pre-main sequence010504 meteorology & atmospheric sciencesAstrophysics::High Energy Astrophysical PhenomenaBrown dwarfFOS: Physical sciencesAstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsAstrophysics01 natural sciencesLuminosity[PHYS.ASTR.CO]Physics [physics]/Astrophysics [astro-ph]/Cosmology and Extra-Galactic Astrophysics [astro-ph.CO]Observatory0103 physical sciencesProtostarAstrophysics::Solar and Stellar Astrophysics010303 astronomy & astrophysicsAstrophysics::Galaxy Astrophysics0105 earth and related environmental sciencesPhysicsstars : formationStar formationMolecular cloudAstrophysics (astro-ph)Astronomy and AstrophysicsAccretion (astrophysics)Starsgravitational waves13. Climate actionSpace and Planetary ScienceX-rays : star
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Spectral properties of X-ray bright variable sources in the Taurus Molecular Cloud

2006

We analyze 19 bright variable X-ray sources detected in the XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST), in order to characterize the variations with time of their coronal properties and to derive informations on the X-ray emitting structures. We performed time-resolved spectroscopy of the EPIC PN and MOS spectra of the XEST sources, using a model with one or two thermal components, and we used the time evolution of the temperatures and emission measures during the decay phase of flares to derive the size of the flaring loops. The light curves of the selected sources show different types of variability: flares, long-lasting decay or rise through the whole observation, sl…

stars : pre-main sequence010504 meteorology & atmospheric sciencesAstrophysics::High Energy Astrophysical PhenomenaX-rays : starsFOS: Physical sciencesFluxAstrophysicsAstrophysics01 natural sciences7. Clean energySpectral linelaw.inventionlaw0103 physical sciencesAstrophysics::Solar and Stellar AstrophysicsSpectroscopy010303 astronomy & astrophysics0105 earth and related environmental sciencesPhysicsMolecular cloudAstrophysics (astro-ph)Astronomy and Astrophysicsstars : late-typeRadiusPlasmaLight curve13. Climate actionSpace and Planetary Sciencestars : coronaeFlare
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