Search results for "React"
showing 10 items of 9101 documents
Nucleon dissociation and incoherent J/ψ photoproduction on nuclei in ion ultraperipheral collisions at the CERN Large Hadron Collider
2019
Using the general notion of cross section fluctuations in hadron-nucleus scattering at high energies, we derive an expression for the cross section of incoherent J / ψ photoproduction on heavy nuclei d σ γ A → J / ψ Y / d t , which includes both elastic d σ γ p → J / ψ p / d t and proton-dissociation d σ γ p → J / ψ Y / d t photoproduction on target nucleons. We find that, with good accuracy, d σ γ A → J / ψ Y / d t can be expressed as a product of the sum of the d σ γ p → J / ψ p / d t and d σ γ p → J / ψ Y / d t cross sections, which have been measured at HERA, and the common nuclear shadowing factor, which is calculated using the leading twist nuclear shadowing model. Our prediction for …
Modulation of Efficient Diiodo-BODIPY in vitro Phototoxicity to Cancer Cells by Carbon Nano-Onions
2020
Photodynamic therapy (PDT) is currently one of the most promising approaches for targeted cancer treatment. It is based on responses of vital physiological signals, namely reactive oxygen species (ROS), which are associated with diseased condition development, such as tumors. This study presents the synthesis, incorporation, and application of a diiodo-BODIPY based photosensitizer, based on a non-covalent functionalization of carbon nano-onions (CNOs). In vitro assays demonstrate that HeLa cells internalize the diiodo-BODIPY molecules, and their CNOs nanohybrids. Upon cell internalization and light exposure, the pyrene-diiodo-BODIPY molecules induce an increase of the ROS level of HeLa cell…
Impact of Platelet Reactivity in ACS Patients on Clinical Outcomes with Triple Antithrombotic Therapy
2021
Optimal antithrombotic therapy after percutaneous coronary intervention (PCI) in patients on oral anticoagulants (OAC) remains a clinical conundrum. In fact, combining an OAC with dual antiplatelet therapy (triple antithrombotic therapy, TAT) increases the risk of bleeding. Clopidogrel is the only thienopyridine recommended in TAT patients. Whether its response plays a relevant role in this setting remains uncertain. We aimed to evaluate the level of platelet reactivity inhibition (PRI) achieved by oral TAT in Acute Coronary Syndrome (ACS) patients undergoing PCI and its relationship with outcomes. We performed a multicenter prospective observational study and assessed PRI by vasodilator-st…
Understanding selective reduction reactions with heterogeneous Pd and Pt : climbing out of the black box
2016
Facile and efficient chemical functionalization of aliphatic polyesters by cross metathesis
2016
International audience; An effective preparation of new tailor-made macromolecular materials via a combination of two (atom-efficient) catalytic transformations is reported. First, new aliphatic polyesters with alternated composition have been prepared using a salen aluminum catalyst system. Next, the pendant vinyl moieties in those copolymers have been selectively transformed into various functional groups by metathesis in the presence of homogeneous Grubbs catalysts. The latter metathesis reaction has been optimized in terms of catalytic activity and selectivity, to define the conditions for an effective and safe procedure that does not affect the macromolecular architecture. All polymer …
On the effectiveness of different additives and concentrations on the re-building of the molecular structure of degraded polyethylene
2006
Mechanical recycling is an easy and economic way to re-use plastic waste as secondary materials, but, in general, their properties are worse with respect to the reclaimed materials and the virgin polymer. The aim of this work was to study the effect of concentration and reaction kinetics of two additives, an ethylene-co-glycidyl methacrylate (Lotader) and a hydroxylamine derivative (CGX), in the re-building of a degraded polyethylene. CGX is a nitroxyl radical generator able to form branching in polyolefins while the epoxy groups of Lotader can react with the functional groups present in the recycled polyethylene. The results indicate that the CGX has a higher reaction rate than Lotader, pr…
On the Preparation and the Characterization of Polyethylene/Polyamide Blends by Melt Processing in the Presence of an Ethylene(co)acrylic Acid Copoly…
2006
Samples of HDPE and PA6 have been meltprocessed in the presence of two new phosphazene compounds, CP-2EPOX and CP-2OXA together with an ethylene/ acrylic acid copolymer. The blends have been prepared in an industrial twin-screw extruder by using PA6 and PE in weight ratios of 25/75 and 75/25. When used, 5 phr of EAA and 0.2 phr of CP have been added. The materials have been completely characterized from a rheological, morphological, and mechanical point of view. The results indicate that the additives used caused an increase in the rupture tensile properties, of the impact strength and viscosity especially in the PE-rich blend in the presence of CP-2EPOX. This result can be attributed both …
Direct asymmetric aldol reaction using polystyrene-supported proline amide
2008
Determinación de Streptococcus Mutans y Streptococcus Sobrinus, mediante pcr cuantitativa a tiempo real, y su relación con la caries dental en escola…
2013
La caries dental presenta una etiología multifactorial, los factores ambientales, los hábitos de alimentación, higiene bucal y la susceptibilidad genética individual, juegan un papel importante en el desarrollo de esta enfermedad (1). Los Streptococcus mutans y Streptococcus sobrinus están fuertemente implicados en la aparición de la caries dental en humanos. Numerosos estudios han demostrado que la asociación de S. mutans y S. sobrinus conlleva niveles más altos de caries (2-4) y varios estudios han encontrado que la prevalencia deS. sobrinus está fuertemente asociada con mayor actividad de caries que la delS. mutans (5-6). Se considera que la determinación de estas dos especies en la infa…
Soybean Diseases Caused by Genus Pseudomonas Phytopathenes Bacteria
2019
The rationale and experimental confirmation of the role of the bacteria of the Pseudomonas genus in the pathogenesis of soybean, and the investigation of the biological properties of the main causative agent Pseudomonas savastanoi pv. glycines. Methods. Theoretical generalization, laboratory-model research, phytopathological, microbiological, physiological, biochemical and genetic methods. Results. The largest group of pathogens in different soil-climatic zones of Ukraine consists of bacteria of the genus Pseudomonas was established. Their biological properties have been investigated and the methods for identification of the dominant type of phytopathogenic bacteria causing bacterial blight…