Search results for "Reduct"

Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi-Lability.

2021

We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. peerReviewed

Algebraic singularities have maximal reductive automorphism groups

1989

LetX = On/ibe an analytic singularity where ṫ is an ideal of theC-algebraOnof germs of analytic functions on (Cn, 0). Letdenote the maximal ideal ofXandA= AutXits group of automorphisms. An abstract subgroupequipped with the structure of an algebraic group is calledalgebraic subgroupofAif the natural representations ofGon all “higher cotangent spaces”are rational. Letπbe the representation ofAon the first cotangent spaceandA1=π(A).

Partial-order reduction for parity games and parameterised Boolean equation systems

2022

AbstractIn model checking, reduction techniques can be helpful tools to fight the state-space explosion problem. Partial-order reduction (POR) is a well-known example, and many POR variants have been developed over the years. However, none of these can be used in the context of model checking stutter-sensitive temporal properties. We propose POR techniques for parity games, a well-established formalism for solving a variety of decision problems, including model checking. As a result, we obtain the first POR method that is sound for the full modal $$\upmu $$ μ -calculus. We show how our technique can be applied to the fixed point logic called parameterised Boolean equation systems, which pro…

Is no One Left Behind? Inclusive Citizenship in Practices of Self-help Groups in Rural Tanzania

2023

The United Nations’ Sustainable Development Goals (SDGs) are based on the Agenda 2030 according to which ‘no one is left behind’, highlighting the need for inclusive citizenship at all levels. This article examines self-help groups in rural Tanzania as potential arenas for inclusive citizenship, which is defined as bottom-up practices of membership, participation, and livelihood enhancement. However, inclusive citizenship is also characterised by exclusions. Therefore, while acknowledging the important contribution of self-help groups for development, this article scrutinises the question of patterns of exclusion, first, in practices of self-help groups, and second, in the relationships bet…

Optimization of BESS Capacity Under a Peak Load Shaving Strategy

2018

Battery energy storage systems (BESSs) are becoming increasingly competitive in the global energy landscape, thanks to the strong cost reduction that has taken place in recent years and it is expected to continue in the next future. Among the many benefits BESSs can provide, time shifting can be exploited by electricity consumers to save on the electricity bill, charging the storage during the off-peak hours and discharging when the cost of electricity is high. This paper describes a simple procedure to optimize the BESS capacity under a peak load shaving strategy, in presence of a time-of-use (TOU) electricity rate, able to guarantee, at the same time, the flattest daily power diagram and …

Relative abundance of the membrane bound- and periplasmic nitrate-reductases in the environment

2007

Molecular evolution of aphids and their primary (Buchnera sp.) and secondary endosymbionts: Implications for the role of symbiosis in insect evolution

2001

Aphids maintain an obligate, endosymbiotic association with Buchnera sp., a bacterium closely related to Escherichia coli. Bacteria are housed in specialized cells of organ-like structures called bacteriomes in the hemocoel of the aphid and are maternally transmitted. Phylogenetic studies have shown that the association had a single origin, dated about 200-250 million years ago, and that host and endosymbiont lineages have evolved in parallel since then. However, the pattern of deepest branching within the aphid family remains unsolved, which thereby hampers an appraisal of, for example, the role played by horizontal gene transfer in the early evolution of Buchnera. The main role of Buchner…

Effect of Er3+-doping on 65GeS2-25Ga2S3-10CsCl glass probed by annihilating positrons

2019

Abstract Effect of Er3+-doping resulting in pronounced mid-IR fluorescence functionality was examined first in chalcohalide 65GeS2-25Ga2S3-10CsCl glass using positron annihilation lifetime (PAL) spectroscopy. The detected PAL spectra were reconstructed from unconstrained x2-term analysis employing two-state simple trapping model for one kind of positron trapping free-volume defects, the parameterization being performed at the example of 65GeS2-25Ga2S3-10CsCl glass doped with 0.6 at. % of Er3+. The observed decrease in positron trapping rate was proved to be primary void-evolution process in this Er-activated glass, like in many other chalcogenide glasses affected by rare earth doping. The n…

Poverty Reduction: The Paradox of the Endogenous Poverty Line

2007

When evaluating poverty, the relative poverty line may be considered as a percentage of the median income or it may be a percentage of the average income. It is proved that, with a poverty line relative to the median income, reducing poverty may become less costly in proportion to the total income as poverty increases (measured by the Sen, the Sen-Shorrocks-Thon or the Foster-Greer-Thorbecke poverty indexes) by passing from a Lorenz concentration curve to another curve associated with more poverty. This is obviously a paradox, although a largely overlooked one. However, it is shown that the paradox vanishes if the poverty line is relative to the average income. The demonstration is both exp…

Numerical and Experimental Study of a Novel Concept for Hydraulically Controlled Negative Loads

2016

This paper presents a numerical and experimental investigation of a novel concept that eliminates oscillations in hydraulic systems containing a counterbalance valve in series with a pressure compensated flow supply. The concept utilizes a secondary circuit where a low-pass filtered value of the load pressure is generated and fed back to the compensator of the flow supply valve. The novel concept has been implemented on a single boom actuated by a cylinder. A nonlinear model of the system has been developed and an experimental verification shows good correspondence between the model and the real system. The model is used for a parameter study on the novel concept. From the study it is found…