Search results for "Reference"

showing 10 items of 2491 documents

On the determination of underivatised fatty alcohol ethoxylates by electrospray ionisation–mass spectrometry

2006

Abstract The oligomers of fatty alcohol ethoxylates (FAEs) exhibit large sensitivity differences in mass spectrometry with electrospray ionisation (ESI–MS) and atmospheric pressure chemical ionization (APCI). Standards of the oligomers from m = 1 to 7 ethylene oxide units (EOs) and linear alkyl chains from n = 10 to 18 carbon atoms were infused to examine the relative sensitivities or response factors in several media. The response factors of the [M + H]+ and [M + Na]+ peaks in 9:1 acetonitrile/water and methanol/water media containing acid buffers increased following irregular patterns when n and m increased. In methanol/water the response factors depended on the parity of m, being larger …

chemistry.chemical_classificationSpectrometry Mass Electrospray IonizationElectrosprayChromatographyEthylene oxideOrganic ChemistryAnalytical chemistryFatty alcoholAtmospheric-pressure chemical ionizationGeneral MedicineBuffersReference StandardsMass spectrometryBiochemistryHigh-performance liquid chromatographyAnalytical Chemistrychemistry.chemical_compoundchemistrySolventsMethanolFatty AlcoholsChromatography High Pressure LiquidAlkylJournal of Chromatography A
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B-DNA Structure and Stability as Function of Nucleic Acid Composition. Dispersion-Corrected DFT Study of Dinucleoside-Monophosphate Single and Double…

2013

actions of the sugar-phosphate skeleton with water; (6) hydrophobic interactions of the DNA cylindrical core, made up by the hydrogen-bonded and stacked nitrogen bases, with the water solvent. Recently, there has been increasing effort in developing and applying quantum chemical methods able to reproduce the structure of native B-DNA and to correctly describe the energy involved in the intrastrand and interstrand noncovalent interactions between the nucleotide monomers. This topic has been approached by both wave function methods and density functional theory. [2] Water solvent and sodium counterions also play an important role in the formation and relative stabilization of the double-helic…

chemistry.chemical_classificationStereochemistryChemistryBase pairHydrogen bondStackingGeneral ChemistryCrystal structureFull Papersstacking interactionsNucleobaseHydrophobic effectCrystallographyDNA structuresSettore CHIM/03 - Chimica Generale E Inorganicadensity functional calculationshydrogen bondsNon-covalent interactionsDNA DFT calculations structure stabilityDensity functional theoryWatson–Crick base pairsTheoretical ChemistryGeneralLiterature_REFERENCE(e.g.dictionariesencyclopediasglossaries)
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Study of the factors influencing the bioaccessibility of 10 elements from chocolate drink powder

2016

Abstract A risk/benefit assessment of chocolate drink powder has been conducted by evaluating the total contents and the bioaccessibilities of Al, Ba, Cd, Cr, Cu, Fe, Mg, Mn, P and Zn. The bioaccessibility was studied considering the type of sample (traditional, light, diet and organic) and the different factors that may affect it, including physical-chemical parameters of the human digestive process (gastric pH, concentration of bile salts and presence of lipase) and the presence of dietary components (phytate, pectin, cellulose and tannin). The bioaccessibility varied greatly according to the sample type, being greater in the diet and organic samples, and on the element being considered (…

chemistry.chemical_classificationfood.ingredientPectinbiologyChemistry010401 analytical chemistryFood composition data04 agricultural and veterinary sciences040401 food science01 natural sciencesReference Daily Intake0104 chemical sciencesGastric phchemistry.chemical_compound0404 agricultural biotechnologyfoodbiology.proteinSample TypeTanninFood scienceLipaseCelluloseFood ScienceJournal of Food Composition and Analysis
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Assessment of Intake of Nicotinic Acid and Nicotinamide in Relation to Tolerable Upper Intake Levels

2018

chemistry.chemical_compoundNicotinic agonistNicotinamidechemistryFood supplementbusiness.industryDietary Reference IntakePhysiologyMedicinebusinessRisk assessmentNiacinEuropean Journal of Nutrition & Food Safety
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ChemInform Abstract: Pyrazolo[3,4-d]pyrimidine Derivatives as COX-2 Selective Inhibitors: Synthesis and Molecular Modelling Studies.

2009

The pyrazolo[3,4-d]pyrimidine system shows a multitude of interesting pharmacological properties. Owing to the potential anti-inflammatory activity of 5-benzamido-pyrazolo[3,4-d]pyrimidin-4-one derivatives and considering the easy synthesis of this class of compounds, a set of new 5-benzamido-1H-pyrazolo[3,4-d]pyrimidin-4-ones has been prepared in 42-80% yields by reacting 5-aminopyrazole-4(N-benzoyl)carbohydrazide derivatives and the opportune triethylorthoesters. Compounds 8a, b, 10a-d, and 11a, b revealed a superior inhibitory profile against COX-2, when compared to that of reference standards NS398 and indomethacin. Molecular modelling studies confirmed the obtained biological results.

chemistry.chemical_compoundPyrimidineChemistryGeneral MedicineCarbohydrazideCombinatorial chemistryReference standardsChemInform
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Pyrazolo[3,4‐d]pyrimidine Derivatives as COX‐2 Selective Inhibitors: Synthesis and Molecular Modelling Studies

2009

The pyrazolo[3,4-d]pyrimidine system shows a multitude of interesting pharmacological properties. Owing to the potential anti-inflammatory activity of 5-benzamido-pyrazolo[3,4-d]pyrimidin-4-one derivatives and considering the easy synthesis of this class of compounds, a set of new 5-benzamido-1H-pyrazolo[3,4-d]pyrimidin-4-ones has been prepared in 42-80% yields by reacting 5-aminopyrazole-4(N-benzoyl)carbohydrazide derivatives and the opportune triethylorthoesters. Compounds 8a, b, 10a-d, and 11a, b revealed a superior inhibitory profile against COX-2, when compared to that of reference standards NS398 and indomethacin. Molecular modelling studies confirmed the obtained biological results.

chemistry.chemical_compoundPyrimidineChemistryStereochemistryDocking (molecular)Drug DiscoveryPharmaceutical ScienceCarbohydrazideReference standardsArchiv der Pharmazie
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Social body odors

2013

Clef UT: 000324010400049; National audience

chemosensory cuesmother breastresponse[ SCCO.PSYC ] Cognitive science/Psychologymothers breast[SDV.AEN] Life Sciences [q-bio]/Food and Nutritionpheromonefemalechemosensory cueovulation[SCCO.PSYC]Cognitive science/Psychology[SCCO.PSYC] Cognitive science/Psychologywomanresponseswomenhumanhumanspheromonespreference[SDV.AEN]Life Sciences [q-bio]/Food and NutritionpreferencesComputingMilieux_MISCELLANEOUSattraction
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Evolution de la perception sensorielle et des préférences alimentaires chez les personnes âgées : quel lien avec le statut nutritionnel ?

2012

Le processus de vieillissement, même lorsqu’il se déroule normalement, est associé à de nombreuses modifications d’ordre physiologiques (ralentissement du transit intestinal, du métabolisme basal, perte de dents, altérations des capacités chimiosensorielles), psychologiques (solitude, dépression, démence) et sociologiques (retraite, veuvage, déménagement…) susceptibles d’avoir un impact sur la prise alimentaire et le statut nutritionnel de la personne âgée. Au-delà de ces changements, l’apparition d’une dépendance pour l’alimentation, qui fait généralement suite à une perte d’autonomie de la personne (apparition d’une incapacité physique ou psychique, veuvage…), modifie en profondeur le rap…

chemosensory perception[SDV.AEN] Life Sciences [q-bio]/Food and Nutrition[ SDV.AEN ] Life Sciences [q-bio]/Food and Nutrition[SDV.AEN]Life Sciences [q-bio]/Food and Nutritionelderlyfood preferences
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Effect of a sensory education programme on children’s preferences and eating behavior

2016

child[SDV.AEN] Life Sciences [q-bio]/Food and Nutritionfood behaviourpreferencesensory education
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Déterminants des préférences alimentaires des enfants

2015

child[SDV.AEN] Life Sciences [q-bio]/Food and Nutritionlearningpreferenceinfant
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