Search results for "Roche"
showing 10 items of 2666 documents
A Tunable, Fullerene‐Based Molecular Amplifier for Vibrational Circular Dichroism
2019
Abstract Vibrational circular dichroism (VCD) studies are reported on a chiral compound in which a fullerene C60 moiety is used as an electron acceptor and local VCD amplifier for an alanine‐based peptide chain. Four redox states are investigated in this study, of which three are reduced species that possess low‐lying electronic states as confirmed by UV/Vis spectroelectrochemistry. VCD measurements in combination with (TD)DFT calculations are used to investigate (i) how the low‐lying electronic states of the reduced species modulate the amplification of VCD signals, (ii) how this amplification depends on the distance between oscillator and amplifier, and (iii) how the spatial extent of the…
Coarse-Graining Intermolecular Interactions in Dispersions of Highly Charged Colloids
2012
International audience; Effective pair potentials between charged colloids, obtained from Monte Carlo simulations of two single colloids in a closed cell at the primitive model level, are shown to reproduce accurately the structure of aqueous salt-free colloidal dispersions, as determined from full primitive model simulations by Linse et al. (Linse, P.; Lobaskin, V. Electrostatic Attraction and Phase Separation in Solutions of Like-Charged Colloidal Particles. Phys. Rev. Lett.1999, 83, 4208). Excellent agreement is obtained even when ion-ion correlations are important and is in principle not limited to spherical particles, providing a potential route to coarse-grained colloidal interactions…
Control of Morphology and Corona Composition in Aggregates of Mixtures of PS-b-PAA and PS-b-P4VP Diblock Copolymers: Effects of Solvent, Water Conten…
2014
The morphologies and corona compositions in aggregates of mixtures of PS-b-PAA and PS-b-P4VP diblock copolymers are influenced by controllable assembly parameters such as water content, block copolymer molar ratios, and solvent effects as well as the hydrophilic block lengths and block length ratios. All these factors can affect the morphology of the aggregates as well as their corona composition, the latter especially in vesicles, where two interfaces are involved. The morphologies and corona compositions of the aggregates were investigated by transmission electron microscopy and electrophoretic mobility, respectively. They depend, to a large extent, on the solubility of P4VP and PAA in th…
Control of Corona Composition and Morphology in Aggregates of Mixtures of PS-b-PAA and PS-b-P4VP Diblock Copolymers: Effects of pH and Block Length
2014
The corona compositions and morphologies in aggregates of mixtures of amphiphilic polystyrene-block-poly(acrylic acid) (PS-b-PAA) and polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) diblock copolymers are influenced by controllable assembly parameters such as the hydrophilic block length and solution pH. The morphologies and corona compositions of the aggregates were investigated by transmission electron microscopy and electrophoretic mobility, respectively. When mineral acids or bases are present during aggregate formation, they can exert a strong influence on the corona composition. Morphology changes were also seen with changing pH, as well as changes in corona composition, specifica…
De Bibracte à Augustodunum : permanences et évolutions des activités manufacturières de l’époque gauloise à la fin du Haut-Empire
2007
L’importance de l’artisanat autunois et son développement jusqu’au iiie siècle prennent racine à Bibracte qui a su exploiter les ressources naturelles de son environnement et parfaire un savoir-faire local ayant survécu à la conquête. Les recherches sur ces activités manufacturières menées conjointement à Bibracte et à Autun nous offrent ainsi une opportunité d’étudier ces problématiques sur la durée. À Bibracte, puis à Autun, les artisans du métal sont omniprésents, mais d’autres métiers, aux témoins plus discrets, ont pu aussi êtres identifiés. Dans le cadre de cet article, nous présentons succinctement les lieux de production et un bilan des différents corps de métier. Enfin, nous évoquo…
Electrochemical Synthesis of an Organic Thermoelectric Power Generator.
2020
[EN] Energy harvesting through residual heat is considered one of the most promising ways to power wearable devices. In this work, thermoelectric textiles were prepared by coating the fabrics, first with multiple-wall carbon nanotubes (MWCNTs) by using the layer-by-layer technique and second with poly(3,4-ethylenedioxythiophene) (PEDOT) deposited by electrochemical polymerization. Sodium deoxycholate and poly(diallyldimethylammonium chloride) were used as stabilizers to prepare the aqueous dispersions of MWCNTs. The electrochemical deposition of PEDOT on the MWCNT-coated fabric was carried out in a three-electrode electrochemical cell. The polymerization of PEDOT on the fabric increased the…
Energy harvesting for mobile agents supporting wireless sensor networks
2022
Abstract Wireless sensor networks (WSNs) have been deployed widely in many different application including in civil and military fields. The sensing data from the networks is very diverse and may cost huge energy consumption for transmission. Hence, mobile sensors with high capacity are deployed to support the static sensors dealing with longer range communicating distances and also supplying power wirelessly the sensors if possible. This paper focuses on an energy harvesting (EH) design for either mobile agents or sensor nodes in WSNs. A hybrid EH system can harvest energy from ambient environment around to power the mobile sensors and static sensors. In addition, these mobile sensors and …
Structural analysis, phase stability and electrochemical characterization of Nb doped BaCe0.9Y0.1O3−x electrolyte for IT-SOFCs
2012
Abstract To improve the chemical stability of high temperature proton conductors based on barium cerate, electrolyte powders doped with different amounts of niobium were synthesized by the citrate–nitrate auto-combustion method. Pure single phases of BaCe 0.9− x Nb x Y 0.1 O 3− x (BCYN, 0.03 ≤ x ≤ 0.12) were obtained by thermal treatment at 1000 °C. Sintering at 1450 °C for 10 h produced dense pellets. X-ray absorption spectroscopy allowed to define the dopant ion insertion site and the co-dopant valency. Treatments in pure CO 2 atmosphere at 700 °C for 3 h and subsequent XRD analysis were carried out to probe the chemical stability of the produced electrolytes. The influence of the prese…
An Experiential Approach to the Consumption Value of Arts and Culture: The Case of Museums and Monuments
2006
This article is intended to enhance our understanding of the consumer experience within the cultural domain. The analysis of arts and culture consumption is based on a paradigm founded on the theory of value, which, in turn, underlies the notion of the consumer experience. By investigating the field of museums and monuments, the authors validate this experiential approach to the consumption value of arts and culture. They recommend that, since a theatrical setting elicits emotional and ludic reactions in individuals and entails visitor participation, attendance at museums and monuments could be increased by means of “theatricalizing” – or adding a show-oriented dimension to the consumer exp…
Le droit, les affaires et l'argent. Célébration du bicentenaire du Code de commerce, Actes des journées internationales de la Société d'histoire du d…
2008
Le droit, les affaires et l'argent fut le thème des Journées internationales de la Société d'histoire du droit, qui se sont déroulées à Dijon du 30 mai au 1er juin 2007, à l'occasion de la célébration du bicentenaire du Code de commerce. Cet ouvrage regroupe trente-huit articles d'histoire du droit consacrés à des périodes allant de l'Antiquité à nos jours et ce, dans toute l'Europe.