Search results for "Roth"

Expression of Heat Shock Proteins Hsp10, Hsp27, Hsp60, Hsp70 and Hsp90 in urothelial carcinoma of urinary bladder

2006

Micellar liquid Chromatographic determination of diuretics by diazotization and coupling with the Bratton-Marshall reagent

1997

Abstract A Chromatographic procedure that uses micellar mobile phases of sodium dodecyl sulphate (SDS) and propanol at pH 3 is reported for the determination, in urine samples, of thiazide diuretics (althiazide, bendroflumethiazide, chlorothiazide, hydrochlorothiazide, hydroflumethiazide, and trichloromethiazide), and other diuretics having a sulphonamide substituent in the benzene ring. Precolumn derivatization with sodium nitrite and N -(1-naphthyl)ethylenediamine, to form the coloured azo dyes of the hydrolyzed diuretics, decreased the polarity of the compounds and, consequently, their retention in the micellar eluents, and permitted detection in the visible region, eliminating thus the …

Occurrence of currently used pesticides in ambient air of Centre Region (France)

2010

Ambient air samples were collected, from 2006 to 2008 at three rural and two urban sites in Centre Region (France) and analyzed for 56 currently used pesticides (CUPS), of which 41 were detected. The four CUPs most frequently detected were the herbicides trifluralin, acetochlor and pendimethalin and the fungicide chlorothalonil, which were found with frequencies ranging between 52 and 78%, and with average concentrations of 1.93, 1.32, 1.84 and 12.15 ng m(-3), respectively. Among the detected pesticides, concentrations of eight fungicides (spiroxamine, fenpropimorph, cyprodinil, tolyfluanid, epoxiconazole, vinchlozolin, fluazinam, fludioxinil), two insecticides (propargite, ethoprophos), an…

Quantification of deep CO2 fluxes from Central Italy. Examples of carbon balance for regional aquifers and of soil diffuse degassing.

1999

Abstract In Central Italy non-volcanic CO 2 is discharged by focused degassing (strong diffuse emission and vents) and by high-CO 2 groundwater. 3 He / 4 He data and the carbon isotopic composition of CO 2 are compatible with derivation from mantle degassing and/or metamorphic decarbonation. The gases produced at depth accumulate in permeable reservoirs composed of Mesozoic carbonates. When total pressure (roughly corresponding to p CO 2 ) of the reservoir fluid exceeds hydrostatic pressure, a free gas phase forms gas reservoirs within the permeable host rocks from which gases may escape toward the surface. This process generates both the focused vents and the CO 2 -rich springs which chara…

The role of the aquifer in soil CO2 degassing in volcanic peripheral areas: A case study of Stromboli Island (Italy)

2017

Abstract The peripheral area of Stromboli Island, Italy, named “Scari”, was continuously studied between January 2009 and December 2010. Data on soil CO 2 flux and the partial pressure of CO 2 (pCO 2 ) in equilibrium with the thermal aquifer linked to the magmatic system are presented. Soil CO 2 fluxes range from 20 to 370 g m − 2  d − 1 and have been strongly affected by soil temperature variations. Soil CO 2 flux data were filtered with respect to the soil temperature and the calculated values, called “residuals”, were considered to detect changes induced by the magmatic system. The pCO 2 values change in a wide range from 0.03 to 0.6 (atm), showing rapid variations. The results of this s…

Total (fumarolic + diffuse soil) CO2 output from Furnas volcano

2015

Furnas volcano, in São Miguel island (Azores), being the surface expression of rising hydrothermal steam, is the site of intense carbon dioxide (CO2) release by diffuse degassing and fumaroles. While the diffusive CO2 output has long (since the early 1990s) been characterized by soil CO2 surveys, no information is presently available on the fumarolic CO2 output. Here, we performed (in August 2014) a study in which soil CO2 degassing survey was combined for the first time with the measurement of the fumarolic CO2 flux. The results were achieved by using a GasFinder 2.0 tunable diode laser. Our measurements were performed in two degassing sites at Furnas volcano (Furnas Lake and Furnas Villag…

Fumarolic alteration products at Sousaki (Greece) : occurrence and environmental impact

2009

Fumarolic alteration crusts and efflorescences have been sampled at the Sousaki solfataric field. Samples have been analysed for mineralogical (XRD) and chemical composition (HNO3 digestion and leaching with distilled water). Results show that mineralogical and chemical compositions (major, minor and trace metals) are controlled by microenvironmental conditions. The sample collected in the anoxic part of a cave is composed almost exclusively by native sulfur. The samples collected in the oxidizing part of the cave and outside in relatively sheltered position are mainly composed by very soluble sulfates. Chemical composition evidence strong enrichments in Al, Ca, Cr, Fe, Mg and Ni which are …

Fumarolic alteration products of three hydrothermal areas of Greece: Chemical characterization and environmental impact.

2018

Samples of efflorescences and encrustations of hydrothermal origin have been collected at three fumarolic areas in Greece. The three sites are Sousaki, Thiafi (Methana) and Kokkino Nero (Kos) and all belong to the South Aegean Active Volcanic Arc. Samples were analysed for their mineralogical (XRD and SEM-EDS) and chemical composition. Solutions obtained from both mineralization with HNO3 and leaching with distilled water, were analysed for major (ICP-OES), minor and trace metals (ICP-MS) and for sulfate contents (IC). Results show that their composition is mainly controlled by the petrological composition of the substrate (ultramafic rocks at Sousaki, felsic volcanic rocks at Methana and l…

Hydrothermal liquefaction of wet biomass in batch reactors: Critical assessment of the role of operating parameters as a function of the nature of th…

2022

A scientometric analysis of articles published from 1986 to 2022 on batch hydrothermal liquefaction of microalgae, macroalgae, lignocellulosic biomass, sewage sludge and organic wastes in water was performed. We found that biocrude yield can be correlated with the kinetic severity factor (KSF) and scattering of experimental data increases in the supercritical region probably for uncertainty in the medium density affecting the kinetics of reactions involved in the process. The level of correlation and the yield increased when fast heating rates of the reactor, higher than 25 ◦C/min, were adopted. Energy recovery of biocrude obtained in fast heating experiments changes linearly with biocrude …

Economic sustainability of hydrothermal liquefaction of sewage sludge: From a conceptual analysis to a practical verification

2022

Introduction: Hydrothermal liquefaction (HTL) could be a promising technology to produce biocrude from wet biomass. A conceptual analysis on the HTL of microalgae assisted by the use of solar heat demonstrated that even if microalgae are one of the most productive and investigated feedstock, their high cost hinders the economic sustainability of the process1. To overcome this issue a zero-cost wet waste biomass like sewage sludge (SS) could be adopted with comparable efficiency. Furthermore, the use of a proper catalyst, promoting the in-situ upgrading of the biocrude, still represents a big challenging opportunity for industrial HTL development. Aim: The outcomes of the conceptual analysis…