Search results for "S2"
showing 10 items of 200 documents
In-situ monitoring by Raman spectroscopy of the thermal doping of graphene and MoS2 in O-2-controlled atmosphere
2017
The effects of temperature and atmosphere (air and O2) on the doping of monolayers of graphene (Gr) on SiO2 and Si substrates, and on the doping of MoS2 multilayer flakes transferred on the same substrates have been investigated. The investigations were carried out by in situ micro-Raman spectroscopy during thermal treatments up to 430 °C, and by atomic force microscopy (AFM). The spectral positions of the G and 2D Raman bands of Gr undergo only minor changes during treatment, while their amplitude and full width at half maximum (FWHM) vary as a function of the temperature and the used atmosphere. The thermal treatments in oxygen atmosphere show, in addition to a thermal effect, an effect a…
O Triclusters Revisited: Classical MD and Quantum Cluster Results for Glasses of Composition (Al2O3)2(SiO2).
2005
The (17)O NMR spectrum of CaAl(2)Si(2)O(8) glass shows two types of O sites that are not present in the crystalline material. One of these, with (17)O NMR parameters C(Q) = 2.3 MHz and delta = +20 ppm, has been assigned to a "tricluster" O, a local geometry in which the O is coordinated to three tetrahedrally coordinated atoms, either Al or Si. For crystalline CaAl(4)O(7), a tricluster site (with three Al linkages to O, i.e., OAl(3)) has been characterized experimentally, with a C(Q) of 2.5 MHz and a delta of about +40 ppm. Thus, a C(Q) value of 2.5 MHz or less seems to be a characteristic of such sites, although they may show a range of delta values. However, several different quantum chem…
O Triclusters Revisited: Classical MD and Quantum Cluster Results for Glasses of Composition (Al2O3)2(SiO2)
2006
The (17)O NMR spectrum of CaAl(2)Si(2)O(8) glass shows two types of O sites that are not present in the crystalline material. One of these, with (17)O NMR parameters C(Q) = 2.3 MHz and delta = +20 ppm, has been assigned to a "tricluster" O, a local geometry in which the O is coordinated to three tetrahedrally coordinated atoms, either Al or Si. For crystalline CaAl(4)O(7), a tricluster site (with three Al linkages to O, i.e., OAl(3)) has been characterized experimentally, with a C(Q) of 2.5 MHz and a delta of about +40 ppm. Thus, a C(Q) value of 2.5 MHz or less seems to be a characteristic of such sites, although they may show a range of delta values. However, several different quantum chem…
Cēzija dimēra spektroskopiskie pētījumi ar lāzera inducētās fluorescences metodi
2017
Šajā bakalaura darbā tika pētīts Cs2 molekulas 〖A^1∑〗_u^+ un 〖b 〗^3 Π_u stāvokļu komplekss ar lāzera inducētās fluorescences un Furjē transformāciju spektroskopijas metodēm. Veicot darba uzdevumus tika apgūta lāzera inducētās fluorescences (LIF) pieeja sārmu divatomu molekulu pētīšanai, izmantojot spektrometru (Bruker IFS-125HR) un titāna-safīra lāzera sistēmu (MBR 110, Coherent). Eksperimentālajām iekārtām tika veikti sagatavošanas un uzstādīšanas darbi, lai varētu detektēt LIF spektrus ar Furjē spektrometru. Iegūtie mērījumi par Cs2 molekulas 〖A^1∑〗_u^+ ~ 〖b 〗^3 Π_u kompleksu tika izanalizēti izmantojot darbā aprakstītās spektru apstrādāšanas metodes. Darba rezultātā iegūti ~2000 rotācija…
The electronic spectra of 2-(2′-hydroxybenzoyl)pyrrole and 2-(2′-methoxybenzoyl)pyrrole: a theoretical study
2005
The gas-phase electronic spectra of 2-(2 0 -hydroxybenzoyl)pyrrole and 2-(2 0 -methoxybenzoyl)pyrrole have been determined using multiconfigurational perturbation theory (CASPT2). Solvatochromic spectral shifts for these molecules have been measured in cyclohexane and methanol and the electrostatic components of these shifts have been estimated using the vertical electrostatic model (VEM 4.2) developed for the configuration interaction with single excitations model implemented with the intermediate neglect of differential overlap Hamiltonian (CIS/INDO/ S2). Comparison between theory and experiment and an interpretation of the main spectral differences between the two substituted pyrroles an…
Nuclear Translocation of Mismatch Repair Proteins MSH2 and MSH6 as a Response of Cells to Alkylating Agents
2000
Mammalian mismatch repair has been implicated in mismatch correction, the prevention of mutagenesis and cancer, and the induction of genotoxicity and apoptosis. Here, we show that treatment of cells specifically with agents inducing O(6)-methylguanine in DNA, such as N-methyl-N'-nitro-N-nitrosoguanidine and N-methyl-N-nitrosourea, elevates the level of MSH2 and MSH6 and increases GT mismatch binding activity in the nucleus. This inducible response occurs immediately after alkylation, is long-lasting and dose-dependent, and results from translocation of the preformed MutSalpha complex (composed of MSH2 and MSH6) from the cytoplasm into the nucleus. It is not caused by an increase in MSH2 gen…
ENO1 gene product binds to the c-myc promoter and acts as a transcriptional repressor: relationship with Myc promoter-binding protein 1 (MBP-1).
2000
The Myc promoter-binding protein-1 (MBP-1) is a 37-38 kDa protein that binds to the c-myc P2 promoter and negatively regulates transcription of the protooncogene. MBP-1 cDNA shares 97% similarity with the cDNA encoding the glycolytic enzyme alpha-enolase and both genes have been mapped to the same region of human chromosome 1, suggesting the hypothesis that the two proteins might be encoded by the same gene. We show here data indicating that a 37 kDa protein is alternatively translated from the full-length alpha-enolase mRNA. This shorter form of alpha-enolase is able to bind the MBP-1 consensus sequence and to downregulate expression of a luciferase reporter gene under the control of the c…
PSD2 direktīvas ieviešana bankās
2020
2019. gada 14.septembrī Eiropas Savienībā stājās spēkā otrā Maksājumu pakalpojumu direktīva, pazīstama kā PSD2 (Payment Service Directive 2). Latvijā tās nosacījumi iestrādāti Maksājumu pakalpojumu un elektroniskās naudas likumā. Darba mērķis ir aprakstīt PSD2 pakalpojumu ieviešanu bankās, tas ir, dot aprakstu bankām par prasībām un dažādām komponentēm, kas ir jāimplementē, lai ieviestu PSD2 direktīvu, piemēram, kā, PSD2 lietotne, atļauju apstrāde, SSL/TLS sertifikātu apstrāde un trešās puses pakalpojumu sniedzēja servisi. Darbā tiek analizētas specifikācijas, kas apraksta PSD2 lietotnes interfeisu, noskaidrojot obligātās prasības un būtiskākās atšķirības. Darbā tiek piedāvāts risinājuma ap…
Le professionnel hautement qualifié et flexible dans la société de la connaissance
2009
09063; Rapport financé par le Conseil Régional de Bourgogne; La question centrale, fil conducteur de ce rapport, est la suivante : le diplômé de l'enseignement supérieur est-il "le professionnel hautement qualifié et flexible dans la société de la connaissance" ? Ce rapport de fin des travaux présente les principaux résultats de la recherche concernant la valorisation des compétences des diplômés européens de l'enseignement supérieur et la flexibilité sur les marchés du travail en mobilisant trois projets. L'enquête la plus récente, qui implique quinze pays d'Europe, fait l'objet du premier chapitre qui est centré sur l'analyse comparative des situations professionnelles et des perceptions …
γ2-Adaptin is functioning in the late endosomal sorting pathway and interacts with ESCRT-I and -III subunits.
2010
Abstractγ2-Adaptin is a clathrin adaptor-related protein with unclear physiological function. Previous studies indicated that γ2-adaptin might act within the multivesicular body (MVB) protein-sorting pathway that is central to receptor down-regulation, lysosome biogenesis, and budding of enveloped viruses. Here, we have analyzed the effects of excess and deficit γ2-adaptin on exogenous and endogenous MVB cargoes and on the MVB machinery itself. Foreign cargoes, like retroviral Gags, are entrapped by overexpressed γ2-adaptin in detergent-insoluble polymers and blocked in budding. When viral budding involves MVB/endosomal structures, excess γ2-adaptin acts by accelerating lysosomal Gag destru…