Search results for "SAH"
showing 10 items of 434 documents
: Evolution of the examination at the end of college in sub-Saharan Africa
2004
The evolution of schooling in the developing systems in sub-Saharan Africa has brought a sizeable new population into the colleges. Unfortunately, the scarcity of resources and the need to pursue development of basic education prevents maintaining this population in the lycees. Thus the examination at the end of college becomes the focus of very stressful management of different currents and finds itself divided about aims which are not easy to reconcile. Original solutions can be found, as is the case in Mauretania, while the combination of better-known solutions may allow this examination to deal with these contradictions.
The climate change effect on the african monsoon region : evolution of the precipitation and atmospheric fields in the CMIP3 and CMIP5 simulations un…
2013
The fourth IPCC report in 2007 established the synthesis of previously published work onthe effects of climate change on global and regional scales. It shows in particular that no consensuscan be found with regard to the future of rainfall — and atmospheric dynamics- associatedwith region — African monsoon. This dissertation revisits this issue in the light of new dataand using an approach avoiding over-representation of the number of simulations available forone type of model and taking into account the diversity of models and their evolution in time :twenty general circulation models (GCMs) participating in the exercises CMIP3 (twelve GCMs)and CMIP5 (eight GCMs) under the A1B emissions sc…
Erosion en milieu sableux cultivé au Niger : dynamique actuelle et passée en liaison avec la pression anthropique et les changements climatiques
2011
Sahelian ecosystems, especially those installed on sandy soils react very quickly and intensely to small climatic changes. In this semi-arid area, wind erosion which occurs mainly on cultivated millet fields and is threatening the sustainable use of land resources. Furthermore, the rapid population growth and the severe droughts of the twentieth century have had important impacts on ecosystems. To better manage this fragile environment, it is important first to understand how it works. This thesis was included in the framework of the AMMA project (African Monsoon Multidisciplinary Analyses) and was in the heart of a CORUS 2 (Coopération pour la Recherche Universitaire et Scientifique) progr…
Electronic Structure and Bonding of Icosahedral Core–Shell Gold–Silver Nanoalloy Clusters Au144–xAgx(SR)60
2011
Atomically precise thiolate-stabilized gold nanoclusters are currently of interest for many cross-disciplinary applications in chemistry, physics and molecular biology. Very recently, synthesis and electronic properties of "nanoalloy" clusters Au_(144-x)Ag_x(SR)_60 were reported. Here, density functional theory is used for electronic structure and bonding in Au_(144-x)Ag_x(SR)_60 based on a structural model of the icosahedral Au_144(SR)_60 that features a 114-atom metal core with 60 symmetry-equivalent surface sites, and a protecting layer of 30 RSAuSR units. In the optimal configuration the 60 surface sites of the core are occupied by silver in Au_84Ag_60(SR)_60. Silver enhances the electr…
Role of the central gold atom in ligand-protected biicosahedral Au 24 and Au25 clusters
2013
The crystal structures of the ligand-protected clusters [Au24(PPh3)10(SC2H4Ph)5Cl2]+ and [Au25(PPh3)10(SC2H4Ph)5Cl2]2+ have been elucidated recently, and they comprise the same biicosahedral structural motif for the Au core. The only difference is the central Au atom joining two icosahedra which is absent in the Au24 cluster. On the basis of density functional simulations, we have evaluated the structural, electronic, optical, and vibrational properties of the clusters in question with a full presentation for the thiolate and phosphine side groups. Our spherical harmonics analysis of the electronic structure shows that the chemical stability of both clusters can be understood based on an 8 …
Atomic structure solution of the complex quasicrystal approximant Al77Rh15Ru8 from electron diffraction data
2014
The crystal structure of the novel Al77Rh15Ru8phase (which is an approximant of decagonal quasicrystals) was determined using modern direct methods (MDM) applied to automated electron diffraction tomography (ADT) data. The Al77Rh15Ru8E-phase is orthorhombic [Pbma,a= 23.40 (5),b= 16.20 (4) andc= 20.00 (5) Å] and has one of the most complicated intermetallic structures solved solely by electron diffraction methods. Its structural model consists of 78 unique atomic positions in the unit cell (19 Rh/Ru and 59 Al). Precession electron diffraction (PED) patterns and high-resolution electron microscopy (HRTEM) images were used for the validation of the proposed atomic model. The structure of the E…
Analysis of eicosapentaenoic and docosahexaenoic acid geometrical isomers formed during fish oil deodorization.
2006
International audience; Addition of long-chain polyunsaturated fatty acids (LC-PUFAs) from marine oil into food products implies preliminary refining procedures of the oil which thermal process affects the integrity of LC-PUFAs. Deodorization, the major step involving high temperatures, is a common process used for the refining of edible fats and oils. The present study evaluates the effect of deodorization temperature on the formation of LC-PUFA geometrical isomers. Chemically isomerized eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) were used as reference samples. Fish oil samples have been deodorized at 180, 220 and 250 °C for 3 h and pure EPA and DHA fatty acid methyl esters…
Climate change engenders a better Early Warning System development across Sub-Saharan Africa: The malaria case
2022
It is expected that diseases are likely to spread to newer areas, and high-income countries may experience some illnesses that may have been restricted to low or middle-income countries. In addition, following the Intergovernmental Panel on Climate Change, the present study noted that climate change is likely to have many effects on the spatial and temporal distribution of malaria in many Sub-Saharan African countries. This study examines climate change effects on the geographical distribution of malaria occurrence and how extreme climatic events may perhaps be determining factors in the range of vectors for human diseases in SSA in the nearest future. Here, the study appraisals the symbiot…
Continuum elastic sphere vibrations as a model for low-lying optical modes in icosahedral quasicrystals
2004
The nearly dispersionless, so-called "optical" vibrational modes observed by inelastic neutron scattering from icosahedral Al-Pd-Mn and Zn-Mg-Y quasicrystals are found to correspond well to modes of a continuum elastic sphere that has the same diameter as the corresponding icosahedral basic units of the quasicrystal. When the sphere is considered as free, most of the experimentally found modes can be accounted for, in both systems. Taking into account the mechanical connection between the clusters and the remainder of the quasicrystal allows a complete assignment of all optical modes in the case of Al-Pd-Mn. This approach provides support to the relevance of clusters in the vibrational prop…
The influence of absorbed solar radiation by Saharan dust on hurricane genesis
2015
To date, the radiative impact of dust and the Sahar an air layer (SAL) on North Atlantic hurricane activity is not yet known. According to previous studies, dust stabilizes the atmosphere due to absorption of solar radiation but thus shifts convection to regions more conducive for hurricane genesis. Here we analyze differences in hurricane genesis and frequency from ensemble sensitivity simulations with radiatively active and inactive dust in the aerosol-climate model ECHAM6-HAM. We investigate dust burden and other hurricane-related variables and determine their influence on disturbances which develop into hurricanes (developing disturbances, DDs) and those which do not (nondeveloping dist…