Search results for "SAMPLE"
showing 10 items of 2270 documents
Analysis of primary aliphatic short-chain monoamines by LC in water samples
2003
Abstract Several derivatization procedures with o-phthaldialdehyde-N-acetylcysteine (OPA-NAC) were compared for a rapid analysis of primary aliphatic short-chain monoamines in water samples by HPLC using a LiChorospher analytical separation column (100RP18 125 mm ×4 mm i.d., 5 μm). Both the solution and the solid-support assisted off-line derivatization on C18 SPE cartridges were inadequate options because of beginning degradation processes of the instable isoindol derivatives during their transfer to the analytical column. This problem was precluded with the on-column or solid-support assisted on-line derivatization. In the last mentioned procedure, the derivatization took place in a Hype…
Environment and excavation: Pre-lab impacts on ancient DNA analyses
2008
Ancient DNA (aDNA) analyses enjoy an increasing role in palaeontological, archaeological and archaeozoological research. The limiting factor for aDNA studies is the degree of DNA preservation. Our study on 291 prehistoric cattle remains from Europe, the Near East and North Africa revealed that DNA preservation is mainly influenced by geographic and climatic conditions. Especially in hot climates, the preservation of sample material is generally low. We observed that these specimens are prone to further degradation and contamination during and after excavation. We give a description of the main caveats and a short guideline for adequate sample handling in order to facilitate the cooperation …
Evaluation of mycotoxins and their metabolites in human breast milk using liquid chromatography coupled to high resolution mass spectrometry
2014
Humans can be exposed to mycotoxins through the food chain. Mycotoxins are mainly found as contaminants in food and could be subsequently excreted via biological fluids such as urine or human breast milk in native or metabolised form. Since breast milk is usually supposed as the only food for new-borns, the occurrence of mycotoxins in thirty-five human milk samples was evaluated by a newly developed method based on QuEChERS extraction and UHPLC-HRMS detection. The method described here allows the detection of target mycotoxins in order to determine the quality of this initial feeding. The method has been fully validated, with recoveries ranging from 64% to 93% and relative standard deviatio…
Photochemical sample treatment for extracts clean up in PCB analysis from sediments.
2013
Sample purification can be considered the most polluting step of the whole analytical process for PCBs determination in sediment samples. The use of photochemical sample treatment represents an alternative methodology for extracts clean up allowing for a reduction of the used amount of organic solvents. The first application of a photochemical sample treatment for the selective removal or reduction of organic substances interfering with PCBs analyses in sediments is reported. The method's efficiency and robustness were compared with currently used chromatographic purification. Quality parameters such as recovery, linearity and reproducibility were studied. The entire procedure was validated…
Silica Materials Containing Cyclodextrin for Pollutant Removal
2018
This chapter reviews the use of cyclodextrin-silica hybrid systems and cyclodextrin-functionalized silica used as adsorbents or filters for the removal of inorganic and organic pollutants from aqueous solutions in solid-phase extraction and adsorption-oriented processes. Actually, there is a need to develop efficient processes for the synthesis and application of multifunctional silica-based materials for pollutant removal by adsorption or filtration, and for sample purification and concentration using solid-phase extraction.
Charge transfer in high-Tc(Y/Pr)Ba2Cu3O7superlattices
1996
We comment on the charge-transfer model for the unique softening of the apex [O(4)] oxygen observed in Raman spectra of a- and c-oriented (${\mathrm{YBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$${)}_{\mathit{m}}$(${\mathrm{PrBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$${)}_{\mathit{n}}$ superlattices presented in a recent paper by Ham et al. [Phys. Rev. B 50, 16 598 (1994)]. We find the size of the charge transfer necessary for the observed shift too large to explain the observations. In addition, a conclusion about the unique behavior of both types of superlattices can only be drawn if the sample quality is properly considered. \textcopyright{} 1996 The American Physical Society.
A Sample Selection Model for Unit and Item Nonresponse in Cross-Sectional Surveys
2007
We consider a general sample selection model where unit and item nonresponse simultaneously affect a regression relationship of interest, and both types of nonresponse are potentially correlated. We estimate both parametric and semiparametric specifications of the model. The parametric specification assumes that the errors in the latent regression equations follow a trivariate Gaussian distribution. The semiparametric specification avoids distributional assumptions about the underlying regression errors. In our empirical application, we estimate Engel curves for consumption expenditure using data from the first wave of SHARE (Survey on Health, Aging and Retirement in Europe).
Long term effect of teenage birth on earnings: Evidence from a British cohort study
2016
We use data from the 1970 British Cohort Study and evaluate the effect of teenage motherhood on hourly earnings at age 30, 34, 38, and 42 using alternative non-experimental estimation methods including linear regression, matching methods, and Heckman sample selection models. We conclude that teenage motherhood has a significant negative long-term effect on hourly wages. At age 42, teenage mothers earn 12% less than other women and 29% less than women who have not had any children. When compared to non-teenage mothers, the pay penalty reduces over time and becomes insignificant on the long term.
On the distribution of education and democracy
2006
This paper empirically analyzes the influence of the distribution of education on democracy by controlling for unobservable heterogeneity and by taking into account the persistency of some of the variables. The most novel finding is that increase in the education attained by the majority of the population is what matters for the implementation and sustainability of democracy, rather than the average years of schooling. We show this result is robust to issues pertaining omitted variables, outliers, sample selection, or a narrow definition of the variables used to measure democracy.
Reply to Douka et al: Critical evaluation of the Ksâr 'Akil chronologies
2015
Our paper (1) proposes a new chronology for Ksâr 'Akil based on 16 accelerator mass spectrometry (AMS) determinations on shells. To minimize the possibility of dating diagenetically compromised samples, we conducted amino acid racemization analyses on the intracrystalline proteins, oxygen isotope analysis, and geochemical characterization of all dated shells. Our calibrated radiocarbon ages fit well with existing Levantine chronologies, but are up to 4,000 y older than Douka et al.’s (2). Our paper explores several possibilities for this difference, whereas Douka et al. (3) provide alternative explanations. They accept our radiocarbon ages as correct but question our sample selection and Ba…