Search results for "SCAD"

2015

One-pot combination of the in-situ generation of hydrogen peroxide (H2O2) with selective oxidation reactions enhances the environmental and economic attractiveness of the use of H2O2 as green oxidant at industrial scale. This tandem reaction improves not only the safety aspects associated to H2O2 storage and transportation but also reduces the capital and operation costs. This review covers the progress in the field focussing on the areas of catalysis development, mechanistic understanding and engineering approaches (such as membrane reactors) for specific systems involving epoxidation of propylene oxide, hydroxylation of benzene, oxygenate synthesis from methane and Fenton processes, highl…

Ligand-Centred Fluorescence and Electronic Relaxation Cascade at Vibrational Time Scales in Transition-Metal Complexes

2015

Using femtosecond-resolved photoluminescence up-conversion, we report the observation of the fluorescence of the high-lying ligand-centered (LC) electronic state upon 266 nm excitation of an iridium complex, Ir(ppy)(3), with a lifetime of 70 +/- 10 fs. It is accompanied by a simultaneous emission of all lower-lying electronic states, except the lowest triplet metal-to-ligand charge-transfer ((MLCT)-M-3) state that shows a rise on the same time scale. Thus, we observe the departure, the intermediate steps, and the arrival of the relaxation cascade spanning similar to 1.6 eV from the (LC)-L-1 state to the lowest 3MLCT state, which then yields the long-lived luminescence of the molecule. This …

Dimethyl 2-(1-methyl-3-oxo-1,3-dihydroisobenzofuran-1-yl)malonate

2020

In this work we report a facile access to a 3,3-disubstituted isobenzofuranone by tandem addition/cyclization reaction to methyl 2-acetylbenzoate in the presence of dimethyl malonate, under basic conditions.

Synthesis of Polycyclic Indolines utilizing a reduction/cyclization cascade reaction

2021

Subsequent reduction and dearomatizing cyclization reactions open up an entry into the synthesis of novel N-fused polycyclic indolines. The dearomatizing cyclization as key step of the sequence proceeds well with Cu(OTf)2 or TfOH as catalyst. At elevated temperature reduction of nitro-substituted precursors with iron under acidic conditions affords a broad variety of polycyclic indolines directly in a two-step cascade reaction in good to excellent yields. Using the developed protocol, the alkaloids Tryptanthrin and Phaitanthrin C have been prepared. peerReviewed

Investigation about selective harmonic elimination in unbalanced multilevel inverters

2022

In this paper 5 and 7 levels cascaded H-bridges inverters are considered, feeding by unequal dc voltage sources. The effect of these unbalancing operation is examined concerning harmonic analysis and total harmonic distortion of the output voltages. The system of equations, obtained by the expansion in the Fourier series of phase output voltage, is solved by applying a method of graphic solution that allows obtaining the switching angles able to eliminate the lower order harmonics.

Data from: Wood-inhabiting fungi with tight associations with other species have declined as a response to forest management

2016

Research on mutualistic and antagonistic networks, such as plant–pollinator and host–parasite networks, has shown that species interactions can influence and be influenced by the responses of species to environmental perturbations. Here we examine whether results obtained for directly observable networks generalize to more complex networks in which species interactions cannot be observed directly. As a case study, we consider data on the occurrences of 98 wood-inhabiting fungal species in managed and natural forests. We specifically ask if and how much the positions of wood-inhabiting fungal species within the interaction networks influence their responses to forest management. For this, we…

Chronically Elevated Interleukin-6 Disturbs the Coagulation Cascade in Mice

2021

Abstract Introduction: Pro-inflammatory cytokines play an essential role as activators of the hemostatic system and in the regulation of physiological antithrombotic mechanisms. Interleukin-6 (IL-6) influences platelet production and platelet activation. It was associated with accelerated clotting and intravascular coagulation in tissue factor (TF)-driven murine thrombosis models. However, the precise role of myeloid cell-derived IL-6 on thrombosis formation and the hemostatic system is still unknown. Methods and Results: To better understand the role of IL-6 in thrombosis and the hemostatic system, we developed a new mouse strain with Cre-recombinase driven constitutive IL-6 expression spe…

Ultrasound and supercritical fluids as useful tools to recover nutrients and bioactive compounds from aquaculture and marine side streams

2021

Los productos provenientes de la acuacultura, así como de los subproductos marinos contienen una cantidad muy importante y diversa de compuestos con diferentes actividades biológicas, atrayendo así el interés de las industrias alimentaria, farmacéutica y cosmética, entre otras. Para beneficiarse de éstos, especialmente subproductos del pescado y microalgas, como fuente potencial de diversos compuestos antioxidantes, proteínas, carbohidratos, pigmentos, compuestos fenólicos, etc., la extracción en sí juega un papel crucial, fundamentalmente cuando se trata de tecnologías verdes y sostenibles. Las técnicas de extracción convencionales implican el uso de disolventes orgánicos y requieren tiemp…

Activation of the p38MAPK cascade is associated with upregulation of TNF alpha receptors in the spinal motor neurons of mouse models of familial ALS.

2005

Phosphorylated p38 mitogen-activated protein kinase (p38MAPK), but not activated c-jun-N-terminal kinase (JNK), increases in the motor neurons of transgenic mice overexpressing ALS-linked SOD1 mutants at different stages of the disease. This effect is associated with a selective increase of phosphorylated MKK3-6, MKK4 and ASK1 and a concomitant upregulation of the TNFalpha receptors (TNFR1 and TNFR2), but not IL1beta and Fas receptors. Activation of both p38 MAPK and JNK occurs in the activated microglial cells of SOD1 mutant mice at the advanced stage of the disease; however, this effect is not accompanied by the concomitant activation of the upstream kinases ASK1 and MKK3,4,6, while both …

Measurement and communication interfaces for distributed generation in smart grids

2013

The aim of this work is to perform a feasibility study on the measurement and communication strategies for the development of a new generation of interface devices for distributed generators and their integration on smart grids. The communication system can use one or more technologies, at the various levels, creating a low cost network infrastructure, in the framework of a SCADA (Supervisory Control and Data Acquisition) architecture. As regards the measurements, the attention is focused on the anti-islanding protection, based on a hybrid solution, which makes use of local measurements and communications with the grid, at both MV and LV level by employing the PLC technology. Some simulatio…